Synthesis and characterization of η3-Allyl palladium(II) complexes with tetraalkyldiphosphine disulfides, R2P(S)P(S)R 2 (R=Me, Et, nPr, nBu, Ph)

Elif Subasi; Ozan Sanli Senturk

doi:10.1080/15533174.2011.591311

Synthesis and characterization of η³-Allyl palladium(II) complexes with tetraalkyldiphosphine disulfides, R₂P(S)P(S)R ₂ (R=Me, Et, ⁿPr, ⁿBu, Ph)

Elif Subasi^*, Ozan Sanli Senturk

^*Corresponding author for this work

Department of Chemistry

Dokuz Eylul University

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

New allyl-palladium tetraalkyl(phenyl)diphosphine disulfide complexes, [(η³-CH₂CMeCH₂)Pd(tmps)]Cl, [(η³-CH₂CMeCH₂) Pd(teps)]Cl, [(η³-CH₂CMeCH₂)Pd(tpps)]Cl, [(η³-CH₂CMeCH₂) Pd(tbps)]Cl, [(η³-CH₂CMeCH₂)Pd(tPhps)]Cl, and [(R ₂P(S)P(S) R₂) R=Me, (tmps); Et, (teps); ⁿPr, (tpps); ⁿBu, (tbps); Ph, (tPhps)] have been prepared from the addition of tetraalkyl (phenyl)diphosphine disulfide to [(η³- CH₂CMeCH₂)Pd(μ-Cl)]₂. All the complexes have been characterized by elemental analysis, Fourier-transform infrared (FT-IR), nuclear magnetic resonance (¹H-NMR and ³¹P-{ ¹H}-NMR) spectroscopy, and fast atom bombardment (FAB) mass spectrometry. The spectroscopic studies suggest that ligands are cis-chelate bidentate coordination, forming five-membered Pd-S=P-P=S palladacycles, with the η³-allyl group completing the coordination sphere.

Original language	English
Pages (from-to)	834-838
Number of pages	5
Journal	Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry
Volume	41
Issue number	7
DOIs	https://doi.org/10.1080/15533174.2011.591311
Publication status	Published - Aug 2011

Funding

The authors thank the Research Foundation of Ege and Dokuz Eylul University for funds. They are grateful to the technical staff of TUBITAK (Technical and Scientific Research Council of Turkey) and Ege University for obtaining elemental analyses and mass and NMR spectra.

Funders	Funder number
Research Foundation of Ege and Dokuz Eylul University

Keywords

allyl complexes
diphosphinedisulfide
palladium complexes
synthesis

Access to Document

10.1080/15533174.2011.591311

Cite this

@article{6c395de98b7146b9842ed459d667a256,

title = "Synthesis and characterization of η3-Allyl palladium(II) complexes with tetraalkyldiphosphine disulfides, R2P(S)P(S)R 2 (R=Me, Et, nPr, nBu, Ph)",

abstract = "New allyl-palladium tetraalkyl(phenyl)diphosphine disulfide complexes, [(η3-CH2CMeCH2)Pd(tmps)]Cl, [(η3-CH2CMeCH2) Pd(teps)]Cl, [(η3-CH2CMeCH2)Pd(tpps)]Cl, [(η3-CH2CMeCH2) Pd(tbps)]Cl, [(η3-CH2CMeCH2)Pd(tPhps)]Cl, and [(R 2P(S)P(S) R2) R=Me, (tmps); Et, (teps); nPr, (tpps); nBu, (tbps); Ph, (tPhps)] have been prepared from the addition of tetraalkyl (phenyl)diphosphine disulfide to [(η3- CH2CMeCH2)Pd(μ-Cl)]2. All the complexes have been characterized by elemental analysis, Fourier-transform infrared (FT-IR), nuclear magnetic resonance (1H-NMR and 31P-{ 1H}-NMR) spectroscopy, and fast atom bombardment (FAB) mass spectrometry. The spectroscopic studies suggest that ligands are cis-chelate bidentate coordination, forming five-membered Pd-S=P-P=S palladacycles, with the η3-allyl group completing the coordination sphere.",

keywords = "allyl complexes, diphosphinedisulfide, palladium complexes, synthesis",

author = "Elif Subasi and Senturk, {Ozan Sanli}",

year = "2011",

month = aug,

doi = "10.1080/15533174.2011.591311",

language = "English",

volume = "41",

pages = "834--838",

journal = "Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry",

issn = "1553-3174",

publisher = "Taylor and Francis Ltd.",

number = "7",

}

Synthesis and characterization of η³-Allyl palladium(II) complexes with tetraalkyldiphosphine disulfides, R₂P(S)P(S)R ₂ (R=Me, Et, ⁿPr, ⁿBu, Ph). / Subasi, Elif; Senturk, Ozan Sanli.
In: Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry, Vol. 41, No. 7, 08.2011, p. 834-838.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis and characterization of η3-Allyl palladium(II) complexes with tetraalkyldiphosphine disulfides, R2P(S)P(S)R 2 (R=Me, Et, nPr, nBu, Ph)

AU - Subasi, Elif

AU - Senturk, Ozan Sanli

PY - 2011/8

Y1 - 2011/8

N2 - New allyl-palladium tetraalkyl(phenyl)diphosphine disulfide complexes, [(η3-CH2CMeCH2)Pd(tmps)]Cl, [(η3-CH2CMeCH2) Pd(teps)]Cl, [(η3-CH2CMeCH2)Pd(tpps)]Cl, [(η3-CH2CMeCH2) Pd(tbps)]Cl, [(η3-CH2CMeCH2)Pd(tPhps)]Cl, and [(R 2P(S)P(S) R2) R=Me, (tmps); Et, (teps); nPr, (tpps); nBu, (tbps); Ph, (tPhps)] have been prepared from the addition of tetraalkyl (phenyl)diphosphine disulfide to [(η3- CH2CMeCH2)Pd(μ-Cl)]2. All the complexes have been characterized by elemental analysis, Fourier-transform infrared (FT-IR), nuclear magnetic resonance (1H-NMR and 31P-{ 1H}-NMR) spectroscopy, and fast atom bombardment (FAB) mass spectrometry. The spectroscopic studies suggest that ligands are cis-chelate bidentate coordination, forming five-membered Pd-S=P-P=S palladacycles, with the η3-allyl group completing the coordination sphere.

AB - New allyl-palladium tetraalkyl(phenyl)diphosphine disulfide complexes, [(η3-CH2CMeCH2)Pd(tmps)]Cl, [(η3-CH2CMeCH2) Pd(teps)]Cl, [(η3-CH2CMeCH2)Pd(tpps)]Cl, [(η3-CH2CMeCH2) Pd(tbps)]Cl, [(η3-CH2CMeCH2)Pd(tPhps)]Cl, and [(R 2P(S)P(S) R2) R=Me, (tmps); Et, (teps); nPr, (tpps); nBu, (tbps); Ph, (tPhps)] have been prepared from the addition of tetraalkyl (phenyl)diphosphine disulfide to [(η3- CH2CMeCH2)Pd(μ-Cl)]2. All the complexes have been characterized by elemental analysis, Fourier-transform infrared (FT-IR), nuclear magnetic resonance (1H-NMR and 31P-{ 1H}-NMR) spectroscopy, and fast atom bombardment (FAB) mass spectrometry. The spectroscopic studies suggest that ligands are cis-chelate bidentate coordination, forming five-membered Pd-S=P-P=S palladacycles, with the η3-allyl group completing the coordination sphere.

KW - allyl complexes

KW - diphosphinedisulfide

KW - palladium complexes

KW - synthesis

UR - http://www.scopus.com/inward/record.url?scp=80051739537&partnerID=8YFLogxK

U2 - 10.1080/15533174.2011.591311

DO - 10.1080/15533174.2011.591311

M3 - Article

AN - SCOPUS:80051739537

SN - 1553-3174

VL - 41

SP - 834

EP - 838

JO - Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry

JF - Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry

IS - 7

ER -