Synthesis and characterization of η3-Allyl palladium(II) complexes with tetraalkyldiphosphine disulfides, R2P(S)P(S)R 2 (R=Me, Et, nPr, nBu, Ph)

Elif Subasi; Ozan Sanli Senturk

doi:10.1080/15533174.2011.591311

Synthesis and characterization of η³-Allyl palladium(II) complexes with tetraalkyldiphosphine disulfides, R₂P(S)P(S)R ₂ (R=Me, Et, ⁿPr, ⁿBu, Ph)

Elif Subasi^*, Ozan Sanli Senturk

^*Corresponding author for this work

Department of Chemistry

Dokuz Eylul University

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

New allyl-palladium tetraalkyl(phenyl)diphosphine disulfide complexes, [(η³-CH₂CMeCH₂)Pd(tmps)]Cl, [(η³-CH₂CMeCH₂) Pd(teps)]Cl, [(η³-CH₂CMeCH₂)Pd(tpps)]Cl, [(η³-CH₂CMeCH₂) Pd(tbps)]Cl, [(η³-CH₂CMeCH₂)Pd(tPhps)]Cl, and [(R ₂P(S)P(S) R₂) R=Me, (tmps); Et, (teps); ⁿPr, (tpps); ⁿBu, (tbps); Ph, (tPhps)] have been prepared from the addition of tetraalkyl (phenyl)diphosphine disulfide to [(η³- CH₂CMeCH₂)Pd(μ-Cl)]₂. All the complexes have been characterized by elemental analysis, Fourier-transform infrared (FT-IR), nuclear magnetic resonance (¹H-NMR and ³¹P-{ ¹H}-NMR) spectroscopy, and fast atom bombardment (FAB) mass spectrometry. The spectroscopic studies suggest that ligands are cis-chelate bidentate coordination, forming five-membered Pd-S=P-P=S palladacycles, with the η³-allyl group completing the coordination sphere.

Original language	English
Pages (from-to)	834-838
Number of pages	5
Journal	Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry
Volume	41
Issue number	7
DOIs	https://doi.org/10.1080/15533174.2011.591311
Publication status	Published - Aug 2011

Keywords

allyl complexes
diphosphinedisulfide
palladium complexes
synthesis

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10.1080/15533174.2011.591311

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@article{6c395de98b7146b9842ed459d667a256,

title = "Synthesis and characterization of η3-Allyl palladium(II) complexes with tetraalkyldiphosphine disulfides, R2P(S)P(S)R 2 (R=Me, Et, nPr, nBu, Ph)",

abstract = "New allyl-palladium tetraalkyl(phenyl)diphosphine disulfide complexes, [(η3-CH2CMeCH2)Pd(tmps)]Cl, [(η3-CH2CMeCH2) Pd(teps)]Cl, [(η3-CH2CMeCH2)Pd(tpps)]Cl, [(η3-CH2CMeCH2) Pd(tbps)]Cl, [(η3-CH2CMeCH2)Pd(tPhps)]Cl, and [(R 2P(S)P(S) R2) R=Me, (tmps); Et, (teps); nPr, (tpps); nBu, (tbps); Ph, (tPhps)] have been prepared from the addition of tetraalkyl (phenyl)diphosphine disulfide to [(η3- CH2CMeCH2)Pd(μ-Cl)]2. All the complexes have been characterized by elemental analysis, Fourier-transform infrared (FT-IR), nuclear magnetic resonance (1H-NMR and 31P-{ 1H}-NMR) spectroscopy, and fast atom bombardment (FAB) mass spectrometry. The spectroscopic studies suggest that ligands are cis-chelate bidentate coordination, forming five-membered Pd-S=P-P=S palladacycles, with the η3-allyl group completing the coordination sphere.",

keywords = "allyl complexes, diphosphinedisulfide, palladium complexes, synthesis",

author = "Elif Subasi and Senturk, {Ozan Sanli}",

year = "2011",

month = aug,

doi = "10.1080/15533174.2011.591311",

language = "English",

volume = "41",

pages = "834--838",

journal = "Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry",

issn = "1553-3174",

publisher = "Taylor and Francis Ltd.",

number = "7",

}

Synthesis and characterization of η³-Allyl palladium(II) complexes with tetraalkyldiphosphine disulfides, R₂P(S)P(S)R ₂ (R=Me, Et, ⁿPr, ⁿBu, Ph). / Subasi, Elif; Senturk, Ozan Sanli.
In: Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry, Vol. 41, No. 7, 08.2011, p. 834-838.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis and characterization of η3-Allyl palladium(II) complexes with tetraalkyldiphosphine disulfides, R2P(S)P(S)R 2 (R=Me, Et, nPr, nBu, Ph)

AU - Subasi, Elif

AU - Senturk, Ozan Sanli

PY - 2011/8

Y1 - 2011/8

N2 - New allyl-palladium tetraalkyl(phenyl)diphosphine disulfide complexes, [(η3-CH2CMeCH2)Pd(tmps)]Cl, [(η3-CH2CMeCH2) Pd(teps)]Cl, [(η3-CH2CMeCH2)Pd(tpps)]Cl, [(η3-CH2CMeCH2) Pd(tbps)]Cl, [(η3-CH2CMeCH2)Pd(tPhps)]Cl, and [(R 2P(S)P(S) R2) R=Me, (tmps); Et, (teps); nPr, (tpps); nBu, (tbps); Ph, (tPhps)] have been prepared from the addition of tetraalkyl (phenyl)diphosphine disulfide to [(η3- CH2CMeCH2)Pd(μ-Cl)]2. All the complexes have been characterized by elemental analysis, Fourier-transform infrared (FT-IR), nuclear magnetic resonance (1H-NMR and 31P-{ 1H}-NMR) spectroscopy, and fast atom bombardment (FAB) mass spectrometry. The spectroscopic studies suggest that ligands are cis-chelate bidentate coordination, forming five-membered Pd-S=P-P=S palladacycles, with the η3-allyl group completing the coordination sphere.

AB - New allyl-palladium tetraalkyl(phenyl)diphosphine disulfide complexes, [(η3-CH2CMeCH2)Pd(tmps)]Cl, [(η3-CH2CMeCH2) Pd(teps)]Cl, [(η3-CH2CMeCH2)Pd(tpps)]Cl, [(η3-CH2CMeCH2) Pd(tbps)]Cl, [(η3-CH2CMeCH2)Pd(tPhps)]Cl, and [(R 2P(S)P(S) R2) R=Me, (tmps); Et, (teps); nPr, (tpps); nBu, (tbps); Ph, (tPhps)] have been prepared from the addition of tetraalkyl (phenyl)diphosphine disulfide to [(η3- CH2CMeCH2)Pd(μ-Cl)]2. All the complexes have been characterized by elemental analysis, Fourier-transform infrared (FT-IR), nuclear magnetic resonance (1H-NMR and 31P-{ 1H}-NMR) spectroscopy, and fast atom bombardment (FAB) mass spectrometry. The spectroscopic studies suggest that ligands are cis-chelate bidentate coordination, forming five-membered Pd-S=P-P=S palladacycles, with the η3-allyl group completing the coordination sphere.

KW - allyl complexes

KW - diphosphinedisulfide

KW - palladium complexes

KW - synthesis

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U2 - 10.1080/15533174.2011.591311

DO - 10.1080/15533174.2011.591311

M3 - Article

AN - SCOPUS:80051739537

SN - 1553-3174

VL - 41

SP - 834

EP - 838

JO - Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry

JF - Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry

IS - 7

ER -

Synthesis and characterization of η³-Allyl palladium(II) complexes with tetraalkyldiphosphine disulfides, R₂P(S)P(S)R ₂ (R=Me, Et, ⁿPr, ⁿBu, Ph)

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