Synthesis and Characterisation of Unsymmetrical Porphyrazines Containing Bis(hydroxyethylthio) Substituents

Ayfer Kalkan; Zehra A. Bayir

doi:10.1007/s00706-003-0074-5

Synthesis and Characterisation of Unsymmetrical Porphyrazines Containing Bis(hydroxyethylthio) Substituents

Ayfer Kalkan, Zehra A. Bayir^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

Unsymmetrical porphyrazines bearing a single peripheral bis(hydroxyethylthio) moiety were synthesised by mixed condensation of bis(2-hydroxyethylthio)maleonitrile and phthalonitrile. Complexation of the thioether groups of metal-free porphyrazine with PdCl₂ further lowered the intensity of the Q-band absorption of the porphyrazine core. The new compounds were characterised by elemental analyses, IR, ¹H NMR, UV-Vis, and mass spectra.

Original language	English
Pages (from-to)	1555-1560
Number of pages	6
Journal	Monatshefte fur Chemie
Volume	134
Issue number	12
DOIs	https://doi.org/10.1007/s00706-003-0074-5
Publication status	Published - Dec 2003

Keywords

Complex
Palladium
Phthalocyanine
Porphyrazine

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10.1007/s00706-003-0074-5

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title = "Synthesis and Characterisation of Unsymmetrical Porphyrazines Containing Bis(hydroxyethylthio) Substituents",

abstract = "Unsymmetrical porphyrazines bearing a single peripheral bis(hydroxyethylthio) moiety were synthesised by mixed condensation of bis(2-hydroxyethylthio)maleonitrile and phthalonitrile. Complexation of the thioether groups of metal-free porphyrazine with PdCl2 further lowered the intensity of the Q-band absorption of the porphyrazine core. The new compounds were characterised by elemental analyses, IR, 1H NMR, UV-Vis, and mass spectra.",

keywords = "Complex, Palladium, Phthalocyanine, Porphyrazine",

author = "Ayfer Kalkan and Bayir, \{Zehra A.\}",

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AU - Kalkan, Ayfer

AU - Bayir, Zehra A.

PY - 2003/12

Y1 - 2003/12

N2 - Unsymmetrical porphyrazines bearing a single peripheral bis(hydroxyethylthio) moiety were synthesised by mixed condensation of bis(2-hydroxyethylthio)maleonitrile and phthalonitrile. Complexation of the thioether groups of metal-free porphyrazine with PdCl2 further lowered the intensity of the Q-band absorption of the porphyrazine core. The new compounds were characterised by elemental analyses, IR, 1H NMR, UV-Vis, and mass spectra.

AB - Unsymmetrical porphyrazines bearing a single peripheral bis(hydroxyethylthio) moiety were synthesised by mixed condensation of bis(2-hydroxyethylthio)maleonitrile and phthalonitrile. Complexation of the thioether groups of metal-free porphyrazine with PdCl2 further lowered the intensity of the Q-band absorption of the porphyrazine core. The new compounds were characterised by elemental analyses, IR, 1H NMR, UV-Vis, and mass spectra.

KW - Complex

KW - Palladium

KW - Phthalocyanine

KW - Porphyrazine

UR - https://www.scopus.com/pages/publications/0346888761

U2 - 10.1007/s00706-003-0074-5

DO - 10.1007/s00706-003-0074-5

M3 - Article

AN - SCOPUS:0346888761

SN - 0026-9247

VL - 134

SP - 1555

EP - 1560

JO - Monatshefte fur Chemie

JF - Monatshefte fur Chemie

IS - 12

ER -

Synthesis and Characterisation of Unsymmetrical Porphyrazines Containing Bis(hydroxyethylthio) Substituents

Abstract

Keywords

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