Synthesis and Characterisation of Unsymmetrical Porphyrazines Containing Bis(hydroxyethylthio) Substituents

Ayfer Kalkan; Zehra A. Bayir

doi:10.1007/s00706-003-0074-5

Synthesis and Characterisation of Unsymmetrical Porphyrazines Containing Bis(hydroxyethylthio) Substituents

Ayfer Kalkan, Zehra A. Bayir^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

Unsymmetrical porphyrazines bearing a single peripheral bis(hydroxyethylthio) moiety were synthesised by mixed condensation of bis(2-hydroxyethylthio)maleonitrile and phthalonitrile. Complexation of the thioether groups of metal-free porphyrazine with PdCl₂ further lowered the intensity of the Q-band absorption of the porphyrazine core. The new compounds were characterised by elemental analyses, IR, ¹H NMR, UV-Vis, and mass spectra.

Original language	English
Pages (from-to)	1555-1560
Number of pages	6
Journal	Monatshefte fur Chemie
Volume	134
Issue number	12
DOIs	https://doi.org/10.1007/s00706-003-0074-5
Publication status	Published - Dec 2003

Keywords

Complex
Palladium
Phthalocyanine
Porphyrazine

Access to Document

10.1007/s00706-003-0074-5

Cite this

@article{00d5d05ef3e14b9ab0937f65e38ed521,

title = "Synthesis and Characterisation of Unsymmetrical Porphyrazines Containing Bis(hydroxyethylthio) Substituents",

abstract = "Unsymmetrical porphyrazines bearing a single peripheral bis(hydroxyethylthio) moiety were synthesised by mixed condensation of bis(2-hydroxyethylthio)maleonitrile and phthalonitrile. Complexation of the thioether groups of metal-free porphyrazine with PdCl2 further lowered the intensity of the Q-band absorption of the porphyrazine core. The new compounds were characterised by elemental analyses, IR, 1H NMR, UV-Vis, and mass spectra.",

keywords = "Complex, Palladium, Phthalocyanine, Porphyrazine",

author = "Ayfer Kalkan and Bayir, {Zehra A.}",

year = "2003",

month = dec,

doi = "10.1007/s00706-003-0074-5",

language = "English",

volume = "134",

pages = "1555--1560",

journal = "Monatshefte fur Chemie",

issn = "0026-9247",

publisher = "Springer-Verlag Wien",

number = "12",

}

TY - JOUR

T1 - Synthesis and Characterisation of Unsymmetrical Porphyrazines Containing Bis(hydroxyethylthio) Substituents

AU - Kalkan, Ayfer

AU - Bayir, Zehra A.

PY - 2003/12

Y1 - 2003/12

N2 - Unsymmetrical porphyrazines bearing a single peripheral bis(hydroxyethylthio) moiety were synthesised by mixed condensation of bis(2-hydroxyethylthio)maleonitrile and phthalonitrile. Complexation of the thioether groups of metal-free porphyrazine with PdCl2 further lowered the intensity of the Q-band absorption of the porphyrazine core. The new compounds were characterised by elemental analyses, IR, 1H NMR, UV-Vis, and mass spectra.

AB - Unsymmetrical porphyrazines bearing a single peripheral bis(hydroxyethylthio) moiety were synthesised by mixed condensation of bis(2-hydroxyethylthio)maleonitrile and phthalonitrile. Complexation of the thioether groups of metal-free porphyrazine with PdCl2 further lowered the intensity of the Q-band absorption of the porphyrazine core. The new compounds were characterised by elemental analyses, IR, 1H NMR, UV-Vis, and mass spectra.

KW - Complex

KW - Palladium

KW - Phthalocyanine

KW - Porphyrazine

UR - http://www.scopus.com/inward/record.url?scp=0346888761&partnerID=8YFLogxK

U2 - 10.1007/s00706-003-0074-5

DO - 10.1007/s00706-003-0074-5

M3 - Article

AN - SCOPUS:0346888761

SN - 0026-9247

VL - 134

SP - 1555

EP - 1560

JO - Monatshefte fur Chemie

JF - Monatshefte fur Chemie

IS - 12

ER -

Synthesis and Characterisation of Unsymmetrical Porphyrazines Containing Bis(hydroxyethylthio) Substituents

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this