Surfactant-modified montmorillonite as a nanosized adsorbent for removal of an insecticide: Kinetic and isotherm studies

Aydin Hassani; Alireza Khataee; Semra Karaca; Mehdi Shirzad-Siboni

doi:10.1080/09593330.2015.1054319

Surfactant-modified montmorillonite as a nanosized adsorbent for removal of an insecticide: Kinetic and isotherm studies

Aydin Hassani, Alireza Khataee^*, Semra Karaca, Mehdi Shirzad-Siboni

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

43 Citations (Scopus)

Abstract

Surfactant-modified montmorillonites (MMT) were prepared using trimethyloctylammonium bromide (TMOAB) and employed as a nanosized adsorbent to remove diazinon from aqueous solutions. The prepared adsorbent was characterized using Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy-dispersive X-ray (EDX). The dependence of removal efficiency on initial diazinon concentration, amount of adsorbent, pH of the solution and ionic strength was investigated. The affinity sequence for ion adsorption on TMOAB/MMT was in the order: without anion> sodium carbonate> sodium bicarbonate> sodium sulphate> sodium chloride. The adsorption kinetic and isotherm were best fit by a pseudo-second-order kinetic and Langmuir isotherm models, respectively.

Original language	English
Pages (from-to)	3125-3135
Number of pages	11
Journal	Environmental Technology (United Kingdom)
Volume	36
Issue number	24
DOIs	https://doi.org/10.1080/09593330.2015.1054319
Publication status	Published - 17 Dec 2015
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2015 Taylor & Francis.

Keywords

adsorption
diazinon
modified clay
montmorillonite
nanoclay

Access to Document

10.1080/09593330.2015.1054319

Cite this

@article{fc14235c36334b35a03ac6a55e831c3f,

title = "Surfactant-modified montmorillonite as a nanosized adsorbent for removal of an insecticide: Kinetic and isotherm studies",

abstract = "Surfactant-modified montmorillonites (MMT) were prepared using trimethyloctylammonium bromide (TMOAB) and employed as a nanosized adsorbent to remove diazinon from aqueous solutions. The prepared adsorbent was characterized using Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy-dispersive X-ray (EDX). The dependence of removal efficiency on initial diazinon concentration, amount of adsorbent, pH of the solution and ionic strength was investigated. The affinity sequence for ion adsorption on TMOAB/MMT was in the order: without anion> sodium carbonate> sodium bicarbonate> sodium sulphate> sodium chloride. The adsorption kinetic and isotherm were best fit by a pseudo-second-order kinetic and Langmuir isotherm models, respectively.",

keywords = "adsorption, diazinon, modified clay, montmorillonite, nanoclay",

author = "Aydin Hassani and Alireza Khataee and Semra Karaca and Mehdi Shirzad-Siboni",

note = "Publisher Copyright: {\textcopyright} 2015 Taylor & Francis.",

year = "2015",

month = dec,

day = "17",

doi = "10.1080/09593330.2015.1054319",

language = "English",

volume = "36",

pages = "3125--3135",

journal = "Environmental Technology (United Kingdom)",

issn = "0959-3330",

publisher = "Taylor and Francis Ltd.",

number = "24",

}

TY - JOUR

T1 - Surfactant-modified montmorillonite as a nanosized adsorbent for removal of an insecticide

T2 - Kinetic and isotherm studies

AU - Hassani, Aydin

AU - Khataee, Alireza

AU - Karaca, Semra

AU - Shirzad-Siboni, Mehdi

PY - 2015/12/17

Y1 - 2015/12/17

N2 - Surfactant-modified montmorillonites (MMT) were prepared using trimethyloctylammonium bromide (TMOAB) and employed as a nanosized adsorbent to remove diazinon from aqueous solutions. The prepared adsorbent was characterized using Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy-dispersive X-ray (EDX). The dependence of removal efficiency on initial diazinon concentration, amount of adsorbent, pH of the solution and ionic strength was investigated. The affinity sequence for ion adsorption on TMOAB/MMT was in the order: without anion> sodium carbonate> sodium bicarbonate> sodium sulphate> sodium chloride. The adsorption kinetic and isotherm were best fit by a pseudo-second-order kinetic and Langmuir isotherm models, respectively.

AB - Surfactant-modified montmorillonites (MMT) were prepared using trimethyloctylammonium bromide (TMOAB) and employed as a nanosized adsorbent to remove diazinon from aqueous solutions. The prepared adsorbent was characterized using Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy-dispersive X-ray (EDX). The dependence of removal efficiency on initial diazinon concentration, amount of adsorbent, pH of the solution and ionic strength was investigated. The affinity sequence for ion adsorption on TMOAB/MMT was in the order: without anion> sodium carbonate> sodium bicarbonate> sodium sulphate> sodium chloride. The adsorption kinetic and isotherm were best fit by a pseudo-second-order kinetic and Langmuir isotherm models, respectively.

KW - adsorption

KW - diazinon

KW - modified clay

KW - montmorillonite

KW - nanoclay

UR - http://www.scopus.com/inward/record.url?scp=84946494532&partnerID=8YFLogxK

U2 - 10.1080/09593330.2015.1054319

DO - 10.1080/09593330.2015.1054319

M3 - Article

C2 - 26006742

AN - SCOPUS:84946494532

SN - 0959-3330

VL - 36

SP - 3125

EP - 3135

JO - Environmental Technology (United Kingdom)

JF - Environmental Technology (United Kingdom)

IS - 24

ER -

Surfactant-modified montmorillonite as a nanosized adsorbent for removal of an insecticide: Kinetic and isotherm studies

Abstract

Bibliographical note

Keywords

Access to Document

Other files and links

Fingerprint

Cite this