Styrenation of triglyceride oils by macromonomer technique

F. S. Güner; S. Usta; A. T. Erciyes; Y. Yagci

doi:10.1007/bf02698030

Styrenation of triglyceride oils by macromonomer technique

F. S. Güner^*, S. Usta, A. T. Erciyes, Y. Yagci

^*Corresponding author for this work

Department of Chemical Engineering

Istanbul Technical University

Research output: Contribution to journal › Article › peer-review

32 Citations (Scopus)

Abstract

A novel macromer technique is described for the styrenation of triglyceride oils. Triglyceride oil-based macromers were prepared via successive transesterification and condensation reactions. The macromers were styrenated at 100 °C using benzoyl peroxide as an initiator. The styrenation led to improved film properties with semidrying oils. Homopolymerization of the macromonomers failed due to the stearic hindrance of the bulky oil moieties. The results obtained were also evaluated by considering the degree of unsaturation.

Original language	English
Pages (from-to)	107-110
Number of pages	4
Journal	Journal of Coatings Technology
Volume	72
Issue number	907
DOIs	https://doi.org/10.1007/bf02698030
Publication status	Published - Aug 2000

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abstract = "A novel macromer technique is described for the styrenation of triglyceride oils. Triglyceride oil-based macromers were prepared via successive transesterification and condensation reactions. The macromers were styrenated at 100 °C using benzoyl peroxide as an initiator. The styrenation led to improved film properties with semidrying oils. Homopolymerization of the macromonomers failed due to the stearic hindrance of the bulky oil moieties. The results obtained were also evaluated by considering the degree of unsaturation.",

author = "G{\"u}ner, {F. S.} and S. Usta and Erciyes, {A. T.} and Y. Yagci",

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AU - Erciyes, A. T.

AU - Yagci, Y.

PY - 2000/8

Y1 - 2000/8

N2 - A novel macromer technique is described for the styrenation of triglyceride oils. Triglyceride oil-based macromers were prepared via successive transesterification and condensation reactions. The macromers were styrenated at 100 °C using benzoyl peroxide as an initiator. The styrenation led to improved film properties with semidrying oils. Homopolymerization of the macromonomers failed due to the stearic hindrance of the bulky oil moieties. The results obtained were also evaluated by considering the degree of unsaturation.

AB - A novel macromer technique is described for the styrenation of triglyceride oils. Triglyceride oil-based macromers were prepared via successive transesterification and condensation reactions. The macromers were styrenated at 100 °C using benzoyl peroxide as an initiator. The styrenation led to improved film properties with semidrying oils. Homopolymerization of the macromonomers failed due to the stearic hindrance of the bulky oil moieties. The results obtained were also evaluated by considering the degree of unsaturation.

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Styrenation of triglyceride oils by macromonomer technique

Abstract

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