Study of the behaviour of thorium adsorption on PAN/zeolite composite adsorbent

A. Kilincarslan Kaygun; S. Akyil

doi:10.1016/j.jhazmat.2007.01.020

Study of the behaviour of thorium adsorption on PAN/zeolite composite adsorbent

A. Kilincarslan Kaygun, S. Akyil^*

^*Corresponding author for this work

Ege University

Research output: Contribution to journal › Article › peer-review

127 Citations (Scopus)

Abstract

The adsorption behaviour of thorium from aqueous solutions by a composite adsorbent has been investigated by a batch technique. The thorium adsorption on composite adsorbent was studied as a function of initial concentration, pH, shaking time and temperature. The sorption of thorium at the determined optimum conditions follows Langmuir, Freundlich and D-R type isotherms. Langmuir constants Q = 0.04 mmol g^-1 and b = 64.94 L mol^-1 and of D-R parameter X_m = 0.04, β = 0.79 and of sorption energy E = 0.80 and Freundlich constants 1/n = 3.12 and c_m = 0.012 mmol g^-1 were evaluated. Thermodynamic parameters such as ΔH and ΔS were found to be 37.32 kJ mol^-1 and 206.17 J mol^-1 K^-1, respectively.

Original language	English
Pages (from-to)	357-362
Number of pages	6
Journal	Journal of Hazardous Materials
Volume	147
Issue number	1-2
DOIs	https://doi.org/10.1016/j.jhazmat.2007.01.020
Publication status	Published - 17 Aug 2007
Externally published	Yes

Keywords

Composite adsorbent
Desorption
Sorption
Thermodynamic parameters
Thorium

Access to Document

10.1016/j.jhazmat.2007.01.020

Cite this

@article{0905cc266a264f608579ba3347b97b77,

title = "Study of the behaviour of thorium adsorption on PAN/zeolite composite adsorbent",

abstract = "The adsorption behaviour of thorium from aqueous solutions by a composite adsorbent has been investigated by a batch technique. The thorium adsorption on composite adsorbent was studied as a function of initial concentration, pH, shaking time and temperature. The sorption of thorium at the determined optimum conditions follows Langmuir, Freundlich and D-R type isotherms. Langmuir constants Q = 0.04 mmol g-1 and b = 64.94 L mol-1 and of D-R parameter Xm = 0.04, β = 0.79 and of sorption energy E = 0.80 and Freundlich constants 1/n = 3.12 and cm = 0.012 mmol g-1 were evaluated. Thermodynamic parameters such as ΔH and ΔS were found to be 37.32 kJ mol-1 and 206.17 J mol-1 K-1, respectively.",

keywords = "Composite adsorbent, Desorption, Sorption, Thermodynamic parameters, Thorium",

author = "Kaygun, {A. Kilincarslan} and S. Akyil",

year = "2007",

month = aug,

day = "17",

doi = "10.1016/j.jhazmat.2007.01.020",

language = "English",

volume = "147",

pages = "357--362",

journal = "Journal of Hazardous Materials",

issn = "0304-3894",

publisher = "Elsevier B.V.",

number = "1-2",

}

TY - JOUR

T1 - Study of the behaviour of thorium adsorption on PAN/zeolite composite adsorbent

AU - Kaygun, A. Kilincarslan

AU - Akyil, S.

PY - 2007/8/17

Y1 - 2007/8/17

N2 - The adsorption behaviour of thorium from aqueous solutions by a composite adsorbent has been investigated by a batch technique. The thorium adsorption on composite adsorbent was studied as a function of initial concentration, pH, shaking time and temperature. The sorption of thorium at the determined optimum conditions follows Langmuir, Freundlich and D-R type isotherms. Langmuir constants Q = 0.04 mmol g-1 and b = 64.94 L mol-1 and of D-R parameter Xm = 0.04, β = 0.79 and of sorption energy E = 0.80 and Freundlich constants 1/n = 3.12 and cm = 0.012 mmol g-1 were evaluated. Thermodynamic parameters such as ΔH and ΔS were found to be 37.32 kJ mol-1 and 206.17 J mol-1 K-1, respectively.

AB - The adsorption behaviour of thorium from aqueous solutions by a composite adsorbent has been investigated by a batch technique. The thorium adsorption on composite adsorbent was studied as a function of initial concentration, pH, shaking time and temperature. The sorption of thorium at the determined optimum conditions follows Langmuir, Freundlich and D-R type isotherms. Langmuir constants Q = 0.04 mmol g-1 and b = 64.94 L mol-1 and of D-R parameter Xm = 0.04, β = 0.79 and of sorption energy E = 0.80 and Freundlich constants 1/n = 3.12 and cm = 0.012 mmol g-1 were evaluated. Thermodynamic parameters such as ΔH and ΔS were found to be 37.32 kJ mol-1 and 206.17 J mol-1 K-1, respectively.

KW - Composite adsorbent

KW - Desorption

KW - Sorption

KW - Thermodynamic parameters

KW - Thorium

UR - http://www.scopus.com/inward/record.url?scp=34447623001&partnerID=8YFLogxK

U2 - 10.1016/j.jhazmat.2007.01.020

DO - 10.1016/j.jhazmat.2007.01.020

M3 - Article

C2 - 17292544

AN - SCOPUS:34447623001

SN - 0304-3894

VL - 147

SP - 357

EP - 362

JO - Journal of Hazardous Materials

JF - Journal of Hazardous Materials

IS - 1-2

ER -

Study of the behaviour of thorium adsorption on PAN/zeolite composite adsorbent

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this