TY - JOUR
T1 - Studies on the block copolymerization of methacrylonitrile and hexafluorobutylmethacrlate using phenylazotriphenylmethane as thermal iniferter
AU - Acar, Metin H.
AU - Yağci, Yusuf
PY - 1991
Y1 - 1991
N2 - The iniferter technique was applied to synthesize a block copolymer of methacrylonitrile (MAN) and 2,3,3,4,4, 4- hexafluorobutylmethacrylate (HFMA). Phenylazotriphenyl methane (PAT) was used as initiator for thermally initiated polymerization which proceeded via quasi-living radical mechanism. This was informed from the fact that yield and molecular weight (Mn) of the polymers increased with reaction time. The prepolymer obtained from one monomer was used as polymeric iniferter for the polymerization of the other monomer.This way block copolymers were obtained.
AB - The iniferter technique was applied to synthesize a block copolymer of methacrylonitrile (MAN) and 2,3,3,4,4, 4- hexafluorobutylmethacrylate (HFMA). Phenylazotriphenyl methane (PAT) was used as initiator for thermally initiated polymerization which proceeded via quasi-living radical mechanism. This was informed from the fact that yield and molecular weight (Mn) of the polymers increased with reaction time. The prepolymer obtained from one monomer was used as polymeric iniferter for the polymerization of the other monomer.This way block copolymers were obtained.
UR - http://www.scopus.com/inward/record.url?scp=0026173849&partnerID=8YFLogxK
U2 - 10.1080/00222339108054398
DO - 10.1080/00222339108054398
M3 - Article
AN - SCOPUS:0026173849
SN - 0022-233X
VL - 28
SP - 177
EP - 183
JO - Journal of Macromolecular Science - Pure and Applied Chemistry
JF - Journal of Macromolecular Science - Pure and Applied Chemistry
IS - sup2
ER -