TY - JOUR
T1 - Structural, electrical, and electromagnetic properties of cotton fabrics coated with polyaniline and polypyrrole
AU - Onar, Nurhan
AU - Akşit, Aysun Cireli
AU - Ebeoglugil, M. Faruk
AU - Birlik, Isil
AU - Celik, Erdal
AU - Ozdemir, Ismail
PY - 2009/11/15
Y1 - 2009/11/15
N2 - In this study, the structural, electrical, and electromagnetic properties of cotton fabrics coated with polyaniline (PAni) and polypyrrole (PPy) were investigated and compared. For the aims, anilin and pyrrole were used as monomers, and in situ polymerization on cotton fabric by chemical oxidative polymerization was performed. After production, the structural properties of the fabrics were determined with Fourier transform infrared spectroscopy and X-ray diffraction. In addition, ultraviolet (UV) permeability, tensile strength, colorfastness, and electrical and electromagnetic measurements of the fabric samples were carried out. The resistance values of the cotton fabrics coated with PAni and PPy were found to be 350 and 512 ω, respectively. The average electromagnetic shielding efficiency and average absorption values of the cotton fabrics coated with PAni were determined to be 3.8 dB and 48%, respectively, and these values for the cotton fabrics coated with PPy were 6 dB and 50%, respectively. Consequently, a significant difference was not observed between the resistance values and electromagnetic parameters of the fabrics coated with PAni and PPy, although the intact textile characteristics of the fabric coated with PPy were protected and improved, whereas the characteristics of the fabric coated with PAni were inferior. Moreover, we first report that the fabrics coated with conductive polymers had excellent UV-protection properties.
AB - In this study, the structural, electrical, and electromagnetic properties of cotton fabrics coated with polyaniline (PAni) and polypyrrole (PPy) were investigated and compared. For the aims, anilin and pyrrole were used as monomers, and in situ polymerization on cotton fabric by chemical oxidative polymerization was performed. After production, the structural properties of the fabrics were determined with Fourier transform infrared spectroscopy and X-ray diffraction. In addition, ultraviolet (UV) permeability, tensile strength, colorfastness, and electrical and electromagnetic measurements of the fabric samples were carried out. The resistance values of the cotton fabrics coated with PAni and PPy were found to be 350 and 512 ω, respectively. The average electromagnetic shielding efficiency and average absorption values of the cotton fabrics coated with PAni were determined to be 3.8 dB and 48%, respectively, and these values for the cotton fabrics coated with PPy were 6 dB and 50%, respectively. Consequently, a significant difference was not observed between the resistance values and electromagnetic parameters of the fabrics coated with PAni and PPy, although the intact textile characteristics of the fabric coated with PPy were protected and improved, whereas the characteristics of the fabric coated with PAni were inferior. Moreover, we first report that the fabrics coated with conductive polymers had excellent UV-protection properties.
KW - Coatings
KW - Conducting polymers
KW - FT-IR
UR - http://www.scopus.com/inward/record.url?scp=69949110783&partnerID=8YFLogxK
U2 - 10.1002/app.30652
DO - 10.1002/app.30652
M3 - Article
AN - SCOPUS:69949110783
SN - 0021-8995
VL - 114
SP - 2003
EP - 2010
JO - Journal of Applied Polymer Science
JF - Journal of Applied Polymer Science
IS - 4
ER -