Statistical group transfer copolymerization. Monomer reactivity ratios for allyl methacrylate and n-butyl methacrylate

H. Çatalgil-Giz; N. Uyanik; C. Erbil

doi:10.1016/0032-3861(92)90747-K

Statistical group transfer copolymerization. Monomer reactivity ratios for allyl methacrylate and n-butyl methacrylate

H. Çatalgil-Giz^*, N. Uyanik, C. Erbil

^*Corresponding author for this work

Department of Chemistry

Istanbul Technical University

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

Statistical copolymerizations have been performed for allyl methacrylate-butyl methacrylate systems using 1-methoxy-2-methyl-1-trimethylsilyloxypropene (initiator) and tris (dimethylamino) sulphonium bifluoride (catalyst) in tetrahydrofuran solution. Soluble allyl copolymers have been obtained by this method. The copolymer compositions were determined by ultraviolet spectroscopy and the results evaluated by the Kelen-Tüdos and Fineman-Ross methods. The reactivity ratios were found to be r_AMA = 2.35, r_BMA = 0.08 (Kelen-Tüdos) and r_AMA = 2.37, r_BMA = 0.08 (Fineman-Ross).

Original language	English
Pages (from-to)	655-656
Number of pages	2
Journal	Polymer
Volume	33
Issue number	3
DOIs	https://doi.org/10.1016/0032-3861(92)90747-K
Publication status	Published - 1992

Keywords

Fineman-Ross method
group transfer polymerization
Kelen-Tüdos method
reactivity ratio
statistical copolymerization

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10.1016/0032-3861(92)90747-K

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@article{98d69686d9d84c00a39c15e1ad34b241,

title = "Statistical group transfer copolymerization. Monomer reactivity ratios for allyl methacrylate and n-butyl methacrylate",

abstract = "Statistical copolymerizations have been performed for allyl methacrylate-butyl methacrylate systems using 1-methoxy-2-methyl-1-trimethylsilyloxypropene (initiator) and tris (dimethylamino) sulphonium bifluoride (catalyst) in tetrahydrofuran solution. Soluble allyl copolymers have been obtained by this method. The copolymer compositions were determined by ultraviolet spectroscopy and the results evaluated by the Kelen-T{\"u}dos and Fineman-Ross methods. The reactivity ratios were found to be rAMA = 2.35, rBMA = 0.08 (Kelen-T{\"u}dos) and rAMA = 2.37, rBMA = 0.08 (Fineman-Ross).",

keywords = "Fineman-Ross method, group transfer polymerization, Kelen-T{\"u}dos method, reactivity ratio, statistical copolymerization",

author = "H. {\c C}atalgil-Giz and N. Uyanik and C. Erbil",

year = "1992",

doi = "10.1016/0032-3861(92)90747-K",

language = "English",

volume = "33",

pages = "655--656",

journal = "Polymer",

issn = "0032-3861",

publisher = "Elsevier B.V.",

number = "3",

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TY - JOUR

T1 - Statistical group transfer copolymerization. Monomer reactivity ratios for allyl methacrylate and n-butyl methacrylate

AU - Çatalgil-Giz, H.

AU - Uyanik, N.

AU - Erbil, C.

PY - 1992

Y1 - 1992

N2 - Statistical copolymerizations have been performed for allyl methacrylate-butyl methacrylate systems using 1-methoxy-2-methyl-1-trimethylsilyloxypropene (initiator) and tris (dimethylamino) sulphonium bifluoride (catalyst) in tetrahydrofuran solution. Soluble allyl copolymers have been obtained by this method. The copolymer compositions were determined by ultraviolet spectroscopy and the results evaluated by the Kelen-Tüdos and Fineman-Ross methods. The reactivity ratios were found to be rAMA = 2.35, rBMA = 0.08 (Kelen-Tüdos) and rAMA = 2.37, rBMA = 0.08 (Fineman-Ross).

AB - Statistical copolymerizations have been performed for allyl methacrylate-butyl methacrylate systems using 1-methoxy-2-methyl-1-trimethylsilyloxypropene (initiator) and tris (dimethylamino) sulphonium bifluoride (catalyst) in tetrahydrofuran solution. Soluble allyl copolymers have been obtained by this method. The copolymer compositions were determined by ultraviolet spectroscopy and the results evaluated by the Kelen-Tüdos and Fineman-Ross methods. The reactivity ratios were found to be rAMA = 2.35, rBMA = 0.08 (Kelen-Tüdos) and rAMA = 2.37, rBMA = 0.08 (Fineman-Ross).

KW - Fineman-Ross method

KW - group transfer polymerization

KW - Kelen-Tüdos method

KW - reactivity ratio

KW - statistical copolymerization

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U2 - 10.1016/0032-3861(92)90747-K

DO - 10.1016/0032-3861(92)90747-K

M3 - Article

AN - SCOPUS:0042172153

SN - 0032-3861

VL - 33

SP - 655

EP - 656

JO - Polymer

JF - Polymer

IS - 3

ER -

Statistical group transfer copolymerization. Monomer reactivity ratios for allyl methacrylate and n-butyl methacrylate

Abstract

Keywords

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