Spectroscopic and electrochemical studies of transition metal complexes with N,N′-bis(2-aminothiophenol)-1,7-bis(2-formylphenyl)-1,4,7- trioxaheptane and structure effects on extractability of ligand towards some divalent cations

Hamdi Temel; Hüseyin Alp; Salih Ilhan; Berrin ZiyadanoǧullarI; Ismail YIlmaz

doi:10.1007/s00706-007-0713-3

Spectroscopic and electrochemical studies of transition metal complexes with N,N′-bis(2-aminothiophenol)-1,7-bis(2-formylphenyl)-1,4,7- trioxaheptane and structure effects on extractability of ligand towards some divalent cations

Hamdi Temel^*, Hüseyin Alp, Salih Ilhan, Berrin ZiyadanoǧullarI, Ismail YIlmaz

^*Corresponding author for this work

Department of Chemistry

Dicle University

Research output: Contribution to journal › Article › peer-review

34 Citations (Scopus)

Abstract

La(III), Cu(II), Ni(II), and Zn(II) metal complexes with a novel quadridentate Schiff base derived from 1,7-bis(2-formylphenyl)-1,4,7- trioxaheptane and 2-aminothiophenol were synthesized and characterized by microanalytical data, elemental analysis, magnetic measurements, ¹H NMR, ¹³C NMR, UV-Vis, IR, mass spectra, cyclic voltammetric and conductance measurements. The extractability of divalent cations was evaluated as a function of relationship between distribution ratio of the metal and pH or ligand concentration. The highest extraction percentage of Cu²⁺ and Ni²⁺ showed pH 7.0 and 6.4. It was concluded that the ligand can effectively be used in solvent extraction of copper(II) and nickel(II) from the aqueous phase to the organic phase.

Original language	English
Pages (from-to)	1199-1209
Number of pages	11
Journal	Monatshefte fur Chemie
Volume	138
Issue number	12
DOIs	https://doi.org/10.1007/s00706-007-0713-3
Publication status	Published - Dec 2007

Keywords

Electrochemical studies
Extraction
Thio Schiff base
Transition metal complexes

Access to Document

10.1007/s00706-007-0713-3

Fingerprint

Dive into the research topics of 'Spectroscopic and electrochemical studies of transition metal complexes with N,N′-bis(2-aminothiophenol)-1,7-bis(2-formylphenyl)-1,4,7- trioxaheptane and structure effects on extractability of ligand towards some divalent cations'. Together they form a unique fingerprint.

Cite this

Temel, H., Alp, H., Ilhan, S., ZiyadanoǧullarI, B., & YIlmaz, I. (2007). Spectroscopic and electrochemical studies of transition metal complexes with N,N′-bis(2-aminothiophenol)-1,7-bis(2-formylphenyl)-1,4,7- trioxaheptane and structure effects on extractability of ligand towards some divalent cations. Monatshefte fur Chemie, 138(12), 1199-1209. https://doi.org/10.1007/s00706-007-0713-3

@article{44f162e9357e4b27b63568f11750bc39,

title = "Spectroscopic and electrochemical studies of transition metal complexes with N,N′-bis(2-aminothiophenol)-1,7-bis(2-formylphenyl)-1,4,7- trioxaheptane and structure effects on extractability of ligand towards some divalent cations",

abstract = "La(III), Cu(II), Ni(II), and Zn(II) metal complexes with a novel quadridentate Schiff base derived from 1,7-bis(2-formylphenyl)-1,4,7- trioxaheptane and 2-aminothiophenol were synthesized and characterized by microanalytical data, elemental analysis, magnetic measurements, 1H NMR, 13C NMR, UV-Vis, IR, mass spectra, cyclic voltammetric and conductance measurements. The extractability of divalent cations was evaluated as a function of relationship between distribution ratio of the metal and pH or ligand concentration. The highest extraction percentage of Cu2+ and Ni2+ showed pH 7.0 and 6.4. It was concluded that the ligand can effectively be used in solvent extraction of copper(II) and nickel(II) from the aqueous phase to the organic phase.",

keywords = "Electrochemical studies, Extraction, Thio Schiff base, Transition metal complexes",

author = "Hamdi Temel and H{\"u}seyin Alp and Salih Ilhan and Berrin ZiyadanoǧullarI and Ismail YIlmaz",

year = "2007",

month = dec,

doi = "10.1007/s00706-007-0713-3",

language = "English",

volume = "138",

pages = "1199--1209",

journal = "Monatshefte fur Chemie",

issn = "0026-9247",

publisher = "Springer-Verlag Wien",

number = "12",

}

Temel, H, Alp, H, Ilhan, S, ZiyadanoǧullarI, B & YIlmaz, I 2007, 'Spectroscopic and electrochemical studies of transition metal complexes with N,N′-bis(2-aminothiophenol)-1,7-bis(2-formylphenyl)-1,4,7- trioxaheptane and structure effects on extractability of ligand towards some divalent cations', Monatshefte fur Chemie, vol. 138, no. 12, pp. 1199-1209. https://doi.org/10.1007/s00706-007-0713-3

Spectroscopic and electrochemical studies of transition metal complexes with N,N′-bis(2-aminothiophenol)-1,7-bis(2-formylphenyl)-1,4,7- trioxaheptane and structure effects on extractability of ligand towards some divalent cations. / Temel, Hamdi; Alp, Hüseyin; Ilhan, Salih et al.
In: Monatshefte fur Chemie, Vol. 138, No. 12, 12.2007, p. 1199-1209.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Spectroscopic and electrochemical studies of transition metal complexes with N,N′-bis(2-aminothiophenol)-1,7-bis(2-formylphenyl)-1,4,7- trioxaheptane and structure effects on extractability of ligand towards some divalent cations

AU - Temel, Hamdi

AU - Alp, Hüseyin

AU - Ilhan, Salih

AU - ZiyadanoǧullarI, Berrin

AU - YIlmaz, Ismail

PY - 2007/12

Y1 - 2007/12

N2 - La(III), Cu(II), Ni(II), and Zn(II) metal complexes with a novel quadridentate Schiff base derived from 1,7-bis(2-formylphenyl)-1,4,7- trioxaheptane and 2-aminothiophenol were synthesized and characterized by microanalytical data, elemental analysis, magnetic measurements, 1H NMR, 13C NMR, UV-Vis, IR, mass spectra, cyclic voltammetric and conductance measurements. The extractability of divalent cations was evaluated as a function of relationship between distribution ratio of the metal and pH or ligand concentration. The highest extraction percentage of Cu2+ and Ni2+ showed pH 7.0 and 6.4. It was concluded that the ligand can effectively be used in solvent extraction of copper(II) and nickel(II) from the aqueous phase to the organic phase.

AB - La(III), Cu(II), Ni(II), and Zn(II) metal complexes with a novel quadridentate Schiff base derived from 1,7-bis(2-formylphenyl)-1,4,7- trioxaheptane and 2-aminothiophenol were synthesized and characterized by microanalytical data, elemental analysis, magnetic measurements, 1H NMR, 13C NMR, UV-Vis, IR, mass spectra, cyclic voltammetric and conductance measurements. The extractability of divalent cations was evaluated as a function of relationship between distribution ratio of the metal and pH or ligand concentration. The highest extraction percentage of Cu2+ and Ni2+ showed pH 7.0 and 6.4. It was concluded that the ligand can effectively be used in solvent extraction of copper(II) and nickel(II) from the aqueous phase to the organic phase.

KW - Electrochemical studies

KW - Extraction

KW - Thio Schiff base

KW - Transition metal complexes

UR - http://www.scopus.com/inward/record.url?scp=36749079826&partnerID=8YFLogxK

U2 - 10.1007/s00706-007-0713-3

DO - 10.1007/s00706-007-0713-3

M3 - Article

AN - SCOPUS:36749079826

SN - 0026-9247

VL - 138

SP - 1199

EP - 1209

JO - Monatshefte fur Chemie

JF - Monatshefte fur Chemie

IS - 12

ER -

Temel H, Alp H, Ilhan S, ZiyadanoǧullarI B, YIlmaz I. Spectroscopic and electrochemical studies of transition metal complexes with N,N′-bis(2-aminothiophenol)-1,7-bis(2-formylphenyl)-1,4,7- trioxaheptane and structure effects on extractability of ligand towards some divalent cations. Monatshefte fur Chemie. 2007 Dec;138(12):1199-1209. doi: 10.1007/s00706-007-0713-3

Spectroscopic and electrochemical studies of transition metal complexes with N,N′-bis(2-aminothiophenol)-1,7-bis(2-formylphenyl)-1,4,7- trioxaheptane and structure effects on extractability of ligand towards some divalent cations

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this