Soluble and conductive copolymers from 1-(hydroxyalkyl) pyrroles

Bariş Kişkan; Ahmet Akar; Nilgün Kizilcan; Belkis Ustamehmetoǧlu

doi:10.1002/app.21069

Soluble and conductive copolymers from 1-(hydroxyalkyl) pyrroles

Bariş Kişkan, Ahmet Akar^*, Nilgün Kizilcan, Belkis Ustamehmetoǧlu

^*Corresponding author for this work

Department of Chemistry

Istanbul Technical University

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

1-Substituted pyrroles such as 1-(hydroxymethyl)pyrrole, 1-(3-hydroxypropyl) pyrrole, 1-H-1-pyrrolylmethyl 4-methyl-1-benzenesulfonate, 1-H-1-pyrrolyl-propyl 4-methyl-1-benzenesulfonate, and 1-H- pyrrolylmethyloctanoate were synthesized and oxidative polymerized and copolymerized with pyrrole by using (NH₄)₂Ce(NO ₃)₆ and FeCl₃. Some of the copolymers were slightly soluble in DMF and DMSO. The products were characterized by FTIR, ¹H-NMR, and four-point probe conductivity.

Original language	English
Pages (from-to)	1830-1834
Number of pages	5
Journal	Journal of Applied Polymer Science
Volume	96
Issue number	5
DOIs	https://doi.org/10.1002/app.21069
Publication status	Published - 5 Jun 2005

Keywords

1-hydroxyalkyl pyrrole
Conducting polymers
Soluble polypyrrole
Solution properties
Synthesis

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10.1002/app.21069

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title = "Soluble and conductive copolymers from 1-(hydroxyalkyl) pyrroles",

abstract = "1-Substituted pyrroles such as 1-(hydroxymethyl)pyrrole, 1-(3-hydroxypropyl) pyrrole, 1-H-1-pyrrolylmethyl 4-methyl-1-benzenesulfonate, 1-H-1-pyrrolyl-propyl 4-methyl-1-benzenesulfonate, and 1-H- pyrrolylmethyloctanoate were synthesized and oxidative polymerized and copolymerized with pyrrole by using (NH4)2Ce(NO 3)6 and FeCl3. Some of the copolymers were slightly soluble in DMF and DMSO. The products were characterized by FTIR, 1H-NMR, and four-point probe conductivity.",

keywords = "1-hydroxyalkyl pyrrole, Conducting polymers, Soluble polypyrrole, Solution properties, Synthesis",

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T1 - Soluble and conductive copolymers from 1-(hydroxyalkyl) pyrroles

AU - Kişkan, Bariş

AU - Akar, Ahmet

AU - Kizilcan, Nilgün

AU - Ustamehmetoǧlu, Belkis

PY - 2005/6/5

Y1 - 2005/6/5

N2 - 1-Substituted pyrroles such as 1-(hydroxymethyl)pyrrole, 1-(3-hydroxypropyl) pyrrole, 1-H-1-pyrrolylmethyl 4-methyl-1-benzenesulfonate, 1-H-1-pyrrolyl-propyl 4-methyl-1-benzenesulfonate, and 1-H- pyrrolylmethyloctanoate were synthesized and oxidative polymerized and copolymerized with pyrrole by using (NH4)2Ce(NO 3)6 and FeCl3. Some of the copolymers were slightly soluble in DMF and DMSO. The products were characterized by FTIR, 1H-NMR, and four-point probe conductivity.

AB - 1-Substituted pyrroles such as 1-(hydroxymethyl)pyrrole, 1-(3-hydroxypropyl) pyrrole, 1-H-1-pyrrolylmethyl 4-methyl-1-benzenesulfonate, 1-H-1-pyrrolyl-propyl 4-methyl-1-benzenesulfonate, and 1-H- pyrrolylmethyloctanoate were synthesized and oxidative polymerized and copolymerized with pyrrole by using (NH4)2Ce(NO 3)6 and FeCl3. Some of the copolymers were slightly soluble in DMF and DMSO. The products were characterized by FTIR, 1H-NMR, and four-point probe conductivity.

KW - 1-hydroxyalkyl pyrrole

KW - Conducting polymers

KW - Soluble polypyrrole

KW - Solution properties

KW - Synthesis

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U2 - 10.1002/app.21069

DO - 10.1002/app.21069

M3 - Article

AN - SCOPUS:19944423485

SN - 0021-8995

VL - 96

SP - 1830

EP - 1834

JO - Journal of Applied Polymer Science

JF - Journal of Applied Polymer Science

IS - 5

ER -

Soluble and conductive copolymers from 1-(hydroxyalkyl) pyrroles

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Keywords

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