Solid-State Supercapacitor Constructed with Organic Electrochromic Electrodes Based on Dithienothiophene and 3,4-Ethylenedioxythiophene

Sebahat Topal; Ilknur Demirtas; Erdal Ertas; Belkis Ustamehmetoglu; Esma Sezer; Turan Ozturk

doi:10.1021/acsaem.3c01851

Solid-State Supercapacitor Constructed with Organic Electrochromic Electrodes Based on Dithienothiophene and 3,4-Ethylenedioxythiophene

Sebahat Topal, Ilknur Demirtas, Erdal Ertas, Belkis Ustamehmetoglu, Esma Sezer^*, Turan Ozturk^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

Capacitive and electrochromic behaviors of electrodeposited poly{4,4′-[2,6-bis(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl) dithieno[3,2-b:2′,3′-d]thiophene-3,5-diyl] dibenzonitrile}, P[E-CNDTT-E], are reported. The morphological, structural, and electrochemical properties of the polymer are determined by atomic force microscopy, Fourier transform infrared, cyclic voltammetry, spectroelectrochemical measurements, electrochemical impedance spectroscopy, and galvanostatic charging/discharging measurements. Theoretical calculations support the planarity of the structure through O···S interactions, which allow the polymer to have a low band gap of 1.43 eV. P[E-CNDTT-E] has a high capacitance of 223 F g^-1 at the current density of 1 A g^-1 and displays a color change from purple to gray with an optical contrast of 30% and a coloration efficiency of 450 cm² C^-1 upon applying cathodic potential. The solid-state supercapacitor is constructed, which has a high specific capacitance of 63 F g^-1 and a significant energy density of 6.5 W h kg^-1. Additionally, the device retains 90% of its capacitance after 8000 cycles.

Original language	English
Pages (from-to)	11532-11540
Number of pages	9
Journal	ACS Applied Energy Materials
Volume	6
Issue number	22
DOIs	https://doi.org/10.1021/acsaem.3c01851
Publication status	Published - 27 Nov 2023

Bibliographical note

Publisher Copyright:
© 2023 American Chemical Society

Funding

We thank the Istanbul Technical University Scientific Research Projects Department (project number: 42325) for their support. We are indebted to the National Center for High Performance Computing (UHeM) (under grant number ) for the computational chemistry studies. We thank the Istanbul Technical University Scientific Research Projects Department (project number: 42325) for their support. We are indebted to the National Center for High Performance Computing (UHeM) (under grant number <4007702020>) for the computational chemistry studies.

Funders	Funder number
Istanbul Technical University Scientific Research Projects Department	42325
Ulusal Yüksek Başarımlı Hesaplama Merkezi, Istanbul Teknik Üniversitesi	<4007702020
Sheikh Bahaei National High Performance Computing Center, Isfahan University of Technology

Keywords

dithienothiophene
EDOT
electrochromic
energy storage
supercapacitor

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10.1021/acsaem.3c01851

Cite this

@article{46a93288b1dc428a933a078fa05b8b62,

title = "Solid-State Supercapacitor Constructed with Organic Electrochromic Electrodes Based on Dithienothiophene and 3,4-Ethylenedioxythiophene",

abstract = "Capacitive and electrochromic behaviors of electrodeposited poly\{4,4′-[2,6-bis(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl) dithieno[3,2-b:2′,3′-d]thiophene-3,5-diyl] dibenzonitrile\}, P[E-CNDTT-E], are reported. The morphological, structural, and electrochemical properties of the polymer are determined by atomic force microscopy, Fourier transform infrared, cyclic voltammetry, spectroelectrochemical measurements, electrochemical impedance spectroscopy, and galvanostatic charging/discharging measurements. Theoretical calculations support the planarity of the structure through O···S interactions, which allow the polymer to have a low band gap of 1.43 eV. P[E-CNDTT-E] has a high capacitance of 223 F g-1 at the current density of 1 A g-1 and displays a color change from purple to gray with an optical contrast of 30\% and a coloration efficiency of 450 cm2 C-1 upon applying cathodic potential. The solid-state supercapacitor is constructed, which has a high specific capacitance of 63 F g-1 and a significant energy density of 6.5 W h kg-1. Additionally, the device retains 90\% of its capacitance after 8000 cycles.",

keywords = "dithienothiophene, EDOT, electrochromic, energy storage, supercapacitor",

author = "Sebahat Topal and Ilknur Demirtas and Erdal Ertas and Belkis Ustamehmetoglu and Esma Sezer and Turan Ozturk",

note = "Publisher Copyright: {\textcopyright} 2023 American Chemical Society",

year = "2023",

month = nov,

day = "27",

doi = "10.1021/acsaem.3c01851",

language = "English",

volume = "6",

pages = "11532--11540",

journal = "ACS Applied Energy Materials",

issn = "2574-0962",

publisher = "American Chemical Society",

number = "22",

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T1 - Solid-State Supercapacitor Constructed with Organic Electrochromic Electrodes Based on Dithienothiophene and 3,4-Ethylenedioxythiophene

AU - Topal, Sebahat

AU - Demirtas, Ilknur

AU - Ertas, Erdal

AU - Ustamehmetoglu, Belkis

AU - Sezer, Esma

AU - Ozturk, Turan

PY - 2023/11/27

Y1 - 2023/11/27

N2 - Capacitive and electrochromic behaviors of electrodeposited poly{4,4′-[2,6-bis(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl) dithieno[3,2-b:2′,3′-d]thiophene-3,5-diyl] dibenzonitrile}, P[E-CNDTT-E], are reported. The morphological, structural, and electrochemical properties of the polymer are determined by atomic force microscopy, Fourier transform infrared, cyclic voltammetry, spectroelectrochemical measurements, electrochemical impedance spectroscopy, and galvanostatic charging/discharging measurements. Theoretical calculations support the planarity of the structure through O···S interactions, which allow the polymer to have a low band gap of 1.43 eV. P[E-CNDTT-E] has a high capacitance of 223 F g-1 at the current density of 1 A g-1 and displays a color change from purple to gray with an optical contrast of 30% and a coloration efficiency of 450 cm2 C-1 upon applying cathodic potential. The solid-state supercapacitor is constructed, which has a high specific capacitance of 63 F g-1 and a significant energy density of 6.5 W h kg-1. Additionally, the device retains 90% of its capacitance after 8000 cycles.

AB - Capacitive and electrochromic behaviors of electrodeposited poly{4,4′-[2,6-bis(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl) dithieno[3,2-b:2′,3′-d]thiophene-3,5-diyl] dibenzonitrile}, P[E-CNDTT-E], are reported. The morphological, structural, and electrochemical properties of the polymer are determined by atomic force microscopy, Fourier transform infrared, cyclic voltammetry, spectroelectrochemical measurements, electrochemical impedance spectroscopy, and galvanostatic charging/discharging measurements. Theoretical calculations support the planarity of the structure through O···S interactions, which allow the polymer to have a low band gap of 1.43 eV. P[E-CNDTT-E] has a high capacitance of 223 F g-1 at the current density of 1 A g-1 and displays a color change from purple to gray with an optical contrast of 30% and a coloration efficiency of 450 cm2 C-1 upon applying cathodic potential. The solid-state supercapacitor is constructed, which has a high specific capacitance of 63 F g-1 and a significant energy density of 6.5 W h kg-1. Additionally, the device retains 90% of its capacitance after 8000 cycles.

KW - dithienothiophene

KW - EDOT

KW - electrochromic

KW - energy storage

KW - supercapacitor

UR - https://www.scopus.com/pages/publications/85178154606

U2 - 10.1021/acsaem.3c01851

DO - 10.1021/acsaem.3c01851

M3 - Article

AN - SCOPUS:85178154606

SN - 2574-0962

VL - 6

SP - 11532

EP - 11540

JO - ACS Applied Energy Materials

JF - ACS Applied Energy Materials

IS - 22

ER -

Solid-State Supercapacitor Constructed with Organic Electrochromic Electrodes Based on Dithienothiophene and 3,4-Ethylenedioxythiophene

Abstract

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Keywords

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