Removal of nitrite ions from aqueous solutions by cross-linked polymer of ethylenediamine with epichlorohydrin

Niyazi Biçak*, Bahire Filiz Şenkal

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

21 Citations (Scopus)

Abstract

We describe, for the first time, a polymeric sorbent which is specific for nitrite ions. We have demonstrated that an epoxy-amine resin obtained by suspension polycondensation of ethylenediamine with epichlorohydrin practically contains only secondary amino groups. The hydrochloride form of the resin is extremely efficient and highly selective in the removal of nitrite ions from aqueous solutions, even in very low concentrations. Nitrite binding occurs through formation of N-nitroso groups. The nitrite-loaded resin can essentially be regenerated by concentrated acid solutions, without losing its reactivity.

Original languageEnglish
Pages (from-to)71-77
Number of pages7
JournalReactive and Functional Polymers
Volume36
Issue number1
DOIs
Publication statusPublished - Feb 1998

Keywords

  • Epoxy-amine resin
  • Ethylenediamine
  • Nitrite ion
  • Water purification

Fingerprint

Dive into the research topics of 'Removal of nitrite ions from aqueous solutions by cross-linked polymer of ethylenediamine with epichlorohydrin'. Together they form a unique fingerprint.

Cite this