Reactions of α,β-Enones with Diazo Compounds: Part 4: Reaction Pathways from (Z)- and (E)-α,β-Enones with Dimethyl Diazomalonate

Olcay Anaç; Füsun Seyma Güngör; Çiǧdem Kahveci; M. Şerif Cansever

doi:10.1002/hlca.200490039

Reactions of α,β-Enones with Diazo Compounds: Part 4: Reaction Pathways from (Z)- and (E)-α,β-Enones with Dimethyl Diazomalonate

Olcay Anaç^*, Füsun Seyma Güngör, Çiǧdem Kahveci, M. Şerif Cansever

^*Corresponding author for this work

Department of Chemistry

Istanbul Technical University

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

In this study, (E)- and (Z)-enones carrying only a phenyl substituent at their C(β) atom were treaced with dimethyl diazomalonate in the presence of (acetylacetonato)copper(II). According to the configuration of the starting enones, the products were dioxole or dihydrofuran derivatives, significant heterocycles in natural products.

Original language	English
Pages (from-to)	408-415
Number of pages	8
Journal	Helvetica Chimica Acta
Volume	87
Issue number	2
DOIs	https://doi.org/10.1002/hlca.200490039
Publication status	Published - 2004

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abstract = "In this study, (E)- and (Z)-enones carrying only a phenyl substituent at their C(β) atom were treaced with dimethyl diazomalonate in the presence of (acetylacetonato)copper(II). According to the configuration of the starting enones, the products were dioxole or dihydrofuran derivatives, significant heterocycles in natural products.",

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AU - Güngör, Füsun Seyma

AU - Kahveci, Çiǧdem

AU - Cansever, M. Şerif

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AB - In this study, (E)- and (Z)-enones carrying only a phenyl substituent at their C(β) atom were treaced with dimethyl diazomalonate in the presence of (acetylacetonato)copper(II). According to the configuration of the starting enones, the products were dioxole or dihydrofuran derivatives, significant heterocycles in natural products.

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Reactions of α,β-Enones with Diazo Compounds: Part 4: Reaction Pathways from (Z)- and (E)-α,β-Enones with Dimethyl Diazomalonate

Abstract

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