Reactions of α,β-enones with diazo compounds, 2: Synthesis of dihydrofuran derivatives

Olcay Anac; Ayse Daut

doi:10.1002/jlac.199719970630

Reactions of α,β-enones with diazo compounds, 2: Synthesis of dihydrofuran derivatives

Olcay Anac^*, Ayse Daut

^*Corresponding author for this work

Department of Chemistry

Istanbul Technical University

Research output: Contribution to journal › Article › peer-review

33 Citations (Scopus)

Abstract

Several α,β-unsaturated ketones were treated with dimethyl diazomalonate and ethyl acetodiazoacetate under bis(acetylacetonato)copper(II) catalysis. Dihydrofuran derivatives, obviously arising from carbonyl ylides, were isolated in high yields. Structural identifications were carried out using 2D-NMR-spectroscopic data.

Original language	English
Pages (from-to)	1249-1254
Number of pages	6
Journal	Liebigs Annales
Issue number	6
DOIs	https://doi.org/10.1002/jlac.199719970630
Publication status	Published - 1997

Keywords

Carbenes
Carbonyl ylides
Chirality
Diazo compounds
α,β-Enones

Access to Document

10.1002/jlac.199719970630

Cite this

@article{561f789795724217a78b3e75d3962613,

title = "Reactions of α,β-enones with diazo compounds, 2: Synthesis of dihydrofuran derivatives",

abstract = "Several α,β-unsaturated ketones were treated with dimethyl diazomalonate and ethyl acetodiazoacetate under bis(acetylacetonato)copper(II) catalysis. Dihydrofuran derivatives, obviously arising from carbonyl ylides, were isolated in high yields. Structural identifications were carried out using 2D-NMR-spectroscopic data.",

keywords = "Carbenes, Carbonyl ylides, Chirality, Diazo compounds, α,β-Enones",

author = "Olcay Anac and Ayse Daut",

year = "1997",

doi = "10.1002/jlac.199719970630",

language = "English",

pages = "1249--1254",

journal = "Liebigs Annales",

issn = "0947-3440",

publisher = "Wiley-VCH Verlag",

number = "6",

}

TY - JOUR

T1 - Reactions of α,β-enones with diazo compounds, 2

T2 - Synthesis of dihydrofuran derivatives

AU - Anac, Olcay

AU - Daut, Ayse

PY - 1997

Y1 - 1997

N2 - Several α,β-unsaturated ketones were treated with dimethyl diazomalonate and ethyl acetodiazoacetate under bis(acetylacetonato)copper(II) catalysis. Dihydrofuran derivatives, obviously arising from carbonyl ylides, were isolated in high yields. Structural identifications were carried out using 2D-NMR-spectroscopic data.

AB - Several α,β-unsaturated ketones were treated with dimethyl diazomalonate and ethyl acetodiazoacetate under bis(acetylacetonato)copper(II) catalysis. Dihydrofuran derivatives, obviously arising from carbonyl ylides, were isolated in high yields. Structural identifications were carried out using 2D-NMR-spectroscopic data.

KW - Carbenes

KW - Carbonyl ylides

KW - Chirality

KW - Diazo compounds

KW - α,β-Enones

UR - http://www.scopus.com/inward/record.url?scp=33748827140&partnerID=8YFLogxK

U2 - 10.1002/jlac.199719970630

DO - 10.1002/jlac.199719970630

M3 - Article

AN - SCOPUS:33748827140

SN - 0947-3440

SP - 1249

EP - 1254

JO - Liebigs Annales

JF - Liebigs Annales

IS - 6

ER -

Reactions of α,β-enones with diazo compounds, 2: Synthesis of dihydrofuran derivatives

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this