Reaction of metal carbonyls with 2-hydroxy-1-naphthaldeyde methanesulfonylhydrazone and characterization of the substitution products

Ü Özdemir; O. S. Şentürk; S. Sert; N. Karacan; F. Uǧur

doi:10.1080/00958970600663880

Reaction of metal carbonyls with 2-hydroxy-1-naphthaldeyde methanesulfonylhydrazone and characterization of the substitution products

Ü Özdemir^*, O. S. Şentürk, S. Sert, N. Karacan, F. Uǧur

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

Five new complexes, [M(CO)₅(nafmsh)] [M = Cr, 1; Mo, 2; W, 3], [Re(CO)₄Br(nafmsh)], 4 and [Mn(CO)₃(nafmsh)], 5 have been synthesized by the photochemical reaction of metal carbonyls [M(CO)₆] (M = Cr, Mo, W), [Re(CO)₅Br], and [Mn(CO)₃Cp] with 2-hydroxy-1-naphthaldehyde methanesulfonylhydrazone (nafmsh). The complexes have been characterized by elemental analysis, EI mass spectrometry, FT-IR, and ¹H NMR spectroscopy. The spectroscopic studies show nafmsh is a monodentate ligand coordinating via the imine N donor atom in 1-4 and as a tridentate ligand in 5.

Original language	English
Pages (from-to)	1905-1911
Number of pages	7
Journal	Journal of Coordination Chemistry
Volume	59
Issue number	17
DOIs	https://doi.org/10.1080/00958970600663880
Publication status	Published - 20 Nov 2006

Funding

This research was supported by Gazi University Research Fund under Project No. 05-98/24. We thank BP (Turkey) for the provision of photochemical apparatus and Research Foundation of Ege. We thank TUBITAK_ for allocation of time at the NMR, mass spectra and elemental analyses.

Funders	Funder number
Gazi University Research Fund	05-98/24

Keywords

Metal carbonyls, Cyclopentadienyl
Methanesulfonylhydrazone
Photosubstitution

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10.1080/00958970600663880

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title = "Reaction of metal carbonyls with 2-hydroxy-1-naphthaldeyde methanesulfonylhydrazone and characterization of the substitution products",

abstract = "Five new complexes, [M(CO)5(nafmsh)] [M = Cr, 1; Mo, 2; W, 3], [Re(CO)4Br(nafmsh)], 4 and [Mn(CO)3(nafmsh)], 5 have been synthesized by the photochemical reaction of metal carbonyls [M(CO)6] (M = Cr, Mo, W), [Re(CO)5Br], and [Mn(CO)3Cp] with 2-hydroxy-1-naphthaldehyde methanesulfonylhydrazone (nafmsh). The complexes have been characterized by elemental analysis, EI mass spectrometry, FT-IR, and 1H NMR spectroscopy. The spectroscopic studies show nafmsh is a monodentate ligand coordinating via the imine N donor atom in 1-4 and as a tridentate ligand in 5.",

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author = "{\"U} {\"O}zdemir and {\c S}ent{\"u}rk, {O. S.} and S. Sert and N. Karacan and F. Uǧur",

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T1 - Reaction of metal carbonyls with 2-hydroxy-1-naphthaldeyde methanesulfonylhydrazone and characterization of the substitution products

AU - Özdemir, Ü

AU - Şentürk, O. S.

AU - Sert, S.

AU - Karacan, N.

AU - Uǧur, F.

PY - 2006/11/20

Y1 - 2006/11/20

N2 - Five new complexes, [M(CO)5(nafmsh)] [M = Cr, 1; Mo, 2; W, 3], [Re(CO)4Br(nafmsh)], 4 and [Mn(CO)3(nafmsh)], 5 have been synthesized by the photochemical reaction of metal carbonyls [M(CO)6] (M = Cr, Mo, W), [Re(CO)5Br], and [Mn(CO)3Cp] with 2-hydroxy-1-naphthaldehyde methanesulfonylhydrazone (nafmsh). The complexes have been characterized by elemental analysis, EI mass spectrometry, FT-IR, and 1H NMR spectroscopy. The spectroscopic studies show nafmsh is a monodentate ligand coordinating via the imine N donor atom in 1-4 and as a tridentate ligand in 5.

AB - Five new complexes, [M(CO)5(nafmsh)] [M = Cr, 1; Mo, 2; W, 3], [Re(CO)4Br(nafmsh)], 4 and [Mn(CO)3(nafmsh)], 5 have been synthesized by the photochemical reaction of metal carbonyls [M(CO)6] (M = Cr, Mo, W), [Re(CO)5Br], and [Mn(CO)3Cp] with 2-hydroxy-1-naphthaldehyde methanesulfonylhydrazone (nafmsh). The complexes have been characterized by elemental analysis, EI mass spectrometry, FT-IR, and 1H NMR spectroscopy. The spectroscopic studies show nafmsh is a monodentate ligand coordinating via the imine N donor atom in 1-4 and as a tridentate ligand in 5.

KW - Metal carbonyls, Cyclopentadienyl

KW - Methanesulfonylhydrazone

KW - Photosubstitution

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U2 - 10.1080/00958970600663880

DO - 10.1080/00958970600663880

M3 - Article

AN - SCOPUS:33750412193

SN - 0095-8972

VL - 59

SP - 1905

EP - 1911

JO - Journal of Coordination Chemistry

JF - Journal of Coordination Chemistry

IS - 17

ER -

Reaction of metal carbonyls with 2-hydroxy-1-naphthaldeyde methanesulfonylhydrazone and characterization of the substitution products

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