Reaction kinetics of spent reactive dye bath ozonation process

T. Ölmez; I. Kabdaşli; O. Tünay

doi:10.1007/978-3-540-95991-5-118

Reaction kinetics of spent reactive dye bath ozonation process

T. Ölmez^*, I. Kabdaşli, O. Tünay

^*Corresponding author for this work

Department of Environmental Engineering

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

Oxidation of a spent reactive dye bath containing a mixture of Remazol brand dyes as well as two main inorganic additives was carried out using ozone and decolorization was obtained in a relatively short time (10-30 min) and ozone utilizations were between 329 and 1609 mg. The spent dye bath oxidation could not be represented by any simple kinetics. Ozonation kinetics and decolorization character was evaluated using synthetic samples with dyes and assisting chemicals. Synthetic Dye Sample decolorization was achieved in 90 s with ozone utilization of 32 mg. NaCl addition decelerated the decolorization rate and increase the ozone utilizations. Na₂CO₃ addition resulted in high pH and alkalinity and changed the mechanismof ozonation process as well as decolorization reactions yielding a better oxidation than that of the sample containing only NaCl.

Original language	English
Title of host publication	Survival and Sustainability
Subtitle of host publication	Environmental Concerns in the 21st Century
Pages	1263-1273
Number of pages	11
DOIs	https://doi.org/10.1007/978-3-540-95991-5-118
Publication status	Published - 2011
Event	International Conference on Environment: Survival and Sustainability - Nicosia, Cyprus Duration: 19 Feb 2007 → 24 Feb 2007

Conference

Conference	International Conference on Environment: Survival and Sustainability
Country/Territory	Cyprus
City	Nicosia
Period	19/02/07 → 24/02/07

Keywords

Color removal
Dye bath additives
Ozonation
Reactive dye bath
Textile finishing industry

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10.1007/978-3-540-95991-5-118

Cite this

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title = "Reaction kinetics of spent reactive dye bath ozonation process",

abstract = "Oxidation of a spent reactive dye bath containing a mixture of Remazol brand dyes as well as two main inorganic additives was carried out using ozone and decolorization was obtained in a relatively short time (10-30 min) and ozone utilizations were between 329 and 1609 mg. The spent dye bath oxidation could not be represented by any simple kinetics. Ozonation kinetics and decolorization character was evaluated using synthetic samples with dyes and assisting chemicals. Synthetic Dye Sample decolorization was achieved in 90 s with ozone utilization of 32 mg. NaCl addition decelerated the decolorization rate and increase the ozone utilizations. Na2CO3 addition resulted in high pH and alkalinity and changed the mechanismof ozonation process as well as decolorization reactions yielding a better oxidation than that of the sample containing only NaCl.",

keywords = "Color removal, Dye bath additives, Ozonation, Reactive dye bath, Textile finishing industry",

author = "T. {\"O}lmez and I. Kabda{\c s}li and O. T{\"u}nay",

year = "2011",

doi = "10.1007/978-3-540-95991-5-118",

language = "English",

isbn = "9783540959908",

pages = "1263--1273",

booktitle = "Survival and Sustainability",

note = "International Conference on Environment: Survival and Sustainability ; Conference date: 19-02-2007 Through 24-02-2007",

}

TY - GEN

T1 - Reaction kinetics of spent reactive dye bath ozonation process

AU - Ölmez, T.

AU - Kabdaşli, I.

AU - Tünay, O.

PY - 2011

Y1 - 2011

N2 - Oxidation of a spent reactive dye bath containing a mixture of Remazol brand dyes as well as two main inorganic additives was carried out using ozone and decolorization was obtained in a relatively short time (10-30 min) and ozone utilizations were between 329 and 1609 mg. The spent dye bath oxidation could not be represented by any simple kinetics. Ozonation kinetics and decolorization character was evaluated using synthetic samples with dyes and assisting chemicals. Synthetic Dye Sample decolorization was achieved in 90 s with ozone utilization of 32 mg. NaCl addition decelerated the decolorization rate and increase the ozone utilizations. Na2CO3 addition resulted in high pH and alkalinity and changed the mechanismof ozonation process as well as decolorization reactions yielding a better oxidation than that of the sample containing only NaCl.

AB - Oxidation of a spent reactive dye bath containing a mixture of Remazol brand dyes as well as two main inorganic additives was carried out using ozone and decolorization was obtained in a relatively short time (10-30 min) and ozone utilizations were between 329 and 1609 mg. The spent dye bath oxidation could not be represented by any simple kinetics. Ozonation kinetics and decolorization character was evaluated using synthetic samples with dyes and assisting chemicals. Synthetic Dye Sample decolorization was achieved in 90 s with ozone utilization of 32 mg. NaCl addition decelerated the decolorization rate and increase the ozone utilizations. Na2CO3 addition resulted in high pH and alkalinity and changed the mechanismof ozonation process as well as decolorization reactions yielding a better oxidation than that of the sample containing only NaCl.

KW - Color removal

KW - Dye bath additives

KW - Ozonation

KW - Reactive dye bath

KW - Textile finishing industry

UR - http://www.scopus.com/inward/record.url?scp=84894347198&partnerID=8YFLogxK

U2 - 10.1007/978-3-540-95991-5-118

DO - 10.1007/978-3-540-95991-5-118

M3 - Conference contribution

AN - SCOPUS:84894347198

SN - 9783540959908

SP - 1263

EP - 1273

BT - Survival and Sustainability

T2 - International Conference on Environment: Survival and Sustainability

Y2 - 19 February 2007 through 24 February 2007

ER -

Reaction kinetics of spent reactive dye bath ozonation process

Abstract

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Keywords

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