Production and Characterization of Nickel Borides for Supercapacitor Applications

Mehtap Arslan-Kaba; Servet Timur; Guldem Kartal Sireli

doi:10.1007/978-3-031-50349-8_37

Production and Characterization of Nickel Borides for Supercapacitor Applications

Mehtap Arslan-Kaba, Servet Timur, Guldem Kartal Sireli^*

^*Corresponding author for this work

Department of Metallurgical and Materials Engineering

Istanbul Technical University

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

This study involves the production of high-capacity nickel borideNickel borides (Ni4B3) electrodes via cathodic reduction and thermal diffusion-based boriding method (CRTD-Bor)CRTD-Bor. After 30 min of CRTD-BorCRTD-Bor at 1000 °C and 200 mA/cm², 10 min of phase homogenization (the substrate was immersed in the electrolyte without any polarization) were applied to form stoichiometric Ni-boride structuresStructure. The electrochemical behaviors of the Ni-boride specimens were examined in a 6 M KOH solution by using a three-electrode system. The cyclic voltammetry experiments were conducted within a potential window of 0–0.45 V, up to 1500 cycles. The areal capacitance (Ca) values were calculated as ~60, 195, 262, and 295 mF/cm² for the 5th, 500th, 1000th, and 1500th cycles, respectively.

Original language	English
Title of host publication	TMS 2024 153rd Annual Meeting and Exhibition Supplemental Proceedings
Publisher	Springer Science and Business Media Deutschland GmbH
Pages	435-440
Number of pages	6
ISBN (Print)	9783031503481
DOIs	https://doi.org/10.1007/978-3-031-50349-8_37
Publication status	Published - 2024
Event	153rd Annual Meeting and Exhibition of The Minerals, Metals and Materials Society, TMS 2024 - Orlando, United States Duration: 3 Mar 2024 → 7 Mar 2024

Publication series

Name	Minerals, Metals and Materials Series
ISSN (Print)	2367-1181
ISSN (Electronic)	2367-1696

Conference

Conference	153rd Annual Meeting and Exhibition of The Minerals, Metals and Materials Society, TMS 2024
Country/Territory	United States
City	Orlando
Period	3/03/24 → 7/03/24

Bibliographical note

Publisher Copyright:
© The Minerals, Metals & Materials Society 2024.

Funding

The authors gratefully acknowledge the financial support provided by the National Natural Science Foundation of China, project No. 52074051, the fundamental funds supported by Sichuan Science and Technology Program (2022YFQ0037), and the Natural Science Foundation of Chongqing (No. cstc2021jcyj-msxmX1111). The authors would like to thank Analytical and Testing Center of Chongqing University for XRD, XPS, TG, BET, and SEM characterizations.

Funders	Funder number
Sichuan Province Science and Technology Support Program	2022YFQ0037
National Natural Science Foundation of China	52074051
Chongqing University
Natural Science Foundation of Chongqing Municipality	cstc2021jcyj-msxmX1111

Keywords

CRTD-Bor
Nickel borides
Supercapacitors

Access to Document

10.1007/978-3-031-50349-8_37

Cite this

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title = "Production and Characterization of Nickel Borides for Supercapacitor Applications",

abstract = "This study involves the production of high-capacity nickel borideNickel borides (Ni4B3) electrodes via cathodic reduction and thermal diffusion-based boriding method (CRTD-Bor)CRTD-Bor. After 30 min of CRTD-BorCRTD-Bor at 1000 °C and 200 mA/cm2, 10 min of phase homogenization (the substrate was immersed in the electrolyte without any polarization) were applied to form stoichiometric Ni-boride structuresStructure. The electrochemical behaviors of the Ni-boride specimens were examined in a 6 M KOH solution by using a three-electrode system. The cyclic voltammetry experiments were conducted within a potential window of 0–0.45 V, up to 1500 cycles. The areal capacitance (Ca) values were calculated as ~60, 195, 262, and 295 mF/cm2 for the 5th, 500th, 1000th, and 1500th cycles, respectively.",

keywords = "CRTD-Bor, Nickel borides, Supercapacitors",

author = "Mehtap Arslan-Kaba and Servet Timur and Sireli, {Guldem Kartal}",

note = "Publisher Copyright: {\textcopyright} The Minerals, Metals & Materials Society 2024.; 153rd Annual Meeting and Exhibition of The Minerals, Metals and Materials Society, TMS 2024 ; Conference date: 03-03-2024 Through 07-03-2024",

year = "2024",

doi = "10.1007/978-3-031-50349-8_37",

language = "English",

isbn = "9783031503481",

series = "Minerals, Metals and Materials Series",

publisher = "Springer Science and Business Media Deutschland GmbH",

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address = "Germany",

}

Arslan-Kaba, M, Timur, S & Sireli, GK 2024, Production and Characterization of Nickel Borides for Supercapacitor Applications. in TMS 2024 153rd Annual Meeting and Exhibition Supplemental Proceedings. Minerals, Metals and Materials Series, Springer Science and Business Media Deutschland GmbH, pp. 435-440, 153rd Annual Meeting and Exhibition of The Minerals, Metals and Materials Society, TMS 2024, Orlando, United States, 3/03/24. https://doi.org/10.1007/978-3-031-50349-8_37

Production and Characterization of Nickel Borides for Supercapacitor Applications. / Arslan-Kaba, Mehtap; Timur, Servet ; Sireli, Guldem Kartal.
TMS 2024 153rd Annual Meeting and Exhibition Supplemental Proceedings. Springer Science and Business Media Deutschland GmbH, 2024. p. 435-440 (Minerals, Metals and Materials Series).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - Production and Characterization of Nickel Borides for Supercapacitor Applications

AU - Arslan-Kaba, Mehtap

AU - Timur, Servet

AU - Sireli, Guldem Kartal

PY - 2024

Y1 - 2024

N2 - This study involves the production of high-capacity nickel borideNickel borides (Ni4B3) electrodes via cathodic reduction and thermal diffusion-based boriding method (CRTD-Bor)CRTD-Bor. After 30 min of CRTD-BorCRTD-Bor at 1000 °C and 200 mA/cm2, 10 min of phase homogenization (the substrate was immersed in the electrolyte without any polarization) were applied to form stoichiometric Ni-boride structuresStructure. The electrochemical behaviors of the Ni-boride specimens were examined in a 6 M KOH solution by using a three-electrode system. The cyclic voltammetry experiments were conducted within a potential window of 0–0.45 V, up to 1500 cycles. The areal capacitance (Ca) values were calculated as ~60, 195, 262, and 295 mF/cm2 for the 5th, 500th, 1000th, and 1500th cycles, respectively.

AB - This study involves the production of high-capacity nickel borideNickel borides (Ni4B3) electrodes via cathodic reduction and thermal diffusion-based boriding method (CRTD-Bor)CRTD-Bor. After 30 min of CRTD-BorCRTD-Bor at 1000 °C and 200 mA/cm2, 10 min of phase homogenization (the substrate was immersed in the electrolyte without any polarization) were applied to form stoichiometric Ni-boride structuresStructure. The electrochemical behaviors of the Ni-boride specimens were examined in a 6 M KOH solution by using a three-electrode system. The cyclic voltammetry experiments were conducted within a potential window of 0–0.45 V, up to 1500 cycles. The areal capacitance (Ca) values were calculated as ~60, 195, 262, and 295 mF/cm2 for the 5th, 500th, 1000th, and 1500th cycles, respectively.

KW - CRTD-Bor

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Y2 - 3 March 2024 through 7 March 2024

ER -

Production and Characterization of Nickel Borides for Supercapacitor Applications

Abstract

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Bibliographical note

Funding

Keywords

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