Preparation of microporous organic polymer through Schiff base chemistry and its potential application

Omer Suat Taskin; Baris Kiskan; Abdullah Aksu; Nuray Balkis; Yusuf Yagci

doi:10.1080/15685551.2015.1041090

Preparation of microporous organic polymer through Schiff base chemistry and its potential application

Omer Suat Taskin, Baris Kiskan, Abdullah Aksu, Nuray Balkis, Yusuf Yagci^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

The uniform microporous organic polymer (MOP) was obtained in one-pot and one-step polymerization process through Schiff base chemistry under thermal conditions. The obtained anthraquinone-melamine based MOP (AM-MOP) displays high surface area (215 m²/g). AM-MOP was manually filled into a column with high pressure and used as packing material in the high-performance liquid chromatographic applications. The analysis of compounds such as polycyclic aromatic hydrocarbons, pesticides, flavonoids, and phenolic acids was performed to display a possible application by using AM-MOP packed column. Compared to the commercial columns, AM-MOP exhibits better selectivity factor and column efficiency arising from its strong π-π interaction activity. Furthermore, it has similar solvent uptake in both polar and nonpolar media, which explains good compatibility of the material with all mobile phases, from acetonitrile to methanol and water.

Original language	English
Pages (from-to)	567-573
Number of pages	7
Journal	Designed Monomers and Polymers
Volume	18
Issue number	6
DOIs	https://doi.org/10.1080/15685551.2015.1041090
Publication status	Published - 18 Aug 2015

Bibliographical note

Publisher Copyright:
© 2015 Taylor & Francis.

Keywords

chromatography
HPLC
microporous polymer
packing material
Schiff base chemistry

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10.1080/15685551.2015.1041090

Cite this

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abstract = "The uniform microporous organic polymer (MOP) was obtained in one-pot and one-step polymerization process through Schiff base chemistry under thermal conditions. The obtained anthraquinone-melamine based MOP (AM-MOP) displays high surface area (215 m2/g). AM-MOP was manually filled into a column with high pressure and used as packing material in the high-performance liquid chromatographic applications. The analysis of compounds such as polycyclic aromatic hydrocarbons, pesticides, flavonoids, and phenolic acids was performed to display a possible application by using AM-MOP packed column. Compared to the commercial columns, AM-MOP exhibits better selectivity factor and column efficiency arising from its strong π-π interaction activity. Furthermore, it has similar solvent uptake in both polar and nonpolar media, which explains good compatibility of the material with all mobile phases, from acetonitrile to methanol and water.",

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AU - Taskin, Omer Suat

AU - Kiskan, Baris

AU - Aksu, Abdullah

AU - Balkis, Nuray

AU - Yagci, Yusuf

PY - 2015/8/18

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N2 - The uniform microporous organic polymer (MOP) was obtained in one-pot and one-step polymerization process through Schiff base chemistry under thermal conditions. The obtained anthraquinone-melamine based MOP (AM-MOP) displays high surface area (215 m2/g). AM-MOP was manually filled into a column with high pressure and used as packing material in the high-performance liquid chromatographic applications. The analysis of compounds such as polycyclic aromatic hydrocarbons, pesticides, flavonoids, and phenolic acids was performed to display a possible application by using AM-MOP packed column. Compared to the commercial columns, AM-MOP exhibits better selectivity factor and column efficiency arising from its strong π-π interaction activity. Furthermore, it has similar solvent uptake in both polar and nonpolar media, which explains good compatibility of the material with all mobile phases, from acetonitrile to methanol and water.

AB - The uniform microporous organic polymer (MOP) was obtained in one-pot and one-step polymerization process through Schiff base chemistry under thermal conditions. The obtained anthraquinone-melamine based MOP (AM-MOP) displays high surface area (215 m2/g). AM-MOP was manually filled into a column with high pressure and used as packing material in the high-performance liquid chromatographic applications. The analysis of compounds such as polycyclic aromatic hydrocarbons, pesticides, flavonoids, and phenolic acids was performed to display a possible application by using AM-MOP packed column. Compared to the commercial columns, AM-MOP exhibits better selectivity factor and column efficiency arising from its strong π-π interaction activity. Furthermore, it has similar solvent uptake in both polar and nonpolar media, which explains good compatibility of the material with all mobile phases, from acetonitrile to methanol and water.

KW - chromatography

KW - HPLC

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KW - packing material

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Preparation of microporous organic polymer through Schiff base chemistry and its potential application

Abstract

Bibliographical note

Keywords

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