Preparation of heterogeneous phthalocyanine catalysts by cotton fabric dyeing

Altuǧ Mert Sevim; Cidal Ilgün; Ahmet Gül

doi:10.1016/j.dyepig.2010.10.008

Preparation of heterogeneous phthalocyanine catalysts by cotton fabric dyeing

Altuǧ Mert Sevim
, Cidal Ilgün
, Ahmet Gül^*

^*Corresponding author for this work

Department of Chemistry

Istanbul Technical University

Research output: Contribution to journal › Article › peer-review

45 Citations (Scopus)

Abstract

Metal-free (2) and metallo-phthalocyanines (2a-d) bearing four thioglycolic acid groups on the periphery were prepared by cyclotetramerization of a new precursor, namely 4-(carboxymethylsulfanyl)phthalonitrile (1) in the presence of the corresponding divalent metal salts (Zn(II), Co(II), Ni(II), Cu(II)). The new compounds were characterized by elemental analyses, IR, UV-Vis, mass, ¹³C-NMR and ¹H-NMR techniques. All these newly synthesized water-soluble metallo-phthalocyanine derivatives were supported on cationic cotton fabrics and the washing and water fastnesses of these novel dyed fabrics were investigated. Washing and water fastness data suggested that cationic cotton fabrics are superior to the others when dyed with these metallo-phthalocyanines.

Original language	English
Pages (from-to)	162-168
Number of pages	7
Journal	Dyes and Pigments
Volume	89
Issue number	2
DOIs	https://doi.org/10.1016/j.dyepig.2010.10.008
Publication status	Published - May 2011

Funding

This work was supported by the Research Fund of the Technical University of Istanbul .

Funders
Istanbul Teknik Üniversitesi

Keywords

Cotton fabric
Cyclotetramerisation
Dyeing
Fastness
Phthalocyanine
Thioglycolic acid

Access to Document

10.1016/j.dyepig.2010.10.008

Cite this

@article{6fd56c87323d46a6a2783f0f1c916a7e,

title = "Preparation of heterogeneous phthalocyanine catalysts by cotton fabric dyeing",

abstract = "Metal-free (2) and metallo-phthalocyanines (2a-d) bearing four thioglycolic acid groups on the periphery were prepared by cyclotetramerization of a new precursor, namely 4-(carboxymethylsulfanyl)phthalonitrile (1) in the presence of the corresponding divalent metal salts (Zn(II), Co(II), Ni(II), Cu(II)). The new compounds were characterized by elemental analyses, IR, UV-Vis, mass, 13C-NMR and 1H-NMR techniques. All these newly synthesized water-soluble metallo-phthalocyanine derivatives were supported on cationic cotton fabrics and the washing and water fastnesses of these novel dyed fabrics were investigated. Washing and water fastness data suggested that cationic cotton fabrics are superior to the others when dyed with these metallo-phthalocyanines.",

keywords = "Cotton fabric, Cyclotetramerisation, Dyeing, Fastness, Phthalocyanine, Thioglycolic acid",

author = "Sevim, \{Altuǧ Mert\} and Cidal Ilg{\"u}n and Ahmet G{\"u}l",

year = "2011",

month = may,

doi = "10.1016/j.dyepig.2010.10.008",

language = "English",

volume = "89",

pages = "162--168",

journal = "Dyes and Pigments",

issn = "0143-7208",

publisher = "Elsevier B.V.",

number = "2",

}

TY - JOUR

T1 - Preparation of heterogeneous phthalocyanine catalysts by cotton fabric dyeing

AU - Sevim, Altuǧ Mert

AU - Ilgün, Cidal

AU - Gül, Ahmet

PY - 2011/5

Y1 - 2011/5

N2 - Metal-free (2) and metallo-phthalocyanines (2a-d) bearing four thioglycolic acid groups on the periphery were prepared by cyclotetramerization of a new precursor, namely 4-(carboxymethylsulfanyl)phthalonitrile (1) in the presence of the corresponding divalent metal salts (Zn(II), Co(II), Ni(II), Cu(II)). The new compounds were characterized by elemental analyses, IR, UV-Vis, mass, 13C-NMR and 1H-NMR techniques. All these newly synthesized water-soluble metallo-phthalocyanine derivatives were supported on cationic cotton fabrics and the washing and water fastnesses of these novel dyed fabrics were investigated. Washing and water fastness data suggested that cationic cotton fabrics are superior to the others when dyed with these metallo-phthalocyanines.

AB - Metal-free (2) and metallo-phthalocyanines (2a-d) bearing four thioglycolic acid groups on the periphery were prepared by cyclotetramerization of a new precursor, namely 4-(carboxymethylsulfanyl)phthalonitrile (1) in the presence of the corresponding divalent metal salts (Zn(II), Co(II), Ni(II), Cu(II)). The new compounds were characterized by elemental analyses, IR, UV-Vis, mass, 13C-NMR and 1H-NMR techniques. All these newly synthesized water-soluble metallo-phthalocyanine derivatives were supported on cationic cotton fabrics and the washing and water fastnesses of these novel dyed fabrics were investigated. Washing and water fastness data suggested that cationic cotton fabrics are superior to the others when dyed with these metallo-phthalocyanines.

KW - Cotton fabric

KW - Cyclotetramerisation

KW - Dyeing

KW - Fastness

KW - Phthalocyanine

KW - Thioglycolic acid

UR - https://www.scopus.com/pages/publications/78649461421

U2 - 10.1016/j.dyepig.2010.10.008

DO - 10.1016/j.dyepig.2010.10.008

M3 - Article

AN - SCOPUS:78649461421

SN - 0143-7208

VL - 89

SP - 162

EP - 168

JO - Dyes and Pigments

JF - Dyes and Pigments

IS - 2

ER -

Preparation of heterogeneous phthalocyanine catalysts by cotton fabric dyeing

Abstract

Funding

Keywords

Access to Document

Other files and links

Fingerprint

Cite this