Preparation of fly ash-Ca(OH)2 sorbents by pressure hydration for so2 removal

N. Karatepe*, A. E. Meriçboyu, S. Küçükbayrak

*Corresponding author for this work

Research output: Contribution to specialist publicationArticle

16 Citations (Scopus)

Abstract

Reactive sorbents for SO2 removal from humidified flue gas were prepared from fly ash-Ca(OH)2 mixtures using the pressure hydration technique. The fly ash samples were taken from three different coal-fired power plants in Turkey. The fly ash/Ca(OH)2 weight ratio, hydration time, and temperature were varied during the sorbent preparation step. Effects of these variations on the physical properties of activated sorbents were investigated. A statistical design technique was applied by use of a two-level factorial design matrix to interpret experimental results. It was found that increasing the temperature and fly ash/Ca(OH)2 weight ratio caused a decrease in the total surface area of sorbents. However, surface area values of sorbents were not generally affected by the hydration time variation. Finally, fly ash-Ca(OH)2 sorbents prepared at the optimum hydration conditions were sulphated at 338 K with a synthetic gaseous mixture containing 5000 ppm SO2 and 55% relative humidity.

Original languageEnglish
Pages945-953
Number of pages9
Volume20
No.10
Specialist publicationEnergy Sources
DOIs
Publication statusPublished - 1998

Keywords

  • Pressure hydration
  • Sorbent
  • Statistical design

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