Preparation of electrocatalytically active RuO2/Ti electrodes by pechini method

O. Kahvecioglu; S. Timur

doi:10.1002/9780470528976.ch8

Preparation of electrocatalytically active RuO₂/Ti electrodes by pechini method

O. Kahvecioglu^*
, S. Timur

^*Corresponding author for this work

Department of Metallurgical and Materials Engineering

Istanbul Technical University

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

1 Citation (Scopus)

Abstract

In this study, DSA® type porous ruthenium oxide coated titanium electrodes with different coating masses were prepared by Pechini method from a polymeric precursor at different decomposition temperatures. The influences of temperature on the morphology and lhe microstructure of RuO₂ formed on titanium were investigated by SEM and thin film-XRD. This work aimed to prepare electrocatalytically active electrodes showing high stability during oxygen evolution reaction (OER). Linear Sweep Voltammetry (LSV) tests were performed in 1 M H₂SO₄ after a 1-h-constant anodic polarization at 20 niA/cm². Tafcl slopes (b) of 55-60 niV/dec were obtained. The electrodes prepared at lower temperatures show lower anode potentials than that of prepared at higher temperatures. Increasing of the coating mass showed an increase in the coating stability of the electrode. Similar clectrocatalytical properties were determined for the electrodes having different oxide loading obtained at 450°C.

Original language	English
Title of host publication	Advances in Energy Materials - A Collection of Papers Presented at the 2008 Materials Science and Technology Conference, MS and T08
Publisher	American Ceramic Society
Pages	77-86
Number of pages	10
ISBN (Print)	9780470408438
DOIs	https://doi.org/10.1002/9780470528976.ch8
Publication status	Published - 2009
Event	Advances in Energy Materials - 2008 Materials Science and Technology Conference, MS and T08 - Pittsburgh, PA, United States Duration: 5 Oct 2008 → 9 Oct 2008

Publication series

Name	Ceramic Transactions
Volume	205
ISSN (Print)	1042-1122

Conference

Conference	Advances in Energy Materials - 2008 Materials Science and Technology Conference, MS and T08
Country/Territory	United States
City	Pittsburgh, PA
Period	5/10/08 → 9/10/08

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Access to Document

10.1002/9780470528976.ch8

Cite this

@inproceedings{a0a3a1ec070b4d83881cb76d759fffb3,

title = "Preparation of electrocatalytically active RuO2/Ti electrodes by pechini method",

abstract = "In this study, DSA{\textregistered} type porous ruthenium oxide coated titanium electrodes with different coating masses were prepared by Pechini method from a polymeric precursor at different decomposition temperatures. The influences of temperature on the morphology and lhe microstructure of RuO2 formed on titanium were investigated by SEM and thin film-XRD. This work aimed to prepare electrocatalytically active electrodes showing high stability during oxygen evolution reaction (OER). Linear Sweep Voltammetry (LSV) tests were performed in 1 M H2SO4 after a 1-h-constant anodic polarization at 20 niA/cm2. Tafcl slopes (b) of 55-60 niV/dec were obtained. The electrodes prepared at lower temperatures show lower anode potentials than that of prepared at higher temperatures. Increasing of the coating mass showed an increase in the coating stability of the electrode. Similar clectrocatalytical properties were determined for the electrodes having different oxide loading obtained at 450°C.",

author = "O. Kahvecioglu and S. Timur",

year = "2009",

doi = "10.1002/9780470528976.ch8",

language = "English",

isbn = "9780470408438",

series = "Ceramic Transactions",

publisher = "American Ceramic Society",

pages = "77--86",

booktitle = "Advances in Energy Materials - A Collection of Papers Presented at the 2008 Materials Science and Technology Conference, MS and T08",

note = "Advances in Energy Materials - 2008 Materials Science and Technology Conference, MS and T08 ; Conference date: 05-10-2008 Through 09-10-2008",

}

Kahvecioglu, O & Timur, S 2009, Preparation of electrocatalytically active RuO₂/Ti electrodes by pechini method. in Advances in Energy Materials - A Collection of Papers Presented at the 2008 Materials Science and Technology Conference, MS and T08. Ceramic Transactions, vol. 205, American Ceramic Society, pp. 77-86, Advances in Energy Materials - 2008 Materials Science and Technology Conference, MS and T08, Pittsburgh, PA, United States, 5/10/08. https://doi.org/10.1002/9780470528976.ch8

Preparation of electrocatalytically active RuO₂/Ti electrodes by pechini method. / Kahvecioglu, O.; Timur, S.
Advances in Energy Materials - A Collection of Papers Presented at the 2008 Materials Science and Technology Conference, MS and T08. American Ceramic Society, 2009. p. 77-86 (Ceramic Transactions; Vol. 205).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

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AB - In this study, DSA® type porous ruthenium oxide coated titanium electrodes with different coating masses were prepared by Pechini method from a polymeric precursor at different decomposition temperatures. The influences of temperature on the morphology and lhe microstructure of RuO2 formed on titanium were investigated by SEM and thin film-XRD. This work aimed to prepare electrocatalytically active electrodes showing high stability during oxygen evolution reaction (OER). Linear Sweep Voltammetry (LSV) tests were performed in 1 M H2SO4 after a 1-h-constant anodic polarization at 20 niA/cm2. Tafcl slopes (b) of 55-60 niV/dec were obtained. The electrodes prepared at lower temperatures show lower anode potentials than that of prepared at higher temperatures. Increasing of the coating mass showed an increase in the coating stability of the electrode. Similar clectrocatalytical properties were determined for the electrodes having different oxide loading obtained at 450°C.

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