Preparation of complexes formed in the reaction between diironnanocarbonyl and tetraalkyl(phenyl)diphosphine disulfides, R2P(S)P(S)R2 (R=Et, n-Pr, n-Bu, Ph)

Ozan Sanli Şentürk

doi:10.1080/00958970701377216

Preparation of complexes formed in the reaction between diironnanocarbonyl and tetraalkyl(phenyl)diphosphine disulfides, R2P(S)P(S)R2 (R=Et, n-Pr, n-Bu, Ph)

Ozan Sanli Şentürk

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

Fe2(CO)9 and R2P(S)P(S)R2 (R = Et, n-Pr, n-Bu, Ph) react to form two types of cluster complexes Fe3(CO)9(μ3-S)2 (1), Fe2(CO)6(μ-SPR2)2 (2A)-(2D), [2A, R = Et; 2B, R = n-Pr; 2C, R = n-Bu; 2D, R = Ph]. The complexes result from phosphorus-phosphorus bond scission; in the former sulfur abstraction has also occurred. The complexes have been characterized by elemental analyses, FT-IR and 31P-[1H]-NMR spectroscopy and mass spectrometry.

Original language	English
Pages (from-to)	776-780
Number of pages	5
Journal	Journal of Coordination Chemistry
Volume	61
Issue number	5
DOIs	https://doi.org/10.1080/00958970701377216
Publication status	Published - 2008

Keywords

Diironenneacarbonyl
Dimer
Diphosphinedisulfide
Iron

Access to Document

10.1080/00958970701377216

Cite this

@article{610fe4544b8c468d8eb41d816c4fee1d,

title = "Preparation of complexes formed in the reaction between diironnanocarbonyl and tetraalkyl(phenyl)diphosphine disulfides, R2P(S)P(S)R2 (R=Et, n-Pr, n-Bu, Ph)",

abstract = "Fe2(CO)9 and R2P(S)P(S)R2 (R = Et, n-Pr, n-Bu, Ph) react to form two types of cluster complexes Fe3(CO)9(μ3-S)2 (1), Fe2(CO)6(μ-SPR2)2 (2A)-(2D), [2A, R = Et; 2B, R = n-Pr; 2C, R = n-Bu; 2D, R = Ph]. The complexes result from phosphorus-phosphorus bond scission; in the former sulfur abstraction has also occurred. The complexes have been characterized by elemental analyses, FT-IR and 31P-[1H]-NMR spectroscopy and mass spectrometry.",

keywords = "Diironenneacarbonyl, Dimer, Diphosphinedisulfide, Iron",

author = "{\c S}ent{\"u}rk, \{Ozan Sanli\}",

year = "2008",

doi = "10.1080/00958970701377216",

language = "English",

volume = "61",

pages = "776--780",

journal = "Journal of Coordination Chemistry",

issn = "0095-8972",

publisher = "Taylor and Francis Ltd.",

number = "5",

}

TY - JOUR

T1 - Preparation of complexes formed in the reaction between diironnanocarbonyl and tetraalkyl(phenyl)diphosphine disulfides, R2P(S)P(S)R2 (R=Et, n-Pr, n-Bu, Ph)

AU - Şentürk, Ozan Sanli

PY - 2008

Y1 - 2008

N2 - Fe2(CO)9 and R2P(S)P(S)R2 (R = Et, n-Pr, n-Bu, Ph) react to form two types of cluster complexes Fe3(CO)9(μ3-S)2 (1), Fe2(CO)6(μ-SPR2)2 (2A)-(2D), [2A, R = Et; 2B, R = n-Pr; 2C, R = n-Bu; 2D, R = Ph]. The complexes result from phosphorus-phosphorus bond scission; in the former sulfur abstraction has also occurred. The complexes have been characterized by elemental analyses, FT-IR and 31P-[1H]-NMR spectroscopy and mass spectrometry.

AB - Fe2(CO)9 and R2P(S)P(S)R2 (R = Et, n-Pr, n-Bu, Ph) react to form two types of cluster complexes Fe3(CO)9(μ3-S)2 (1), Fe2(CO)6(μ-SPR2)2 (2A)-(2D), [2A, R = Et; 2B, R = n-Pr; 2C, R = n-Bu; 2D, R = Ph]. The complexes result from phosphorus-phosphorus bond scission; in the former sulfur abstraction has also occurred. The complexes have been characterized by elemental analyses, FT-IR and 31P-[1H]-NMR spectroscopy and mass spectrometry.

KW - Diironenneacarbonyl

KW - Dimer

KW - Diphosphinedisulfide

KW - Iron

UR - https://www.scopus.com/pages/publications/40149097149

U2 - 10.1080/00958970701377216

DO - 10.1080/00958970701377216

M3 - Article

AN - SCOPUS:40149097149

SN - 0095-8972

VL - 61

SP - 776

EP - 780

JO - Journal of Coordination Chemistry

JF - Journal of Coordination Chemistry

IS - 5

ER -

Preparation of complexes formed in the reaction between diironnanocarbonyl and tetraalkyl(phenyl)diphosphine disulfides, R2P(S)P(S)R2 (R=Et, n-Pr, n-Bu, Ph)

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this