TY - JOUR
T1 - Preparation of complexes formed in the reaction between diironnanocarbonyl and tetraalkyl(phenyl)diphosphine disulfides, R2P(S)P(S)R2 (R=Et, n-Pr, n-Bu, Ph)
AU - Şentürk, Ozan Sanli
PY - 2008
Y1 - 2008
N2 - Fe2(CO)9 and R2P(S)P(S)R2 (R = Et, n-Pr, n-Bu, Ph) react to form two types of cluster complexes Fe3(CO)9(μ3-S)2 (1), Fe2(CO)6(μ-SPR2)2 (2A)-(2D), [2A, R = Et; 2B, R = n-Pr; 2C, R = n-Bu; 2D, R = Ph]. The complexes result from phosphorus-phosphorus bond scission; in the former sulfur abstraction has also occurred. The complexes have been characterized by elemental analyses, FT-IR and 31P-[1H]-NMR spectroscopy and mass spectrometry.
AB - Fe2(CO)9 and R2P(S)P(S)R2 (R = Et, n-Pr, n-Bu, Ph) react to form two types of cluster complexes Fe3(CO)9(μ3-S)2 (1), Fe2(CO)6(μ-SPR2)2 (2A)-(2D), [2A, R = Et; 2B, R = n-Pr; 2C, R = n-Bu; 2D, R = Ph]. The complexes result from phosphorus-phosphorus bond scission; in the former sulfur abstraction has also occurred. The complexes have been characterized by elemental analyses, FT-IR and 31P-[1H]-NMR spectroscopy and mass spectrometry.
KW - Diironenneacarbonyl
KW - Dimer
KW - Diphosphinedisulfide
KW - Iron
UR - http://www.scopus.com/inward/record.url?scp=40149097149&partnerID=8YFLogxK
U2 - 10.1080/00958970701377216
DO - 10.1080/00958970701377216
M3 - Article
AN - SCOPUS:40149097149
SN - 0095-8972
VL - 61
SP - 776
EP - 780
JO - Journal of Coordination Chemistry
JF - Journal of Coordination Chemistry
IS - 5
ER -