Preparation of complexes formed in the reaction between dicobaltoctacarbonyl and tetraalkyldiphosphine disulfides, R2P(S)P(S)R2 (R = Me, Et, n-Pr, n-Bu)

Fadime Uǧur; Ozan Sanli Şentürk; Işil Topaloǧlu

doi:10.1080/00945710009351862

Preparation of complexes formed in the reaction between dicobaltoctacarbonyl and tetraalkyldiphosphine disulfides, R₂P(S)P(S)R₂ (R = Me, Et, n-Pr, n-Bu)

Fadime Uǧur^*, Ozan Sanli Şentürk, Işil Topaloǧlu

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

Co₂(CO)₈ and R₂P(S)P(S)R₂ (R = Me, Et, n-Pr, n-Bu) react to form the three types of cluster complexes [Co₂(μ-CO)(μ₄-S)(CO)₄]₂, (1), [Co₄(CO)₉(μ3-S)(μ-PR₂)₂] (2A)-(2D), [(2A), R = Me; (2B), R = Et; (2C), R = n-Pr; (2D), R = n-Bu] and [Co₃(CO)₇(μ₃-S)(SPR₂)] (3A)-(3D), [(3A), R = Me; (3B), R = Et; (3C), R = n-Pr; (3D), R = n-Bu]. The structure of (2A) and the disubstituted triphenylphosphine derivative of (3A) were reported previously. The complexes have been characterized by elemental analyses, FT-IR and ³¹P-[¹H] NMR spectroscopy and mass spectrometry.

Original language	English
Pages (from-to)	1697-1702
Number of pages	6
Journal	Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry
Volume	30
Issue number	9
DOIs	https://doi.org/10.1080/00945710009351862
Publication status	Published - 2000
Externally published	Yes

Funding

We thank TUBITAK and the Research Foundation of Ege University for funds and

Funders	Funder number
Research Foundation of Ege University
TUBITAK

Access to Document

10.1080/00945710009351862

Cite this

@article{99f2550571f24d62b115558563104a41,

title = "Preparation of complexes formed in the reaction between dicobaltoctacarbonyl and tetraalkyldiphosphine disulfides, R2P(S)P(S)R2 (R = Me, Et, n-Pr, n-Bu)",

abstract = "Co2(CO)8 and R2P(S)P(S)R2 (R = Me, Et, n-Pr, n-Bu) react to form the three types of cluster complexes [Co2(μ-CO)(μ4-S)(CO)4]2, (1), [Co4(CO)9(μ3-S)(μ-PR2)2] (2A)-(2D), [(2A), R = Me; (2B), R = Et; (2C), R = n-Pr; (2D), R = n-Bu] and [Co3(CO)7(μ3-S)(SPR2)] (3A)-(3D), [(3A), R = Me; (3B), R = Et; (3C), R = n-Pr; (3D), R = n-Bu]. The structure of (2A) and the disubstituted triphenylphosphine derivative of (3A) were reported previously. The complexes have been characterized by elemental analyses, FT-IR and 31P-[1H] NMR spectroscopy and mass spectrometry.",

author = "Fadime Uǧur and {\c S}ent{\"u}rk, \{Ozan Sanli\} and I{\c s}il Topaloǧlu",

year = "2000",

doi = "10.1080/00945710009351862",

language = "English",

volume = "30",

pages = "1697--1702",

journal = "Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry",

issn = "0094-5714",

publisher = "Taylor and Francis Ltd.",

number = "9",

}

Preparation of complexes formed in the reaction between dicobaltoctacarbonyl and tetraalkyldiphosphine disulfides, R₂P(S)P(S)R₂ (R = Me, Et, n-Pr, n-Bu). / Uǧur, Fadime; Şentürk, Ozan Sanli; Topaloǧlu, Işil.
In: Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, Vol. 30, No. 9, 2000, p. 1697-1702.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Preparation of complexes formed in the reaction between dicobaltoctacarbonyl and tetraalkyldiphosphine disulfides, R2P(S)P(S)R2 (R = Me, Et, n-Pr, n-Bu)

AU - Uǧur, Fadime

AU - Şentürk, Ozan Sanli

AU - Topaloǧlu, Işil

PY - 2000

Y1 - 2000

N2 - Co2(CO)8 and R2P(S)P(S)R2 (R = Me, Et, n-Pr, n-Bu) react to form the three types of cluster complexes [Co2(μ-CO)(μ4-S)(CO)4]2, (1), [Co4(CO)9(μ3-S)(μ-PR2)2] (2A)-(2D), [(2A), R = Me; (2B), R = Et; (2C), R = n-Pr; (2D), R = n-Bu] and [Co3(CO)7(μ3-S)(SPR2)] (3A)-(3D), [(3A), R = Me; (3B), R = Et; (3C), R = n-Pr; (3D), R = n-Bu]. The structure of (2A) and the disubstituted triphenylphosphine derivative of (3A) were reported previously. The complexes have been characterized by elemental analyses, FT-IR and 31P-[1H] NMR spectroscopy and mass spectrometry.

AB - Co2(CO)8 and R2P(S)P(S)R2 (R = Me, Et, n-Pr, n-Bu) react to form the three types of cluster complexes [Co2(μ-CO)(μ4-S)(CO)4]2, (1), [Co4(CO)9(μ3-S)(μ-PR2)2] (2A)-(2D), [(2A), R = Me; (2B), R = Et; (2C), R = n-Pr; (2D), R = n-Bu] and [Co3(CO)7(μ3-S)(SPR2)] (3A)-(3D), [(3A), R = Me; (3B), R = Et; (3C), R = n-Pr; (3D), R = n-Bu]. The structure of (2A) and the disubstituted triphenylphosphine derivative of (3A) were reported previously. The complexes have been characterized by elemental analyses, FT-IR and 31P-[1H] NMR spectroscopy and mass spectrometry.

UR - https://www.scopus.com/pages/publications/0034367863

U2 - 10.1080/00945710009351862

DO - 10.1080/00945710009351862

M3 - Article

AN - SCOPUS:0034367863

SN - 0094-5714

VL - 30

SP - 1697

EP - 1702

JO - Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry

JF - Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry

IS - 9

ER -

Preparation of complexes formed in the reaction between dicobaltoctacarbonyl and tetraalkyldiphosphine disulfides, R₂P(S)P(S)R₂ (R = Me, Et, n-Pr, n-Bu)

Abstract

Funding

Access to Document

Other files and links

Fingerprint

Cite this