Preparation of complexes formed in the reaction between dicobaltoctacarbonyl and tetraalkyldiphosphine disulfides, R2P(S)P(S)R2 (R = Me, Et, n-Pr, n-Bu)

Fadime Uǧur; Ozan Sanli Şentürk; Işil Topaloǧlu

doi:10.1080/00945710009351862

Preparation of complexes formed in the reaction between dicobaltoctacarbonyl and tetraalkyldiphosphine disulfides, R₂P(S)P(S)R₂ (R = Me, Et, n-Pr, n-Bu)

Fadime Uǧur^*, Ozan Sanli Şentürk, Işil Topaloǧlu

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

Co₂(CO)₈ and R₂P(S)P(S)R₂ (R = Me, Et, n-Pr, n-Bu) react to form the three types of cluster complexes [Co₂(μ-CO)(μ₄-S)(CO)₄]₂, (1), [Co₄(CO)₉(μ3-S)(μ-PR₂)₂] (2A)-(2D), [(2A), R = Me; (2B), R = Et; (2C), R = n-Pr; (2D), R = n-Bu] and [Co₃(CO)₇(μ₃-S)(SPR₂)] (3A)-(3D), [(3A), R = Me; (3B), R = Et; (3C), R = n-Pr; (3D), R = n-Bu]. The structure of (2A) and the disubstituted triphenylphosphine derivative of (3A) were reported previously. The complexes have been characterized by elemental analyses, FT-IR and ³¹P-[¹H] NMR spectroscopy and mass spectrometry.

Original language	English
Pages (from-to)	1697-1702
Number of pages	6
Journal	Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry
Volume	30
Issue number	9
DOIs	https://doi.org/10.1080/00945710009351862
Publication status	Published - 2000
Externally published	Yes

Funding

We thank TUBITAK and the Research Foundation of Ege University for funds and

Funders	Funder number
Research Foundation of Ege University
TUBITAK

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10.1080/00945710009351862

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title = "Preparation of complexes formed in the reaction between dicobaltoctacarbonyl and tetraalkyldiphosphine disulfides, R2P(S)P(S)R2 (R = Me, Et, n-Pr, n-Bu)",

abstract = "Co2(CO)8 and R2P(S)P(S)R2 (R = Me, Et, n-Pr, n-Bu) react to form the three types of cluster complexes [Co2(μ-CO)(μ4-S)(CO)4]2, (1), [Co4(CO)9(μ3-S)(μ-PR2)2] (2A)-(2D), [(2A), R = Me; (2B), R = Et; (2C), R = n-Pr; (2D), R = n-Bu] and [Co3(CO)7(μ3-S)(SPR2)] (3A)-(3D), [(3A), R = Me; (3B), R = Et; (3C), R = n-Pr; (3D), R = n-Bu]. The structure of (2A) and the disubstituted triphenylphosphine derivative of (3A) were reported previously. The complexes have been characterized by elemental analyses, FT-IR and 31P-[1H] NMR spectroscopy and mass spectrometry.",

author = "Fadime Uǧur and {\c S}ent{\"u}rk, {Ozan Sanli} and I{\c s}il Topaloǧlu",

year = "2000",

doi = "10.1080/00945710009351862",

language = "English",

volume = "30",

pages = "1697--1702",

journal = "Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry",

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publisher = "Taylor and Francis Ltd.",

number = "9",

}

Preparation of complexes formed in the reaction between dicobaltoctacarbonyl and tetraalkyldiphosphine disulfides, R₂P(S)P(S)R₂ (R = Me, Et, n-Pr, n-Bu). / Uǧur, Fadime; Şentürk, Ozan Sanli; Topaloǧlu, Işil.
In: Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, Vol. 30, No. 9, 2000, p. 1697-1702.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Preparation of complexes formed in the reaction between dicobaltoctacarbonyl and tetraalkyldiphosphine disulfides, R2P(S)P(S)R2 (R = Me, Et, n-Pr, n-Bu)

AU - Uǧur, Fadime

AU - Şentürk, Ozan Sanli

AU - Topaloǧlu, Işil

PY - 2000

Y1 - 2000

N2 - Co2(CO)8 and R2P(S)P(S)R2 (R = Me, Et, n-Pr, n-Bu) react to form the three types of cluster complexes [Co2(μ-CO)(μ4-S)(CO)4]2, (1), [Co4(CO)9(μ3-S)(μ-PR2)2] (2A)-(2D), [(2A), R = Me; (2B), R = Et; (2C), R = n-Pr; (2D), R = n-Bu] and [Co3(CO)7(μ3-S)(SPR2)] (3A)-(3D), [(3A), R = Me; (3B), R = Et; (3C), R = n-Pr; (3D), R = n-Bu]. The structure of (2A) and the disubstituted triphenylphosphine derivative of (3A) were reported previously. The complexes have been characterized by elemental analyses, FT-IR and 31P-[1H] NMR spectroscopy and mass spectrometry.

AB - Co2(CO)8 and R2P(S)P(S)R2 (R = Me, Et, n-Pr, n-Bu) react to form the three types of cluster complexes [Co2(μ-CO)(μ4-S)(CO)4]2, (1), [Co4(CO)9(μ3-S)(μ-PR2)2] (2A)-(2D), [(2A), R = Me; (2B), R = Et; (2C), R = n-Pr; (2D), R = n-Bu] and [Co3(CO)7(μ3-S)(SPR2)] (3A)-(3D), [(3A), R = Me; (3B), R = Et; (3C), R = n-Pr; (3D), R = n-Bu]. The structure of (2A) and the disubstituted triphenylphosphine derivative of (3A) were reported previously. The complexes have been characterized by elemental analyses, FT-IR and 31P-[1H] NMR spectroscopy and mass spectrometry.

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DO - 10.1080/00945710009351862

M3 - Article

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SN - 0094-5714

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JO - Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry

JF - Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry

IS - 9

ER -

Preparation of complexes formed in the reaction between dicobaltoctacarbonyl and tetraalkyldiphosphine disulfides, R₂P(S)P(S)R₂ (R = Me, Et, n-Pr, n-Bu)

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