Preparation, electrochemistry and optical properties of unsymmetrical phthalocyanines bearing morpholine and tert-butylphenoxy substituents

Ayfer Kalkan Burat; Atif Koca; Jan P. Lewtak; Daniel T. Gryko

doi:10.1016/j.synthmet.2011.05.010

Preparation, electrochemistry and optical properties of unsymmetrical phthalocyanines bearing morpholine and tert-butylphenoxy substituents

Ayfer Kalkan Burat^*, Atif Koca, Jan P. Lewtak, Daniel T. Gryko

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

25 Citations (Scopus)

Abstract

The synthesis of novel, unsymmetrical, octasubstituted metal-free and metallophthalocyanines (zinc, cobalt) bearing one chlorine, one morpholine moieties and six 4-tert-butylphenoxy substituents was achieved by a statistical condensation reaction of two corresponding phthalonitriles. The new compounds have been characterized by using elemental analyses, UV-vis, IR, ¹H NMR and mass spectroscopic data. Voltammetric and spectroelectrochemical studies are in harmony with the reported metallophthalocyanine complexes, which support the proposed structure of the complexes.

Original language	English
Pages (from-to)	1537-1545
Number of pages	9
Journal	Synthetic Metals
Volume	161
Issue number	15-16
DOIs	https://doi.org/10.1016/j.synthmet.2011.05.010
Publication status	Published - Aug 2011

Funding

This work was funded by Marie Curie Research Training Network ‘REVCAT’ (Contract Number: MRTN-CT-2006-035866 ).

Funders	Funder number
Marie Curie Research Training Network	MRTN-CT-2006-035866

Keywords

Electrochemistry
Phthalocyanine
Spectroelectrochemistry
Unsymmetric
Zinc

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10.1016/j.synthmet.2011.05.010

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title = "Preparation, electrochemistry and optical properties of unsymmetrical phthalocyanines bearing morpholine and tert-butylphenoxy substituents",

abstract = "The synthesis of novel, unsymmetrical, octasubstituted metal-free and metallophthalocyanines (zinc, cobalt) bearing one chlorine, one morpholine moieties and six 4-tert-butylphenoxy substituents was achieved by a statistical condensation reaction of two corresponding phthalonitriles. The new compounds have been characterized by using elemental analyses, UV-vis, IR, 1H NMR and mass spectroscopic data. Voltammetric and spectroelectrochemical studies are in harmony with the reported metallophthalocyanine complexes, which support the proposed structure of the complexes.",

keywords = "Electrochemistry, Phthalocyanine, Spectroelectrochemistry, Unsymmetric, Zinc",

author = "Burat, {Ayfer Kalkan} and Atif Koca and Lewtak, {Jan P.} and Gryko, {Daniel T.}",

year = "2011",

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T1 - Preparation, electrochemistry and optical properties of unsymmetrical phthalocyanines bearing morpholine and tert-butylphenoxy substituents

AU - Burat, Ayfer Kalkan

AU - Koca, Atif

AU - Lewtak, Jan P.

AU - Gryko, Daniel T.

PY - 2011/8

Y1 - 2011/8

N2 - The synthesis of novel, unsymmetrical, octasubstituted metal-free and metallophthalocyanines (zinc, cobalt) bearing one chlorine, one morpholine moieties and six 4-tert-butylphenoxy substituents was achieved by a statistical condensation reaction of two corresponding phthalonitriles. The new compounds have been characterized by using elemental analyses, UV-vis, IR, 1H NMR and mass spectroscopic data. Voltammetric and spectroelectrochemical studies are in harmony with the reported metallophthalocyanine complexes, which support the proposed structure of the complexes.

AB - The synthesis of novel, unsymmetrical, octasubstituted metal-free and metallophthalocyanines (zinc, cobalt) bearing one chlorine, one morpholine moieties and six 4-tert-butylphenoxy substituents was achieved by a statistical condensation reaction of two corresponding phthalonitriles. The new compounds have been characterized by using elemental analyses, UV-vis, IR, 1H NMR and mass spectroscopic data. Voltammetric and spectroelectrochemical studies are in harmony with the reported metallophthalocyanine complexes, which support the proposed structure of the complexes.

KW - Electrochemistry

KW - Phthalocyanine

KW - Spectroelectrochemistry

KW - Unsymmetric

KW - Zinc

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DO - 10.1016/j.synthmet.2011.05.010

M3 - Article

AN - SCOPUS:80051596389

SN - 0379-6779

VL - 161

SP - 1537

EP - 1545

JO - Synthetic Metals

JF - Synthetic Metals

IS - 15-16

ER -

Preparation, electrochemistry and optical properties of unsymmetrical phthalocyanines bearing morpholine and tert-butylphenoxy substituents

Abstract

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