Preparation, electrochemical, and spectroelectrochemical characterization of a new water-soluble copper phthalocyanine

Sonmez Arslan; Ismail Yilmaz

doi:10.1016/j.inoche.2006.12.004

Preparation, electrochemical, and spectroelectrochemical characterization of a new water-soluble copper phthalocyanine

Sonmez Arslan, Ismail Yilmaz^*

^*Corresponding author for this work

Department of Chemistry

Istanbul Technical University

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

A new water-soluble copper phthalocyanine, 2,9,16,23-tetrakis(4-(1-naphthoxy-4-sulfonic acid sodium salt)) phthalocyaninato copper NhtCuPc, where Nht indicates naphthoxy-4-sulfonic acid sodium salt, was synthesized and its electrochemical and spectroelectrochemical behavior were investigated in DMSO solution. The in situ spectroelectrochemical studies showed that the neutral complex exhibited the characteristic spectral changes corresponding to mono-anionic [NhtCuPc(3-)]^- and di-anionic [NhtCuPc(4-)]^2- species having long-term stability during reduction processes.

Original language	English
Pages (from-to)	385-388
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	10
Issue number	4
DOIs	https://doi.org/10.1016/j.inoche.2006.12.004
Publication status	Published - Apr 2007

Funding

The supports of State Planning Organization (DPT, Project No: 90177) is gratefully acknowledged. This work has also been supported, in part, by the Turkish Academy of Sciences in the framework of the Young Scientist Award Program (EA-TÜBA-GEBİP/2001-1-1).

Funders	Funder number
DPT	90177
Devlet Planlama Örgütü
Türkiye Bilimler Akademisi	EA-TÜBA-GEBİP/2001-1-1

Keywords

Complexation
Electrochemistry
Phthalocyanines
Spectroelectrochemistry

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10.1016/j.inoche.2006.12.004

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abstract = "A new water-soluble copper phthalocyanine, 2,9,16,23-tetrakis(4-(1-naphthoxy-4-sulfonic acid sodium salt)) phthalocyaninato copper NhtCuPc, where Nht indicates naphthoxy-4-sulfonic acid sodium salt, was synthesized and its electrochemical and spectroelectrochemical behavior were investigated in DMSO solution. The in situ spectroelectrochemical studies showed that the neutral complex exhibited the characteristic spectral changes corresponding to mono-anionic [NhtCuPc(3-)]- and di-anionic [NhtCuPc(4-)]2- species having long-term stability during reduction processes.",

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author = "Sonmez Arslan and Ismail Yilmaz",

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AU - Yilmaz, Ismail

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AB - A new water-soluble copper phthalocyanine, 2,9,16,23-tetrakis(4-(1-naphthoxy-4-sulfonic acid sodium salt)) phthalocyaninato copper NhtCuPc, where Nht indicates naphthoxy-4-sulfonic acid sodium salt, was synthesized and its electrochemical and spectroelectrochemical behavior were investigated in DMSO solution. The in situ spectroelectrochemical studies showed that the neutral complex exhibited the characteristic spectral changes corresponding to mono-anionic [NhtCuPc(3-)]- and di-anionic [NhtCuPc(4-)]2- species having long-term stability during reduction processes.

KW - Complexation

KW - Electrochemistry

KW - Phthalocyanines

KW - Spectroelectrochemistry

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M3 - Article

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SN - 1387-7003

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JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 4

ER -

Preparation, electrochemical, and spectroelectrochemical characterization of a new water-soluble copper phthalocyanine

Abstract

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Keywords

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