Preparation, electrochemical, and spectroelectrochemical characterization of a new water-soluble copper phthalocyanine

Sonmez Arslan; Ismail Yilmaz

doi:10.1016/j.inoche.2006.12.004

Preparation, electrochemical, and spectroelectrochemical characterization of a new water-soluble copper phthalocyanine

Sonmez Arslan, Ismail Yilmaz^*

^*Corresponding author for this work

Department of Chemistry

Istanbul Technical University

Research output: Contribution to journal › Article › peer-review

26 Citations (Scopus)

Abstract

A new water-soluble copper phthalocyanine, 2,9,16,23-tetrakis(4-(1-naphthoxy-4-sulfonic acid sodium salt)) phthalocyaninato copper NhtCuPc, where Nht indicates naphthoxy-4-sulfonic acid sodium salt, was synthesized and its electrochemical and spectroelectrochemical behavior were investigated in DMSO solution. The in situ spectroelectrochemical studies showed that the neutral complex exhibited the characteristic spectral changes corresponding to mono-anionic [NhtCuPc(3-)]^- and di-anionic [NhtCuPc(4-)]^2- species having long-term stability during reduction processes.

Original language	English
Pages (from-to)	385-388
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	10
Issue number	4
DOIs	https://doi.org/10.1016/j.inoche.2006.12.004
Publication status	Published - Apr 2007

Keywords

Complexation
Electrochemistry
Phthalocyanines
Spectroelectrochemistry

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10.1016/j.inoche.2006.12.004

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abstract = "A new water-soluble copper phthalocyanine, 2,9,16,23-tetrakis(4-(1-naphthoxy-4-sulfonic acid sodium salt)) phthalocyaninato copper NhtCuPc, where Nht indicates naphthoxy-4-sulfonic acid sodium salt, was synthesized and its electrochemical and spectroelectrochemical behavior were investigated in DMSO solution. The in situ spectroelectrochemical studies showed that the neutral complex exhibited the characteristic spectral changes corresponding to mono-anionic [NhtCuPc(3-)]- and di-anionic [NhtCuPc(4-)]2- species having long-term stability during reduction processes.",

keywords = "Complexation, Electrochemistry, Phthalocyanines, Spectroelectrochemistry",

author = "Sonmez Arslan and Ismail Yilmaz",

year = "2007",

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AU - Arslan, Sonmez

AU - Yilmaz, Ismail

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N2 - A new water-soluble copper phthalocyanine, 2,9,16,23-tetrakis(4-(1-naphthoxy-4-sulfonic acid sodium salt)) phthalocyaninato copper NhtCuPc, where Nht indicates naphthoxy-4-sulfonic acid sodium salt, was synthesized and its electrochemical and spectroelectrochemical behavior were investigated in DMSO solution. The in situ spectroelectrochemical studies showed that the neutral complex exhibited the characteristic spectral changes corresponding to mono-anionic [NhtCuPc(3-)]- and di-anionic [NhtCuPc(4-)]2- species having long-term stability during reduction processes.

AB - A new water-soluble copper phthalocyanine, 2,9,16,23-tetrakis(4-(1-naphthoxy-4-sulfonic acid sodium salt)) phthalocyaninato copper NhtCuPc, where Nht indicates naphthoxy-4-sulfonic acid sodium salt, was synthesized and its electrochemical and spectroelectrochemical behavior were investigated in DMSO solution. The in situ spectroelectrochemical studies showed that the neutral complex exhibited the characteristic spectral changes corresponding to mono-anionic [NhtCuPc(3-)]- and di-anionic [NhtCuPc(4-)]2- species having long-term stability during reduction processes.

KW - Complexation

KW - Electrochemistry

KW - Phthalocyanines

KW - Spectroelectrochemistry

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DO - 10.1016/j.inoche.2006.12.004

M3 - Article

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SN - 1387-7003

VL - 10

SP - 385

EP - 388

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 4

ER -

Preparation, electrochemical, and spectroelectrochemical characterization of a new water-soluble copper phthalocyanine

Abstract

Keywords

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