Preparation and characterization of UV-Cured hybrid polyvinyl alcohol nanofiber membranes by electrospinning

Bihter Zeytuncu; Süleyman Akman; Onuralp Yucel; Memetvezir Kahraman

doi:10.1590/S1516-14392014005000055

Preparation and characterization of UV-Cured hybrid polyvinyl alcohol nanofiber membranes by electrospinning

Bihter Zeytuncu, Süleyman Akman, Onuralp Yucel, Memetvezir Kahraman

Department of Metallurgical and Materials Engineering

Research output: Contribution to journal › Article › peer-review

25 Citations (Scopus)

Abstract

The present study investigated the possibility of preparing polyvinyl alcoholic (PVA) organic-inorganic hybrid nanofiber membranes by electrospinning with UV irradiation. To this end, PVA, PVA/SiO₂ organic-inorganic hybrid obtained with Geniosil^® XL 33 as a SiO₂ source, and imidazole-functionalized mesoporous PVA/SiO₂/N=N nanofiber membranes were synthesized. These membranes were characterized by Fourier transform infrared spectroscopy, scanning electron microscopy, thermogravimetric-differential thermal analysis, and Brunauer-Emmett-Teller analysis. According to results, fine polymeric nanofibers were obtained in the size range of 100-200 nm for pure PVA nanofibers and 150-250 nm for PVA/SiO ₂ hybrid nanofibers, while imidazole-functionalized PVA/SiO ₂ nanofibers were less than 100 nm. The membranes produced are suitable for use in various applications, including filtration and adsorption, in the biomedical and textile industries, among others.

Original language	English
Pages (from-to)	565-569
Number of pages	5
Journal	Materials Research
Volume	17
Issue number	3
DOIs	https://doi.org/10.1590/S1516-14392014005000055
Publication status	Published - 2014

Keywords

Electrospinning
Hybrid material
Nanofiber
Polyvinyl alcohol
UV-curable

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10.1590/S1516-14392014005000055

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title = "Preparation and characterization of UV-Cured hybrid polyvinyl alcohol nanofiber membranes by electrospinning",

abstract = "The present study investigated the possibility of preparing polyvinyl alcoholic (PVA) organic-inorganic hybrid nanofiber membranes by electrospinning with UV irradiation. To this end, PVA, PVA/SiO2 organic-inorganic hybrid obtained with Geniosil{\textregistered} XL 33 as a SiO2 source, and imidazole-functionalized mesoporous PVA/SiO2/N=N nanofiber membranes were synthesized. These membranes were characterized by Fourier transform infrared spectroscopy, scanning electron microscopy, thermogravimetric-differential thermal analysis, and Brunauer-Emmett-Teller analysis. According to results, fine polymeric nanofibers were obtained in the size range of 100-200 nm for pure PVA nanofibers and 150-250 nm for PVA/SiO 2 hybrid nanofibers, while imidazole-functionalized PVA/SiO 2 nanofibers were less than 100 nm. The membranes produced are suitable for use in various applications, including filtration and adsorption, in the biomedical and textile industries, among others.",

keywords = "Electrospinning, Hybrid material, Nanofiber, Polyvinyl alcohol, UV-curable",

author = "Bihter Zeytuncu and S{\"u}leyman Akman and Onuralp Yucel and Memetvezir Kahraman",

year = "2014",

doi = "10.1590/S1516-14392014005000055",

language = "English",

volume = "17",

pages = "565--569",

journal = "Materials Research",

issn = "1516-1439",

publisher = "Universidade Federal de Sao Carlos",

number = "3",

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T1 - Preparation and characterization of UV-Cured hybrid polyvinyl alcohol nanofiber membranes by electrospinning

AU - Zeytuncu, Bihter

AU - Akman, Süleyman

AU - Yucel, Onuralp

AU - Kahraman, Memetvezir

PY - 2014

Y1 - 2014

N2 - The present study investigated the possibility of preparing polyvinyl alcoholic (PVA) organic-inorganic hybrid nanofiber membranes by electrospinning with UV irradiation. To this end, PVA, PVA/SiO2 organic-inorganic hybrid obtained with Geniosil® XL 33 as a SiO2 source, and imidazole-functionalized mesoporous PVA/SiO2/N=N nanofiber membranes were synthesized. These membranes were characterized by Fourier transform infrared spectroscopy, scanning electron microscopy, thermogravimetric-differential thermal analysis, and Brunauer-Emmett-Teller analysis. According to results, fine polymeric nanofibers were obtained in the size range of 100-200 nm for pure PVA nanofibers and 150-250 nm for PVA/SiO 2 hybrid nanofibers, while imidazole-functionalized PVA/SiO 2 nanofibers were less than 100 nm. The membranes produced are suitable for use in various applications, including filtration and adsorption, in the biomedical and textile industries, among others.

AB - The present study investigated the possibility of preparing polyvinyl alcoholic (PVA) organic-inorganic hybrid nanofiber membranes by electrospinning with UV irradiation. To this end, PVA, PVA/SiO2 organic-inorganic hybrid obtained with Geniosil® XL 33 as a SiO2 source, and imidazole-functionalized mesoporous PVA/SiO2/N=N nanofiber membranes were synthesized. These membranes were characterized by Fourier transform infrared spectroscopy, scanning electron microscopy, thermogravimetric-differential thermal analysis, and Brunauer-Emmett-Teller analysis. According to results, fine polymeric nanofibers were obtained in the size range of 100-200 nm for pure PVA nanofibers and 150-250 nm for PVA/SiO 2 hybrid nanofibers, while imidazole-functionalized PVA/SiO 2 nanofibers were less than 100 nm. The membranes produced are suitable for use in various applications, including filtration and adsorption, in the biomedical and textile industries, among others.

KW - Electrospinning

KW - Hybrid material

KW - Nanofiber

KW - Polyvinyl alcohol

KW - UV-curable

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U2 - 10.1590/S1516-14392014005000055

DO - 10.1590/S1516-14392014005000055

M3 - Article

AN - SCOPUS:84906250416

SN - 1516-1439

VL - 17

SP - 565

EP - 569

JO - Materials Research

JF - Materials Research

IS - 3

ER -

Preparation and characterization of UV-Cured hybrid polyvinyl alcohol nanofiber membranes by electrospinning

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Keywords

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