Preparation and characterization of highly pure silica from sedge as agricultural waste and its utilization in the synthesis of mesoporous silica MCM-41

Farshid Ghorbani, Habibollah Younesi*, Zahra Mehraban, Mehmet Sabri Çelik, Ali Asghar Ghoreyshi, Mansoor Anbia

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

99 Citations (Scopus)

Abstract

Sedge (Carex riparia) is a weed which produces large quantities of agricultural waste. The objective of the present study was to develop a procedure for obtaining and characterization of amorphous silica from sedge and its application for synthesize of mesopororous silica MCM-41. Combustion of sedge was studied at different temperatures in the range of 500-800°C. The resultant silica and as-synthesized MCM-41 were characterized by X-ray diffraction (XRD), X-ray fluorescence (XRF), N2 adsorption-desorption isotherms, Fourier-transform infrared (FT-IR) spectrometry, thermogravimetric analysis (TGA), scanning electron microscopy (SEM) and Transmission electron microscopy (TEM). The x-ray diffraction pattern of the resulting silica revealed that 600°C is optimum temperature for obtaining amorphous silica. White ash, containing majority of SiO2 with trace amounts of CaO, K2O, Al2O3, MgO, P2O5, etc., was successfully produced by a combination of heating, leaching and refluxing schemes to facilitate decomposition and gasification of the organic materials while avoiding complete ignition. The XRF results revealed that the highest purity of amorphous silica (98%) was obtained by applying a combination of pretreatment of sedge using leaching and post-treatment of sedge ash with refluxing. SEM results reveals that sedge ash particles are not spherical in shape and exhibit irregularly fragmented particles. The XRD pattern of the resulting MCM-41 revealed a typical pattern of hexagonal mesophase. In agreement with the XRD, the hexagonal structure of pores of MCM-41 was confirmed by the TEM oservations. The N2 adsorption results revealed that synthesized MCM-41 having large pore sizes of about 4.1nm, high surface areas up to 1174m2/g and total pore volume of 0.98cm3/g. Through a combination of XRD, N2 adsorption and TEM methods, porosity parameters were compared.

Original languageEnglish
Pages (from-to)821-828
Number of pages8
JournalJournal of the Taiwan Institute of Chemical Engineers
Volume44
Issue number5
DOIs
Publication statusPublished - Sept 2013

Funding

The present research was sponsored by Tarbiat Modares University (TMU) and Iran Nanotechnology Initiative Council . We are grateful to Mineral Processing Engineering Department of Istanbul Technical University (ITU) for analytical and scientific supports.

FundersFunder number
Iran Nanotechnology Initiative Council
Tarbiat Modares University

    Keywords

    • Amorphous silica
    • MCM-41
    • Sedge (Carex riparia)

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