Precipitation-Redissolution Phenomena in Sulfonate-AlCl3 Solutions

P. Somasundaran; K. P. Ananthapadmanabhar; M. S. Celik

doi:10.1021/la00082a043

Precipitation-Redissolution Phenomena in Sulfonate-AlCl₃ Solutions

P. Somasundaran^*, K. P. Ananthapadmanabhar, M. S. Celik

^*Corresponding author for this work

Columbia University

Research output: Contribution to journal › Article › peer-review

49 Citations (Scopus)

Abstract

In this paper, the precipitation-redissolution behavior of AlCl₃ and the dependence of it on pH in sodium dodecyl benzenesulfonate and sodium dodecanesulfonate solutions are discussed. As in the case of bivalent metal ion-sulfonate systems, the redissolution is found to be caused by micelles. In contrast to the bivalent metal ion systems, precipitation in AlCl₃-sulfonate solutions is influenced markedly by pH. The results indicate that the competition among sulfonate monomers, micelles, and hydroxyl ions for Al species controls the system behavior. The thermodynamic solubility product for the precipitation of aluminum trisulfonates and the dependence of onset of redissolution on AlCl₃ concentration have been determined.

Original language	English
Pages (from-to)	1061-1063
Number of pages	3
Journal	Langmuir
Volume	4
Issue number	4
DOIs	https://doi.org/10.1021/la00082a043
Publication status	Published - 1 Jul 1988
Externally published	Yes

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title = "Precipitation-Redissolution Phenomena in Sulfonate-AlCl3 Solutions",

abstract = "In this paper, the precipitation-redissolution behavior of AlCl3 and the dependence of it on pH in sodium dodecyl benzenesulfonate and sodium dodecanesulfonate solutions are discussed. As in the case of bivalent metal ion-sulfonate systems, the redissolution is found to be caused by micelles. In contrast to the bivalent metal ion systems, precipitation in AlCl3-sulfonate solutions is influenced markedly by pH. The results indicate that the competition among sulfonate monomers, micelles, and hydroxyl ions for Al species controls the system behavior. The thermodynamic solubility product for the precipitation of aluminum trisulfonates and the dependence of onset of redissolution on AlCl3 concentration have been determined.",

author = "P. Somasundaran and Ananthapadmanabhar, {K. P.} and Celik, {M. S.}",

year = "1988",

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T1 - Precipitation-Redissolution Phenomena in Sulfonate-AlCl3 Solutions

AU - Somasundaran, P.

AU - Ananthapadmanabhar, K. P.

AU - Celik, M. S.

PY - 1988/7/1

Y1 - 1988/7/1

N2 - In this paper, the precipitation-redissolution behavior of AlCl3 and the dependence of it on pH in sodium dodecyl benzenesulfonate and sodium dodecanesulfonate solutions are discussed. As in the case of bivalent metal ion-sulfonate systems, the redissolution is found to be caused by micelles. In contrast to the bivalent metal ion systems, precipitation in AlCl3-sulfonate solutions is influenced markedly by pH. The results indicate that the competition among sulfonate monomers, micelles, and hydroxyl ions for Al species controls the system behavior. The thermodynamic solubility product for the precipitation of aluminum trisulfonates and the dependence of onset of redissolution on AlCl3 concentration have been determined.

AB - In this paper, the precipitation-redissolution behavior of AlCl3 and the dependence of it on pH in sodium dodecyl benzenesulfonate and sodium dodecanesulfonate solutions are discussed. As in the case of bivalent metal ion-sulfonate systems, the redissolution is found to be caused by micelles. In contrast to the bivalent metal ion systems, precipitation in AlCl3-sulfonate solutions is influenced markedly by pH. The results indicate that the competition among sulfonate monomers, micelles, and hydroxyl ions for Al species controls the system behavior. The thermodynamic solubility product for the precipitation of aluminum trisulfonates and the dependence of onset of redissolution on AlCl3 concentration have been determined.

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U2 - 10.1021/la00082a043

DO - 10.1021/la00082a043

M3 - Article

AN - SCOPUS:0024047852

SN - 0743-7463

VL - 4

SP - 1061

EP - 1063

JO - Langmuir

JF - Langmuir

IS - 4

ER -

Precipitation-Redissolution Phenomena in Sulfonate-AlCl₃ Solutions

Abstract

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