Poly(vinyl alcohol)-thioxanthone as one-component type II photoinitiator for free radical polymerization in organic and aqueous media

Senem Kork, Gorkem Yilmaz, Yusuf Yagci*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

67 Citations (Scopus)

Abstract

A novel one-component type II polymeric photoinitiator, poly(vinyl alcohol)-thioxanthone (PVA-TX), is synthesized by a simple acetalization process and characterized. PVA-TX enables photopolymerization of methyl methacrylate and acrylamide in both organic and aqueous media. Photopolymerization proceeds even in the absence of a co-initiator since PVA-TX possesses both chromophoric and hydrogen donating sites in the structure.

Original languageEnglish
Pages (from-to)923-928
Number of pages6
JournalMacromolecular Rapid Communications
Volume36
Issue number10
DOIs
Publication statusPublished - 1 May 2015

Bibliographical note

Publisher Copyright:
© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Keywords

  • Hydrogen abstraction
  • Photoinitiators
  • Poly(vinyl alcohol)
  • Polymerization
  • Thioxanthone

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