TY - JOUR
T1 - Polymers with acyloxime ester in the main chain
T2 - Synthesis, characterization and initiator properties of an azo‐containing ester initiator
AU - Onen, Aysen
AU - Denizligil, Selcuk
AU - Yagci, Yusuf
PY - 1994/4
Y1 - 1994/4
N2 - For application as initiator, a new polymeric azo‐acyloxime ester (AOE) was synthesized by condensation of 4,4′‐azobis(4‐cyanopentanoic acid chloride) (ACPC) with 1‐(4‐hydroxyphenyl)‐1,2‐propanedione‐2‐oxime (HPO). The initiator structure was confirmed by IR and NMR spectroscopy. The kinetics of the free‐radical polymerization of styrene initiated by AOE was investigated and the kinetic parameters evaluated. The initiation of polymerization of styrene by means of AOE yields polymers with photoactive acyloxime groups in the main chain.
AB - For application as initiator, a new polymeric azo‐acyloxime ester (AOE) was synthesized by condensation of 4,4′‐azobis(4‐cyanopentanoic acid chloride) (ACPC) with 1‐(4‐hydroxyphenyl)‐1,2‐propanedione‐2‐oxime (HPO). The initiator structure was confirmed by IR and NMR spectroscopy. The kinetics of the free‐radical polymerization of styrene initiated by AOE was investigated and the kinetic parameters evaluated. The initiation of polymerization of styrene by means of AOE yields polymers with photoactive acyloxime groups in the main chain.
UR - http://www.scopus.com/inward/record.url?scp=84985521877&partnerID=8YFLogxK
U2 - 10.1002/apmc.1994.052170109
DO - 10.1002/apmc.1994.052170109
M3 - Article
AN - SCOPUS:84985521877
SN - 0003-3146
VL - 217
SP - 79
EP - 89
JO - Macromolecular Materials and Engineering
JF - Macromolecular Materials and Engineering
IS - 1
ER -