Polymerization of acrylamide initiated with electrogenerated cerium (IV) in the presence of EDTA

A. Sezai Saraç; Candan Erbil; A. Bahattin Soydan

doi:10.1002/app.1992.070440515

Polymerization of acrylamide initiated with electrogenerated cerium (IV) in the presence of EDTA

A. Sezai Saraç^*, Candan Erbil, A. Bahattin Soydan

^*Corresponding author for this work

Department of Chemistry

Istanbul Technical University

Research output: Contribution to journal › Article › peer-review

55 Citations (Scopus)

Abstract

Polymerization of acrylamide was carried out with cerium (IV)‐EDTA redox initiator system with and without electrolysis. The effect of temperature, time, cerium (IV), and EDTA concentrations on the polymerization yield and molecular weight were studied and compared with electrolytic conditions. At low concentrations of cerium (IV) the electrolytic method continuously supplying Ce (IV) from Ce (III) has an advantage over the nonelectrolytic method for which polymerization did not occur under these conditions. A possible polymerization mechanism is suggested.

Original language	English
Pages (from-to)	877-881
Number of pages	5
Journal	Journal of Applied Polymer Science
Volume	44
Issue number	5
DOIs	https://doi.org/10.1002/app.1992.070440515
Publication status	Published - 15 Feb 1992

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10.1002/app.1992.070440515

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title = "Polymerization of acrylamide initiated with electrogenerated cerium (IV) in the presence of EDTA",

abstract = "Polymerization of acrylamide was carried out with cerium (IV)‐EDTA redox initiator system with and without electrolysis. The effect of temperature, time, cerium (IV), and EDTA concentrations on the polymerization yield and molecular weight were studied and compared with electrolytic conditions. At low concentrations of cerium (IV) the electrolytic method continuously supplying Ce (IV) from Ce (III) has an advantage over the nonelectrolytic method for which polymerization did not occur under these conditions. A possible polymerization mechanism is suggested.",

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T1 - Polymerization of acrylamide initiated with electrogenerated cerium (IV) in the presence of EDTA

AU - Saraç, A. Sezai

AU - Erbil, Candan

AU - Soydan, A. Bahattin

PY - 1992/2/15

Y1 - 1992/2/15

N2 - Polymerization of acrylamide was carried out with cerium (IV)‐EDTA redox initiator system with and without electrolysis. The effect of temperature, time, cerium (IV), and EDTA concentrations on the polymerization yield and molecular weight were studied and compared with electrolytic conditions. At low concentrations of cerium (IV) the electrolytic method continuously supplying Ce (IV) from Ce (III) has an advantage over the nonelectrolytic method for which polymerization did not occur under these conditions. A possible polymerization mechanism is suggested.

AB - Polymerization of acrylamide was carried out with cerium (IV)‐EDTA redox initiator system with and without electrolysis. The effect of temperature, time, cerium (IV), and EDTA concentrations on the polymerization yield and molecular weight were studied and compared with electrolytic conditions. At low concentrations of cerium (IV) the electrolytic method continuously supplying Ce (IV) from Ce (III) has an advantage over the nonelectrolytic method for which polymerization did not occur under these conditions. A possible polymerization mechanism is suggested.

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U2 - 10.1002/app.1992.070440515

DO - 10.1002/app.1992.070440515

M3 - Article

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JO - Journal of Applied Polymer Science

JF - Journal of Applied Polymer Science

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ER -

Polymerization of acrylamide initiated with electrogenerated cerium (IV) in the presence of EDTA

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