Polymerization of acrylamide initiated by the redox system Ce(IV)-4,4′-azobis (4-cyano pentanol)

Ümit Tunca; I. Ersin Serhatli; Yusuf Yağci

doi:10.1007/BF00718923

Polymerization of acrylamide initiated by the redox system Ce(IV)-4,4′-azobis (4-cyano pentanol)

Ümit Tunca, I. Ersin Serhatli, Yusuf Yağci^*

^*Corresponding author for this work

Department of Chemistry

Istanbul Technical University

Research output: Contribution to journal › Article › peer-review

43 Citations (Scopus)

Abstract

Acrylamide was polymerized by eeric ion Ce (IV)-4,4′-azobis(4-cyano pentanol)(ACP) redox pair in aqueous nitric acid under nitrogen atmosphere. The rate of polymerization is proportional to [M] ² ,[ACP] and [Ce(IV)] ^-1 . Termination mechanism which was exclusively linear offered one azo group per polymeric chain. The obtained polyacrylamide can be used as a water soluble initiator for vinyl polymerization.

Original language	English
Pages (from-to)	483-488
Number of pages	6
Journal	Polymer Bulletin
Volume	22
Issue number	5-6
DOIs	https://doi.org/10.1007/BF00718923
Publication status	Published - Dec 1989

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10.1007/BF00718923

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title = "Polymerization of acrylamide initiated by the redox system Ce(IV)-4,4′-azobis (4-cyano pentanol)",

abstract = " Acrylamide was polymerized by eeric ion Ce (IV)-4,4′-azobis(4-cyano pentanol)(ACP) redox pair in aqueous nitric acid under nitrogen atmosphere. The rate of polymerization is proportional to [M] 2 ,[ACP] and [Ce(IV)] -1 . Termination mechanism which was exclusively linear offered one azo group per polymeric chain. The obtained polyacrylamide can be used as a water soluble initiator for vinyl polymerization.",

author = "{\"U}mit Tunca and \{Ersin Serhatli\}, I. and Yusuf Yağci",

year = "1989",

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pages = "483--488",

journal = "Polymer Bulletin",

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T1 - Polymerization of acrylamide initiated by the redox system Ce(IV)-4,4′-azobis (4-cyano pentanol)

AU - Tunca, Ümit

AU - Ersin Serhatli, I.

AU - Yağci, Yusuf

PY - 1989/12

Y1 - 1989/12

N2 - Acrylamide was polymerized by eeric ion Ce (IV)-4,4′-azobis(4-cyano pentanol)(ACP) redox pair in aqueous nitric acid under nitrogen atmosphere. The rate of polymerization is proportional to [M] 2 ,[ACP] and [Ce(IV)] -1 . Termination mechanism which was exclusively linear offered one azo group per polymeric chain. The obtained polyacrylamide can be used as a water soluble initiator for vinyl polymerization.

AB - Acrylamide was polymerized by eeric ion Ce (IV)-4,4′-azobis(4-cyano pentanol)(ACP) redox pair in aqueous nitric acid under nitrogen atmosphere. The rate of polymerization is proportional to [M] 2 ,[ACP] and [Ce(IV)] -1 . Termination mechanism which was exclusively linear offered one azo group per polymeric chain. The obtained polyacrylamide can be used as a water soluble initiator for vinyl polymerization.

UR - https://www.scopus.com/pages/publications/0024899665

U2 - 10.1007/BF00718923

DO - 10.1007/BF00718923

M3 - Article

AN - SCOPUS:0024899665

SN - 0170-0839

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EP - 488

JO - Polymer Bulletin

JF - Polymer Bulletin

IS - 5-6

ER -

Polymerization of acrylamide initiated by the redox system Ce(IV)-4,4′-azobis (4-cyano pentanol)

Abstract

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