Polymer supported amino bis-(cis-propan 2,3 diol) functions for removal of trace boron from water

Niyazi Bicak; Mustafa Gazi; Bahire Filiz Senkal

doi:10.1016/j.reactfunctpolym.2005.01.010

Polymer supported amino bis-(cis-propan 2,3 diol) functions for removal of trace boron from water

Niyazi Bicak^*
, Mustafa Gazi
, Bahire Filiz Senkal

^*Corresponding author for this work

Department of Chemistry

Istanbul Technical University

Research output: Contribution to journal › Conference article › peer-review

40 Citations (Scopus)

Abstract

Reaction of diallylamine with crosslinked terpolymer beads of glycidyl metacrylate-methyl methacrylate-ethylene glycol dimethacrylate yields corresponding polymers with diallylamino functions (2.4 mmol g^-1). Cis-dihydroxylation of the allyl groups with hydrogen peroxide, in presence of OsO₄ catalyst yields polymer supported amino-bis(cis-propane 2,3-diol) functions with 81.7% of conversion yields. The resulting polymer resin having vicinal cis-diol functions is a high capacity (1.77 mmol g ^-1) boron-specific sorbent and useful for extraction of of trace boric acid (105.1 ppm) from aqueous solutions in about 20 min.

Original language	English
Pages (from-to)	143-148
Number of pages	6
Journal	Reactive and Functional Polymers
Volume	65
Issue number	1-2
DOIs	https://doi.org/10.1016/j.reactfunctpolym.2005.01.010
Publication status	Published - Nov 2005
Event	Proceedings of the 11th International Conference on Polymers and Organic Chemistry (POC'04) - Duration: 18 Jul 2004 → 23 Jul 2004

Keywords

Boron removal
Cis-dihydroxylation
Glycidyl methacrylate
Polymeric sorbent

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10.1016/j.reactfunctpolym.2005.01.010

Cite this

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title = "Polymer supported amino bis-(cis-propan 2,3 diol) functions for removal of trace boron from water",

abstract = "Reaction of diallylamine with crosslinked terpolymer beads of glycidyl metacrylate-methyl methacrylate-ethylene glycol dimethacrylate yields corresponding polymers with diallylamino functions (2.4 mmol g-1). Cis-dihydroxylation of the allyl groups with hydrogen peroxide, in presence of OsO4 catalyst yields polymer supported amino-bis(cis-propane 2,3-diol) functions with 81.7\% of conversion yields. The resulting polymer resin having vicinal cis-diol functions is a high capacity (1.77 mmol g -1) boron-specific sorbent and useful for extraction of of trace boric acid (105.1 ppm) from aqueous solutions in about 20 min.",

keywords = "Boron removal, Cis-dihydroxylation, Glycidyl methacrylate, Polymeric sorbent",

author = "Niyazi Bicak and Mustafa Gazi and Senkal, \{Bahire Filiz\}",

year = "2005",

month = nov,

doi = "10.1016/j.reactfunctpolym.2005.01.010",

language = "English",

volume = "65",

pages = "143--148",

journal = "Reactive and Functional Polymers",

issn = "1381-5148",

publisher = "Elsevier B.V.",

number = "1-2",

note = "Proceedings of the 11th International Conference on Polymers and Organic Chemistry (POC'04) ; Conference date: 18-07-2004 Through 23-07-2004",

}

TY - JOUR

T1 - Polymer supported amino bis-(cis-propan 2,3 diol) functions for removal of trace boron from water

AU - Bicak, Niyazi

AU - Gazi, Mustafa

AU - Senkal, Bahire Filiz

PY - 2005/11

Y1 - 2005/11

N2 - Reaction of diallylamine with crosslinked terpolymer beads of glycidyl metacrylate-methyl methacrylate-ethylene glycol dimethacrylate yields corresponding polymers with diallylamino functions (2.4 mmol g-1). Cis-dihydroxylation of the allyl groups with hydrogen peroxide, in presence of OsO4 catalyst yields polymer supported amino-bis(cis-propane 2,3-diol) functions with 81.7% of conversion yields. The resulting polymer resin having vicinal cis-diol functions is a high capacity (1.77 mmol g -1) boron-specific sorbent and useful for extraction of of trace boric acid (105.1 ppm) from aqueous solutions in about 20 min.

AB - Reaction of diallylamine with crosslinked terpolymer beads of glycidyl metacrylate-methyl methacrylate-ethylene glycol dimethacrylate yields corresponding polymers with diallylamino functions (2.4 mmol g-1). Cis-dihydroxylation of the allyl groups with hydrogen peroxide, in presence of OsO4 catalyst yields polymer supported amino-bis(cis-propane 2,3-diol) functions with 81.7% of conversion yields. The resulting polymer resin having vicinal cis-diol functions is a high capacity (1.77 mmol g -1) boron-specific sorbent and useful for extraction of of trace boric acid (105.1 ppm) from aqueous solutions in about 20 min.

KW - Boron removal

KW - Cis-dihydroxylation

KW - Glycidyl methacrylate

KW - Polymeric sorbent

UR - https://www.scopus.com/pages/publications/27144451417

U2 - 10.1016/j.reactfunctpolym.2005.01.010

DO - 10.1016/j.reactfunctpolym.2005.01.010

M3 - Conference article

AN - SCOPUS:27144451417

SN - 1381-5148

VL - 65

SP - 143

EP - 148

JO - Reactive and Functional Polymers

JF - Reactive and Functional Polymers

IS - 1-2

T2 - Proceedings of the 11th International Conference on Polymers and Organic Chemistry (POC'04)

Y2 - 18 July 2004 through 23 July 2004

ER -

Polymer supported amino bis-(cis-propan 2,3 diol) functions for removal of trace boron from water

Abstract

Keywords

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