TY - JOUR
T1 - Polyaminocarboxylic acids–Ce(IV) redox systems as an initiator in acrylamide polymerization
AU - Erbil, Candan
AU - Cin, Canan
AU - Soydan, A. Bahattin
AU - Sarac, A. Sezai
PY - 1993/3/5
Y1 - 1993/3/5
N2 - Acrylamide polymerization by Ce(IV)‐polyaminocarboxylic acids, i.e., EDTA, DTPA, EGTA, and NTA, which have strong chelating properties, have been studied at different [H+], initiator concentration, and reaction time. Initiation of polymerization proceeds through the formation of the free radical after decarboxylation of the carboxyl group of polyaminocarboxylic acid. Results also indicate that the termination of the polymerization reaction is mainly mutual termination. Decrease of the rate of disappearance of the cerium(IV) is in the order of DTPA ≥ EDTA > NTA > EGTA. © 1993 John Wiley & Sons, Inc.
AB - Acrylamide polymerization by Ce(IV)‐polyaminocarboxylic acids, i.e., EDTA, DTPA, EGTA, and NTA, which have strong chelating properties, have been studied at different [H+], initiator concentration, and reaction time. Initiation of polymerization proceeds through the formation of the free radical after decarboxylation of the carboxyl group of polyaminocarboxylic acid. Results also indicate that the termination of the polymerization reaction is mainly mutual termination. Decrease of the rate of disappearance of the cerium(IV) is in the order of DTPA ≥ EDTA > NTA > EGTA. © 1993 John Wiley & Sons, Inc.
UR - http://www.scopus.com/inward/record.url?scp=0027909050&partnerID=8YFLogxK
U2 - 10.1002/app.1993.070470911
DO - 10.1002/app.1993.070470911
M3 - Article
AN - SCOPUS:0027909050
SN - 0021-8995
VL - 47
SP - 1643
EP - 1648
JO - Journal of Applied Polymer Science
JF - Journal of Applied Polymer Science
IS - 9
ER -