Phthalocyanines with rigid carboxylic acid containing pendant arms

Ayfer Kalkan; Zehra Altuntaş Bayir

doi:10.1016/j.poly.2005.06.056

Phthalocyanines with rigid carboxylic acid containing pendant arms

Ayfer Kalkan, Zehra Altuntaş Bayir^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

34 Citations (Scopus)

Abstract

Metal-free and metallophthalocyanines (Zn, Co) substituted with four carboxybiphenyloxy groups on the peripheral positions were prepared from 4-(4′-carboxybiphenyloxy)phthalonitrile. Esterification of all of the biphenylcarboxylic acid groups of metal-free phthalocyanine with hexanol afforded 2,9,16,23-tetrakis(4′-carbhexyloxybiphenyloxy) phthalocyanine. These new compounds have been characterised by ¹H NMR, ¹³C NMR, FT-IR, UV-Vis and mass spectroscopies.

Original language	English
Pages (from-to)	39-42
Number of pages	4
Journal	Polyhedron
Volume	25
Issue number	1
DOIs	https://doi.org/10.1016/j.poly.2005.06.056
Publication status	Published - 2 Jan 2006

Funding

This work was supported by the Research Fund of the Technical University of Istanbul and State Planning Organization (DPT).

Funders	Funder number
DPT
Technical University of Istanbul and State Planning Organization

Keywords

Biphenylcarboxylic acid
Cobalt
Phthalocyanine
Zinc

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10.1016/j.poly.2005.06.056

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abstract = "Metal-free and metallophthalocyanines (Zn, Co) substituted with four carboxybiphenyloxy groups on the peripheral positions were prepared from 4-(4′-carboxybiphenyloxy)phthalonitrile. Esterification of all of the biphenylcarboxylic acid groups of metal-free phthalocyanine with hexanol afforded 2,9,16,23-tetrakis(4′-carbhexyloxybiphenyloxy) phthalocyanine. These new compounds have been characterised by 1H NMR, 13C NMR, FT-IR, UV-Vis and mass spectroscopies.",

keywords = "Biphenylcarboxylic acid, Cobalt, Phthalocyanine, Zinc",

author = "Ayfer Kalkan and Bayir, {Zehra Altunta{\c s}}",

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AU - Kalkan, Ayfer

AU - Bayir, Zehra Altuntaş

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N2 - Metal-free and metallophthalocyanines (Zn, Co) substituted with four carboxybiphenyloxy groups on the peripheral positions were prepared from 4-(4′-carboxybiphenyloxy)phthalonitrile. Esterification of all of the biphenylcarboxylic acid groups of metal-free phthalocyanine with hexanol afforded 2,9,16,23-tetrakis(4′-carbhexyloxybiphenyloxy) phthalocyanine. These new compounds have been characterised by 1H NMR, 13C NMR, FT-IR, UV-Vis and mass spectroscopies.

AB - Metal-free and metallophthalocyanines (Zn, Co) substituted with four carboxybiphenyloxy groups on the peripheral positions were prepared from 4-(4′-carboxybiphenyloxy)phthalonitrile. Esterification of all of the biphenylcarboxylic acid groups of metal-free phthalocyanine with hexanol afforded 2,9,16,23-tetrakis(4′-carbhexyloxybiphenyloxy) phthalocyanine. These new compounds have been characterised by 1H NMR, 13C NMR, FT-IR, UV-Vis and mass spectroscopies.

KW - Biphenylcarboxylic acid

KW - Cobalt

KW - Phthalocyanine

KW - Zinc

UR - http://www.scopus.com/inward/record.url?scp=29144516267&partnerID=8YFLogxK

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DO - 10.1016/j.poly.2005.06.056

M3 - Article

AN - SCOPUS:29144516267

SN - 0277-5387

VL - 25

SP - 39

EP - 42

JO - Polyhedron

JF - Polyhedron

IS - 1

ER -

Phthalocyanines with rigid carboxylic acid containing pendant arms

Abstract

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Keywords

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