Photopolymerization of enzymatically synthesized methacrylated poly(caprolactone) with poly(ethylene glycol) macromonomer

Nazif Ugur Kaya; Didem Saloglu; Yuksel Guvenilir

doi:10.1080/10601325.2019.1594891

Photopolymerization of enzymatically synthesized methacrylated poly(caprolactone) with poly(ethylene glycol) macromonomer

Nazif Ugur Kaya^*, Didem Saloglu, Yuksel Guvenilir

^*Corresponding author for this work

Department of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

Polycaprolactone (PCL) based α,ω-methacrylated macromonomer (DMPCL) was synthesized via enzymatic ring-opening polymerization (eROP) by using Novozyme 435 as the enzyme immobilized catalyst. DMPCL was further photopolymerized with monofunctional poly(ethylene glycol) methyl ether methacrylate (PEGMA-950) macromonomer and trimethylolpropane triacrylate (TMPTA) as tri-functionalized crosslinking agent in glass vials when CHCl₃ was the solvent and Irgacure 819 was the photoinitiator. Ultraviolet (UV) Light Emitting Diode (LED) bulbs enabled photoinduced reactions at room temperature with low heat generation and high reaction efficiency. The obtained gels were characterized with Fourier Transform Infrared Spectroscopy (FT-IR) and Differential Scanning Calorimetry (DSC). DMPCL participated as an effective crosslinking agent in the photopolymerization of PEGMA-950. Combined usage of DMPCL and PEGMA-950 resulted in significantly more effective polymerization than the separate photopolymerizations of these macromonomers.

Original language	English
Pages (from-to)	658-666
Number of pages	9
Journal	Journal of Macromolecular Science - Pure and Applied Chemistry
Volume	56
Issue number	7
DOIs	https://doi.org/10.1080/10601325.2019.1594891
Publication status	Published - 3 Jul 2019

Bibliographical note

Publisher Copyright:
© 2019, © 2019 Taylor & Francis Group, LLC.

Keywords

Biopolymer
enzymatic ring-opening polymerization (eROP)
macromonomer
methacrylate end-group
photopolymerization
polycaprolactone
polyethyleneglycol

Access to Document

10.1080/10601325.2019.1594891

Cite this

@article{7b4f7f8d31ce4dcca0893e8f7bbd4e6a,

title = "Photopolymerization of enzymatically synthesized methacrylated poly(caprolactone) with poly(ethylene glycol) macromonomer",

abstract = "Polycaprolactone (PCL) based α,ω-methacrylated macromonomer (DMPCL) was synthesized via enzymatic ring-opening polymerization (eROP) by using Novozyme 435 as the enzyme immobilized catalyst. DMPCL was further photopolymerized with monofunctional poly(ethylene glycol) methyl ether methacrylate (PEGMA-950) macromonomer and trimethylolpropane triacrylate (TMPTA) as tri-functionalized crosslinking agent in glass vials when CHCl3 was the solvent and Irgacure 819 was the photoinitiator. Ultraviolet (UV) Light Emitting Diode (LED) bulbs enabled photoinduced reactions at room temperature with low heat generation and high reaction efficiency. The obtained gels were characterized with Fourier Transform Infrared Spectroscopy (FT-IR) and Differential Scanning Calorimetry (DSC). DMPCL participated as an effective crosslinking agent in the photopolymerization of PEGMA-950. Combined usage of DMPCL and PEGMA-950 resulted in significantly more effective polymerization than the separate photopolymerizations of these macromonomers.",

keywords = "Biopolymer, enzymatic ring-opening polymerization (eROP), macromonomer, methacrylate end-group, photopolymerization, polycaprolactone, polyethyleneglycol",

author = "Kaya, {Nazif Ugur} and Didem Saloglu and Yuksel Guvenilir",

note = "Publisher Copyright: {\textcopyright} 2019, {\textcopyright} 2019 Taylor & Francis Group, LLC.",

year = "2019",

month = jul,

day = "3",

doi = "10.1080/10601325.2019.1594891",

language = "English",

volume = "56",

pages = "658--666",

journal = "Journal of Macromolecular Science - Pure and Applied Chemistry",

issn = "1060-1325",

publisher = "Taylor and Francis Ltd.",

number = "7",

}

TY - JOUR

T1 - Photopolymerization of enzymatically synthesized methacrylated poly(caprolactone) with poly(ethylene glycol) macromonomer

AU - Kaya, Nazif Ugur

AU - Saloglu, Didem

AU - Guvenilir, Yuksel

PY - 2019/7/3

Y1 - 2019/7/3

N2 - Polycaprolactone (PCL) based α,ω-methacrylated macromonomer (DMPCL) was synthesized via enzymatic ring-opening polymerization (eROP) by using Novozyme 435 as the enzyme immobilized catalyst. DMPCL was further photopolymerized with monofunctional poly(ethylene glycol) methyl ether methacrylate (PEGMA-950) macromonomer and trimethylolpropane triacrylate (TMPTA) as tri-functionalized crosslinking agent in glass vials when CHCl3 was the solvent and Irgacure 819 was the photoinitiator. Ultraviolet (UV) Light Emitting Diode (LED) bulbs enabled photoinduced reactions at room temperature with low heat generation and high reaction efficiency. The obtained gels were characterized with Fourier Transform Infrared Spectroscopy (FT-IR) and Differential Scanning Calorimetry (DSC). DMPCL participated as an effective crosslinking agent in the photopolymerization of PEGMA-950. Combined usage of DMPCL and PEGMA-950 resulted in significantly more effective polymerization than the separate photopolymerizations of these macromonomers.

AB - Polycaprolactone (PCL) based α,ω-methacrylated macromonomer (DMPCL) was synthesized via enzymatic ring-opening polymerization (eROP) by using Novozyme 435 as the enzyme immobilized catalyst. DMPCL was further photopolymerized with monofunctional poly(ethylene glycol) methyl ether methacrylate (PEGMA-950) macromonomer and trimethylolpropane triacrylate (TMPTA) as tri-functionalized crosslinking agent in glass vials when CHCl3 was the solvent and Irgacure 819 was the photoinitiator. Ultraviolet (UV) Light Emitting Diode (LED) bulbs enabled photoinduced reactions at room temperature with low heat generation and high reaction efficiency. The obtained gels were characterized with Fourier Transform Infrared Spectroscopy (FT-IR) and Differential Scanning Calorimetry (DSC). DMPCL participated as an effective crosslinking agent in the photopolymerization of PEGMA-950. Combined usage of DMPCL and PEGMA-950 resulted in significantly more effective polymerization than the separate photopolymerizations of these macromonomers.

KW - Biopolymer

KW - enzymatic ring-opening polymerization (eROP)

KW - macromonomer

KW - methacrylate end-group

KW - photopolymerization

KW - polycaprolactone

KW - polyethyleneglycol

UR - http://www.scopus.com/inward/record.url?scp=85065073725&partnerID=8YFLogxK

U2 - 10.1080/10601325.2019.1594891

DO - 10.1080/10601325.2019.1594891

M3 - Article

AN - SCOPUS:85065073725

SN - 1060-1325

VL - 56

SP - 658

EP - 666

JO - Journal of Macromolecular Science - Pure and Applied Chemistry

JF - Journal of Macromolecular Science - Pure and Applied Chemistry

IS - 7

ER -

Photopolymerization of enzymatically synthesized methacrylated poly(caprolactone) with poly(ethylene glycol) macromonomer

Abstract

Bibliographical note

Keywords

Access to Document

Other files and links

Fingerprint

Cite this