Photoinitiated polymerization of ethyl cyanoacrylate by phosphonium salts

Ayşen Önen; Nergis Arsu; Yusuf Yaǧci

doi:10.1002/(SICI)1522-9505(19990201)264:1<56::AID-APMC56>3.0.CO;2-5

Photoinitiated polymerization of ethyl cyanoacrylate by phosphonium salts

Ayşen Önen, Nergis Arsu, Yusuf Yaǧci^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

42 Citations (Scopus)

Abstract

The photoinitiated polymerization of ethyl cyanoacrylate (ECA) by benzyl triphenylphosphonium hexafluoroantimonate (BP⁺) and (anthracen-9-ylmethyl)triphenylphosphonium hexafluoroantimonate (MAP⁺) was studied. Zwitterionic and free radical mechanisms which involved homolytic and heterolytic decomposition of the phosphonium salts are discussed. The anthracene-sensitized photopolymerization of ECA was also demonstrated.

Original language	English
Pages (from-to)	56-59
Number of pages	4
Journal	Angewandte Makromolekulare Chemie
Volume	264
DOIs	https://doi.org/10.1002/(SICI)1522-9505(19990201)264:1<56::AID-APMC56>3.0.CO;2-5
Publication status	Published - Feb 1999

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10.1002/(SICI)1522-9505(19990201)264:1<56::AID-APMC56>3.0.CO;2-5

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abstract = "The photoinitiated polymerization of ethyl cyanoacrylate (ECA) by benzyl triphenylphosphonium hexafluoroantimonate (BP+) and (anthracen-9-ylmethyl)triphenylphosphonium hexafluoroantimonate (MAP+) was studied. Zwitterionic and free radical mechanisms which involved homolytic and heterolytic decomposition of the phosphonium salts are discussed. The anthracene-sensitized photopolymerization of ECA was also demonstrated.",

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AU - Arsu, Nergis

AU - Yaǧci, Yusuf

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Y1 - 1999/2

N2 - The photoinitiated polymerization of ethyl cyanoacrylate (ECA) by benzyl triphenylphosphonium hexafluoroantimonate (BP+) and (anthracen-9-ylmethyl)triphenylphosphonium hexafluoroantimonate (MAP+) was studied. Zwitterionic and free radical mechanisms which involved homolytic and heterolytic decomposition of the phosphonium salts are discussed. The anthracene-sensitized photopolymerization of ECA was also demonstrated.

AB - The photoinitiated polymerization of ethyl cyanoacrylate (ECA) by benzyl triphenylphosphonium hexafluoroantimonate (BP+) and (anthracen-9-ylmethyl)triphenylphosphonium hexafluoroantimonate (MAP+) was studied. Zwitterionic and free radical mechanisms which involved homolytic and heterolytic decomposition of the phosphonium salts are discussed. The anthracene-sensitized photopolymerization of ECA was also demonstrated.

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DO - 10.1002/(SICI)1522-9505(19990201)264:1<56::AID-APMC56>3.0.CO;2-5

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JO - Angewandte Makromolekulare Chemie

JF - Angewandte Makromolekulare Chemie

ER -

Photoinitiated polymerization of ethyl cyanoacrylate by phosphonium salts

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