Abstract
A novel phenacyl anilinium salt, N-phenacyl, N,N-dimethylanilinium hexafluoroantimonate, (PDA), has been synthesized and used as photoinitiator for cationic polymerization of cyclohexene oxide (CHO), butyl vinyl ether (BVE) and N-vinyl carbazol (NVC). Plausible mechanism of the photoinitiation involves the decay of the excited PDA with both heterolytic and homolytic cleavages of carbon-nitrogen bond. Thus, phenacylium cations formed directly or subsequent intermolecular electron transfer, respectively, initiate the polymerization.
| Original language | English |
|---|---|
| Pages (from-to) | 2575-2579 |
| Number of pages | 5 |
| Journal | Polymer |
| Volume | 43 |
| Issue number | 8 |
| DOIs | |
| Publication status | Published - 18 Feb 2002 |
Funding
The authors would like to thank Istanbul Technical University, Research Fund and Turkish State Planning Association (DPT) for financial support.
| Funders |
|---|
| DPT |
| Turkish State Planning Association |
| Istanbul Teknik Üniversitesi |
Keywords
- Phenacyl anilinium salt
- Photoinitiated cationic polymerization
Fingerprint
Dive into the research topics of 'Photoinitiated cationic polymerization using a novel phenacyl anilinium salt'. Together they form a unique fingerprint.Cite this
- APA
- Author
- BIBTEX
- Harvard
- Standard
- RIS
- Vancouver