Photoinitiated cationic polymerization using a novel phenacyl anilinium salt

Fatmanur Kasapoglu; Aysen Onen; Niyazi Bicak; Yusuf Yagci

doi:10.1016/S0032-3861(02)00029-0

Photoinitiated cationic polymerization using a novel phenacyl anilinium salt

Fatmanur Kasapoglu, Aysen Onen, Niyazi Bicak, Yusuf Yagci^*

^*Corresponding author for this work

Department of Chemistry

Istanbul Technical University

Research output: Contribution to journal › Article › peer-review

42 Citations (Scopus)

Abstract

A novel phenacyl anilinium salt, N-phenacyl, N,N-dimethylanilinium hexafluoroantimonate, (PDA), has been synthesized and used as photoinitiator for cationic polymerization of cyclohexene oxide (CHO), butyl vinyl ether (BVE) and N-vinyl carbazol (NVC). Plausible mechanism of the photoinitiation involves the decay of the excited PDA with both heterolytic and homolytic cleavages of carbon-nitrogen bond. Thus, phenacylium cations formed directly or subsequent intermolecular electron transfer, respectively, initiate the polymerization.

Original language	English
Pages (from-to)	2575-2579
Number of pages	5
Journal	Polymer
Volume	43
Issue number	8
DOIs	https://doi.org/10.1016/S0032-3861(02)00029-0
Publication status	Published - 18 Feb 2002

Funding

The authors would like to thank Istanbul Technical University, Research Fund and Turkish State Planning Association (DPT) for financial support.

Funders	Funder number
DPT
Turkish State Planning Association
Istanbul Teknik Üniversitesi

Keywords

Phenacyl anilinium salt
Photoinitiated cationic polymerization

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10.1016/S0032-3861(02)00029-0

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title = "Photoinitiated cationic polymerization using a novel phenacyl anilinium salt",

abstract = "A novel phenacyl anilinium salt, N-phenacyl, N,N-dimethylanilinium hexafluoroantimonate, (PDA), has been synthesized and used as photoinitiator for cationic polymerization of cyclohexene oxide (CHO), butyl vinyl ether (BVE) and N-vinyl carbazol (NVC). Plausible mechanism of the photoinitiation involves the decay of the excited PDA with both heterolytic and homolytic cleavages of carbon-nitrogen bond. Thus, phenacylium cations formed directly or subsequent intermolecular electron transfer, respectively, initiate the polymerization.",

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T1 - Photoinitiated cationic polymerization using a novel phenacyl anilinium salt

AU - Kasapoglu, Fatmanur

AU - Onen, Aysen

AU - Bicak, Niyazi

AU - Yagci, Yusuf

PY - 2002/2/18

Y1 - 2002/2/18

N2 - A novel phenacyl anilinium salt, N-phenacyl, N,N-dimethylanilinium hexafluoroantimonate, (PDA), has been synthesized and used as photoinitiator for cationic polymerization of cyclohexene oxide (CHO), butyl vinyl ether (BVE) and N-vinyl carbazol (NVC). Plausible mechanism of the photoinitiation involves the decay of the excited PDA with both heterolytic and homolytic cleavages of carbon-nitrogen bond. Thus, phenacylium cations formed directly or subsequent intermolecular electron transfer, respectively, initiate the polymerization.

AB - A novel phenacyl anilinium salt, N-phenacyl, N,N-dimethylanilinium hexafluoroantimonate, (PDA), has been synthesized and used as photoinitiator for cationic polymerization of cyclohexene oxide (CHO), butyl vinyl ether (BVE) and N-vinyl carbazol (NVC). Plausible mechanism of the photoinitiation involves the decay of the excited PDA with both heterolytic and homolytic cleavages of carbon-nitrogen bond. Thus, phenacylium cations formed directly or subsequent intermolecular electron transfer, respectively, initiate the polymerization.

KW - Phenacyl anilinium salt

KW - Photoinitiated cationic polymerization

UR - https://www.scopus.com/pages/publications/0037127989

U2 - 10.1016/S0032-3861(02)00029-0

DO - 10.1016/S0032-3861(02)00029-0

M3 - Article

AN - SCOPUS:0037127989

SN - 0032-3861

VL - 43

SP - 2575

EP - 2579

JO - Polymer

JF - Polymer

IS - 8

ER -

Photoinitiated cationic polymerization using a novel phenacyl anilinium salt

Abstract

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Keywords

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