Photoinduced cross-linking polymerization of monofunctional vinyl monomer without conventional photoinitiator and cross-linker

Mehmet Atilla Tasdelen, Volkan Kumbaraci, Naciye Talinli*, Yusuf Yagci

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

42 Citations (Scopus)

Abstract

A study was conducted to demonstrate strategies that performed photoinduced cross-linking polymerization of monofunctional vinyl monomer, without conventional photoinitiator and cross-linker. The technique was most widely employed in coating industries, as vinyl monomers were effectively polymerized with the method. The strategies for photoinduced cross-linking were divided into two stages, such as one-stage crosslinking of of multifunctional monomers or copolymerization with difunctional monomers and two-stage cross-linking through polymers possessing photosensitive sites. A set of structurally designed bisbenzodioxinones was used in the polymerization process that liberated both the photoinitiator and cross-linker after simulation by light.

Original languageEnglish
Pages (from-to)4406-4408
Number of pages3
JournalMacromolecules
Volume40
Issue number13
DOIs
Publication statusPublished - 26 Jun 2007

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