Photoinduced Controlled/Living Polymerizations

Cansu Aydogan; Gorkem Yilmaz; Ataulla Shegiwal; David M. Haddleton; Yusuf Yagci

doi:10.1002/anie.202117377

Photoinduced Controlled/Living Polymerizations

Cansu Aydogan, Gorkem Yilmaz, Ataulla Shegiwal, David M. Haddleton^*, Yusuf Yagci^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Review article › peer-review

99 Citations (Scopus)

Abstract

The application of photochemistry in polymer synthesis is of interest due to the unique possibilities offered compared to thermochemistry, including topological and temporal control, rapid polymerization, sustainable low-energy processes, and environmentally benign features leading to established and emerging applications in adhesives, coatings, adaptive manufacturing, etc. In particular, the utilization of photochemistry in controlled/living polymerizations often offers the capability for precise control over the macromolecular structure and chain length in addition to the associated advantages of photochemistry. Herein, the latest developments in photocontrolled living radical and cationic polymerizations and their combinations for application in polymer syntheses are discussed. This Review summarizes and highlights recent studies in the emerging area of photoinduced controlled/living polymerizations. A discussion of mechanistic details highlights differences as well as parallels between different systems for different polymerization methods and monomer applicability.

Original language	English
Article number	e202117377
Journal	Angewandte Chemie - International Edition
Volume	61
Issue number	23
DOIs	https://doi.org/10.1002/anie.202117377
Publication status	Published - 7 Jun 2022

Bibliographical note

Publisher Copyright:
© 2022 Wiley-VCH GmbH.

Funding

C.A. is grateful for the financial support from the Scientific and Technological Research Council of Turkey (TUBITAK, BIDEB‐2219 International Postdoctoral Research Scholarship Program). We would like to acknowledge the financial support from The Scientific and Technological Research Council of Turkey (Project Number: 120C121) and Istanbul Technical University Research Fund.

Funders	Funder number
TUBITAK
Türkiye Bilimsel ve Teknolojik Araştirma Kurumu	120C121
Istanbul Teknik Üniversitesi

Keywords

Cationic Polymerization
Free-Radical Polymerization
Mechanistic Transformations
Photoinduced Controlled Living Polymerization

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1002/anie.202117377

Cite this

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title = "Photoinduced Controlled/Living Polymerizations",

abstract = "The application of photochemistry in polymer synthesis is of interest due to the unique possibilities offered compared to thermochemistry, including topological and temporal control, rapid polymerization, sustainable low-energy processes, and environmentally benign features leading to established and emerging applications in adhesives, coatings, adaptive manufacturing, etc. In particular, the utilization of photochemistry in controlled/living polymerizations often offers the capability for precise control over the macromolecular structure and chain length in addition to the associated advantages of photochemistry. Herein, the latest developments in photocontrolled living radical and cationic polymerizations and their combinations for application in polymer syntheses are discussed. This Review summarizes and highlights recent studies in the emerging area of photoinduced controlled/living polymerizations. A discussion of mechanistic details highlights differences as well as parallels between different systems for different polymerization methods and monomer applicability.",

keywords = "Cationic Polymerization, Free-Radical Polymerization, Mechanistic Transformations, Photoinduced Controlled Living Polymerization",

author = "Cansu Aydogan and Gorkem Yilmaz and Ataulla Shegiwal and Haddleton, {David M.} and Yusuf Yagci",

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doi = "10.1002/anie.202117377",

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AU - Aydogan, Cansu

AU - Yilmaz, Gorkem

AU - Shegiwal, Ataulla

AU - Haddleton, David M.

AU - Yagci, Yusuf

PY - 2022/6/7

Y1 - 2022/6/7

N2 - The application of photochemistry in polymer synthesis is of interest due to the unique possibilities offered compared to thermochemistry, including topological and temporal control, rapid polymerization, sustainable low-energy processes, and environmentally benign features leading to established and emerging applications in adhesives, coatings, adaptive manufacturing, etc. In particular, the utilization of photochemistry in controlled/living polymerizations often offers the capability for precise control over the macromolecular structure and chain length in addition to the associated advantages of photochemistry. Herein, the latest developments in photocontrolled living radical and cationic polymerizations and their combinations for application in polymer syntheses are discussed. This Review summarizes and highlights recent studies in the emerging area of photoinduced controlled/living polymerizations. A discussion of mechanistic details highlights differences as well as parallels between different systems for different polymerization methods and monomer applicability.

AB - The application of photochemistry in polymer synthesis is of interest due to the unique possibilities offered compared to thermochemistry, including topological and temporal control, rapid polymerization, sustainable low-energy processes, and environmentally benign features leading to established and emerging applications in adhesives, coatings, adaptive manufacturing, etc. In particular, the utilization of photochemistry in controlled/living polymerizations often offers the capability for precise control over the macromolecular structure and chain length in addition to the associated advantages of photochemistry. Herein, the latest developments in photocontrolled living radical and cationic polymerizations and their combinations for application in polymer syntheses are discussed. This Review summarizes and highlights recent studies in the emerging area of photoinduced controlled/living polymerizations. A discussion of mechanistic details highlights differences as well as parallels between different systems for different polymerization methods and monomer applicability.

KW - Cationic Polymerization

KW - Free-Radical Polymerization

KW - Mechanistic Transformations

KW - Photoinduced Controlled Living Polymerization

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Photoinduced Controlled/Living Polymerizations

Abstract

Bibliographical note

Funding

Keywords

UN SDGs

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