Photochemical synthesis of metal carbonyl complexes of tetraalkyldiphosphine disulfides, [M2(CO)10(μ-R2P(S)P(S)R2)] (M = Mo, W; R = Me, Et, n-Pr, n-Bu)

Ozan Sanlı Şentürk; Fadime Ugˇur

doi:10.1081/SIM-100108266

Photochemical synthesis of metal carbonyl complexes of tetraalkyldiphosphine disulfides, [M₂(CO)₁₀(μ-R₂P(S)P(S)R₂)] (M = Mo, W; R = Me, Et, n-Pr, n-Bu)

Ozan Sanlı Şentürk, Fadime Ugˇur

Ege University

Research output: Contribution to journal › Article › peer-review

30 Citations (Scopus)

Abstract

The new complexes [M₂(CO)₁₀(μ-R₂P(S)P(S)R₂)] (M=Mo, W; R=Me, Et, n-Pr, n-Bu), (la)7(1d) and (2a)7(2d) [(1a), M=Mo, R=Me; (1b), M=Mo, R=Et; (1c), M=Mo, R=n-Pr; (1d), M=Mo, R=n-Bu; (2a), M=W, R=Me; (2b), M=W, R=Et; (2c), M=W, R=n-Pr; (2d), M=W, R=n-Bu] have been prepared by the photochemical reaction of M(CO)6 with R₂P(S)P(S)R₂ (R=Me, Et, n-Pr, n-Bu). The complexes have been characterized by elemental analyses, FT-IR and ³¹P-[¹H]-NMR spectroscopy and FAB-mass spectrometry. The spectroscopic studies suggest cis-bridging bidentate coordination of the ligand between the two metals.

Original language	English
Pages (from-to)	1843-1851
Number of pages	9
Journal	Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry
Volume	31
Issue number	10
DOIs	https://doi.org/10.1081/SIM-100108266
Publication status	Published - 2001
Externally published	Yes

Funding

We thank BP (Turkey) for the provision of the photochemical apparatus. We are grateful to Dr. I. Topaloglu for obtaining the mass spectra at the University of Bristol. We thank the British Council (The Foreign and Commonwealth Office Scholarships) for financial support to Ozan Sanlı S¸ entürk and Fadime Ugˇ ur (Sarikahya). We are grateftul to Mr. P. Heath for obtaining the NMR data at the University of Reading.

Funders	Funder number
British Council

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@article{96a612ee96734e9184304ab015993c6e,

title = "Photochemical synthesis of metal carbonyl complexes of tetraalkyldiphosphine disulfides, [M2(CO)10(μ-R2P(S)P(S)R2)] (M = Mo, W; R = Me, Et, n-Pr, n-Bu)",

abstract = "The new complexes [M2(CO)10(μ-R2P(S)P(S)R2)] (M=Mo, W; R=Me, Et, n-Pr, n-Bu), (la)7(1d) and (2a)7(2d) [(1a), M=Mo, R=Me; (1b), M=Mo, R=Et; (1c), M=Mo, R=n-Pr; (1d), M=Mo, R=n-Bu; (2a), M=W, R=Me; (2b), M=W, R=Et; (2c), M=W, R=n-Pr; (2d), M=W, R=n-Bu] have been prepared by the photochemical reaction of M(CO)6 with R2P(S)P(S)R2 (R=Me, Et, n-Pr, n-Bu). The complexes have been characterized by elemental analyses, FT-IR and 31P-[1H]-NMR spectroscopy and FAB-mass spectrometry. The spectroscopic studies suggest cis-bridging bidentate coordination of the ligand between the two metals.",

author = "{\c S}ent{\"u}rk, {Ozan Sanlı} and Fadime Ugˇur",

year = "2001",

doi = "10.1081/SIM-100108266",

language = "English",

volume = "31",

pages = "1843--1851",

journal = "Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry",

issn = "0094-5714",

publisher = "Taylor and Francis Ltd.",

number = "10",

}

Photochemical synthesis of metal carbonyl complexes of tetraalkyldiphosphine disulfides, [M₂(CO)₁₀(μ-R₂P(S)P(S)R₂)] (M = Mo, W; R = Me, Et, n-Pr, n-Bu). / Şentürk, Ozan Sanlı; Ugˇur, Fadime.
In: Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, Vol. 31, No. 10, 2001, p. 1843-1851.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Photochemical synthesis of metal carbonyl complexes of tetraalkyldiphosphine disulfides, [M2(CO)10(μ-R2P(S)P(S)R2)] (M = Mo, W; R = Me, Et, n-Pr, n-Bu)

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N2 - The new complexes [M2(CO)10(μ-R2P(S)P(S)R2)] (M=Mo, W; R=Me, Et, n-Pr, n-Bu), (la)7(1d) and (2a)7(2d) [(1a), M=Mo, R=Me; (1b), M=Mo, R=Et; (1c), M=Mo, R=n-Pr; (1d), M=Mo, R=n-Bu; (2a), M=W, R=Me; (2b), M=W, R=Et; (2c), M=W, R=n-Pr; (2d), M=W, R=n-Bu] have been prepared by the photochemical reaction of M(CO)6 with R2P(S)P(S)R2 (R=Me, Et, n-Pr, n-Bu). The complexes have been characterized by elemental analyses, FT-IR and 31P-[1H]-NMR spectroscopy and FAB-mass spectrometry. The spectroscopic studies suggest cis-bridging bidentate coordination of the ligand between the two metals.

AB - The new complexes [M2(CO)10(μ-R2P(S)P(S)R2)] (M=Mo, W; R=Me, Et, n-Pr, n-Bu), (la)7(1d) and (2a)7(2d) [(1a), M=Mo, R=Me; (1b), M=Mo, R=Et; (1c), M=Mo, R=n-Pr; (1d), M=Mo, R=n-Bu; (2a), M=W, R=Me; (2b), M=W, R=Et; (2c), M=W, R=n-Pr; (2d), M=W, R=n-Bu] have been prepared by the photochemical reaction of M(CO)6 with R2P(S)P(S)R2 (R=Me, Et, n-Pr, n-Bu). The complexes have been characterized by elemental analyses, FT-IR and 31P-[1H]-NMR spectroscopy and FAB-mass spectrometry. The spectroscopic studies suggest cis-bridging bidentate coordination of the ligand between the two metals.

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Photochemical synthesis of metal carbonyl complexes of tetraalkyldiphosphine disulfides, [M₂(CO)₁₀(μ-R₂P(S)P(S)R₂)] (M = Mo, W; R = Me, Et, n-Pr, n-Bu)

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