Photochemical synthesis and crystal structure of dimethylphosphinodithiatomanganese(I) tetracarbonyl, [Mn(CO)4(S2PMe2)]

Matthew J. Almond; Michael G.B. Drew; Fadime Sarikahya; Ozan Sanli Senturk

doi:10.1016/0277-5387(94)00416-C

Photochemical synthesis and crystal structure of dimethylphosphinodithiatomanganese(I) tetracarbonyl, [Mn(CO)₄(S₂PMe₂)]

Matthew J. Almond^*, Michael G.B. Drew, Fadime Sarikahya, Ozan Sanli Senturk

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

The new compound [Mn(CO)₄(S₂PMe₂] (A) has been prepared by the photochemical reaction of Mn₂(CO)₁₀ and Me₂P(S)P(S)Me₂ in benzene solution. A single crystal X-ray diffraction study confirms that the manganese atom in A is six-coordinate with a distorted octahedral array around the metal centre: the dithiophosphinate ligand adopts a chelating bidentate mode of coordination. The two PS distances [2.008(4) and 2.004(4) Å] are equal within the limits of experimental error, as indeed are the two MnS distances [2.419(4) and 2.423(4) Å]. The "bite" S...S distance is ca 3.196 Å. The Mn(CO)₄ moiety adopts local C_2v symmetry. The crystallographic data are backed up by an IR spectroscopic study.

Original language	English
Pages (from-to)	1433-1437
Number of pages	5
Journal	Polyhedron
Volume	14
Issue number	11
DOIs	https://doi.org/10.1016/0277-5387(94)00416-C
Publication status	Published - Jun 1995
Externally published	Yes

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@article{d04c8a62e8ee444ca0d3f4cf8c865808,

title = "Photochemical synthesis and crystal structure of dimethylphosphinodithiatomanganese(I) tetracarbonyl, [Mn(CO)4(S2PMe2)]",

abstract = "The new compound [Mn(CO)4(S2PMe2] (A) has been prepared by the photochemical reaction of Mn2(CO)10 and Me2P(S)P(S)Me2 in benzene solution. A single crystal X-ray diffraction study confirms that the manganese atom in A is six-coordinate with a distorted octahedral array around the metal centre: the dithiophosphinate ligand adopts a chelating bidentate mode of coordination. The two PS distances [2.008(4) and 2.004(4) {\AA}] are equal within the limits of experimental error, as indeed are the two MnS distances [2.419(4) and 2.423(4) {\AA}]. The {"}bite{"} S...S distance is ca 3.196 {\AA}. The Mn(CO)4 moiety adopts local C2v symmetry. The crystallographic data are backed up by an IR spectroscopic study.",

author = "Almond, {Matthew J.} and Drew, {Michael G.B.} and Fadime Sarikahya and Senturk, {Ozan Sanli}",

year = "1995",

month = jun,

doi = "10.1016/0277-5387(94)00416-C",

language = "English",

volume = "14",

pages = "1433--1437",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Ltd",

number = "11",

}

TY - JOUR

T1 - Photochemical synthesis and crystal structure of dimethylphosphinodithiatomanganese(I) tetracarbonyl, [Mn(CO)4(S2PMe2)]

AU - Almond, Matthew J.

AU - Drew, Michael G.B.

AU - Sarikahya, Fadime

AU - Senturk, Ozan Sanli

PY - 1995/6

Y1 - 1995/6

N2 - The new compound [Mn(CO)4(S2PMe2] (A) has been prepared by the photochemical reaction of Mn2(CO)10 and Me2P(S)P(S)Me2 in benzene solution. A single crystal X-ray diffraction study confirms that the manganese atom in A is six-coordinate with a distorted octahedral array around the metal centre: the dithiophosphinate ligand adopts a chelating bidentate mode of coordination. The two PS distances [2.008(4) and 2.004(4) Å] are equal within the limits of experimental error, as indeed are the two MnS distances [2.419(4) and 2.423(4) Å]. The "bite" S...S distance is ca 3.196 Å. The Mn(CO)4 moiety adopts local C2v symmetry. The crystallographic data are backed up by an IR spectroscopic study.

AB - The new compound [Mn(CO)4(S2PMe2] (A) has been prepared by the photochemical reaction of Mn2(CO)10 and Me2P(S)P(S)Me2 in benzene solution. A single crystal X-ray diffraction study confirms that the manganese atom in A is six-coordinate with a distorted octahedral array around the metal centre: the dithiophosphinate ligand adopts a chelating bidentate mode of coordination. The two PS distances [2.008(4) and 2.004(4) Å] are equal within the limits of experimental error, as indeed are the two MnS distances [2.419(4) and 2.423(4) Å]. The "bite" S...S distance is ca 3.196 Å. The Mn(CO)4 moiety adopts local C2v symmetry. The crystallographic data are backed up by an IR spectroscopic study.

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U2 - 10.1016/0277-5387(94)00416-C

DO - 10.1016/0277-5387(94)00416-C

M3 - Article

AN - SCOPUS:0006360315

SN - 0277-5387

VL - 14

SP - 1433

EP - 1437

JO - Polyhedron

JF - Polyhedron

IS - 11

ER -

Photochemical synthesis and crystal structure of dimethylphosphinodithiatomanganese(I) tetracarbonyl, [Mn(CO)₄(S₂PMe₂)]

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