Photochemical reactions of metal carbonyls [M(CO)6 (M=Cr, Mo, W), Re(CO)5Br, Mn(CO)3Cp] with salicylaldehyde ethanesulfonylhydrazone (Hsalesh)

Ozan Sanli Şentürk; Ümmühan Özdemir; Sema Sert; Nurcan Karacan; Fadime Uǧur

doi:10.1080/00958970600857029

Photochemical reactions of metal carbonyls [M(CO)₆ (M=Cr, Mo, W), Re(CO)₅Br, Mn(CO)₃Cp] with salicylaldehyde ethanesulfonylhydrazone (Hsalesh)

Ozan Sanli Şentürk^*
, Ümmühan Özdemir
, Sema Sert
, Nurcan Karacan
, Fadime Uǧur

^*Corresponding author for this work

Department of Chemistry

Gazi University
Ege University

Research output: Contribution to journal › Article › peer-review

31 Citations (Scopus)

Abstract

The new complexes, M(CO)₅(Hsalesh) (M∈=∈Cr (1), Mo (2), W (3)), Re(CO)₄Br(Hsalesh) (4) and Mn(CO)₃(Hsalesh) (5) have been synthesized by the photochemical reaction of metal carbonyls M(CO)₆ (M∈=∈Cr, Mo, W), Re(CO)₅Br, and Mn(CO)₃Cp with salicylaldehyde ethanesulfonyl hydrazone (Hsalesh). The complexes have been characterized by elemental analysis, EI mass spectrometry, FT-IR and ¹H NMR spectroscopy. The spectroscopic studies show that Hsalesh behaves as a monodentate ligand coordinating via imine N donor atom in M(CO)₅(Hsalesh) (M∈=∈Cr, Mo, W) and Re(CO)₄Br(Hsalesh) and as a tridentate ligand in Mn(CO) ₃(salesh).

Original language	English
Pages (from-to)	229-235
Number of pages	7
Journal	Journal of Coordination Chemistry
Volume	60
Issue number	2
DOIs	https://doi.org/10.1080/00958970600857029
Publication status	Published - 20 Jan 2007

Funding

This research was supported by Gazi University Research Found under Project No. 05-98/24. We thank BP (Turkey) for the provision of photochemical apparatus and Research Foundation of Ege. We thank TUBITAK_ for allocation of time at the NMR, mass spectra and elemental analyses.

Funders	Funder number
Gazi University Research Found	05-98/24

Keywords

Hydrazone
Metal carbonyls
Salicylaldehyde ethanesulfonylhydrazone

Access to Document

10.1080/00958970600857029

Cite this

@article{20459da3eba044bbadf405994bdc4e87,

title = "Photochemical reactions of metal carbonyls [M(CO)6 (M=Cr, Mo, W), Re(CO)5Br, Mn(CO)3Cp] with salicylaldehyde ethanesulfonylhydrazone (Hsalesh)",

abstract = "The new complexes, M(CO)5(Hsalesh) (M∈=∈Cr (1), Mo (2), W (3)), Re(CO)4Br(Hsalesh) (4) and Mn(CO)3(Hsalesh) (5) have been synthesized by the photochemical reaction of metal carbonyls M(CO)6 (M∈=∈Cr, Mo, W), Re(CO)5Br, and Mn(CO)3Cp with salicylaldehyde ethanesulfonyl hydrazone (Hsalesh). The complexes have been characterized by elemental analysis, EI mass spectrometry, FT-IR and 1H NMR spectroscopy. The spectroscopic studies show that Hsalesh behaves as a monodentate ligand coordinating via imine N donor atom in M(CO)5(Hsalesh) (M∈=∈Cr, Mo, W) and Re(CO)4Br(Hsalesh) and as a tridentate ligand in Mn(CO) 3(salesh).",

keywords = "Hydrazone, Metal carbonyls, Salicylaldehyde ethanesulfonylhydrazone",

author = "{\c S}ent{\"u}rk, \{Ozan Sanli\} and {\"U}mm{\"u}han {\"O}zdemir and Sema Sert and Nurcan Karacan and Fadime Uǧur",

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T1 - Photochemical reactions of metal carbonyls [M(CO)6 (M=Cr, Mo, W), Re(CO)5Br, Mn(CO)3Cp] with salicylaldehyde ethanesulfonylhydrazone (Hsalesh)

AU - Şentürk, Ozan Sanli

AU - Özdemir, Ümmühan

AU - Sert, Sema

AU - Karacan, Nurcan

AU - Uǧur, Fadime

PY - 2007/1/20

Y1 - 2007/1/20

N2 - The new complexes, M(CO)5(Hsalesh) (M∈=∈Cr (1), Mo (2), W (3)), Re(CO)4Br(Hsalesh) (4) and Mn(CO)3(Hsalesh) (5) have been synthesized by the photochemical reaction of metal carbonyls M(CO)6 (M∈=∈Cr, Mo, W), Re(CO)5Br, and Mn(CO)3Cp with salicylaldehyde ethanesulfonyl hydrazone (Hsalesh). The complexes have been characterized by elemental analysis, EI mass spectrometry, FT-IR and 1H NMR spectroscopy. The spectroscopic studies show that Hsalesh behaves as a monodentate ligand coordinating via imine N donor atom in M(CO)5(Hsalesh) (M∈=∈Cr, Mo, W) and Re(CO)4Br(Hsalesh) and as a tridentate ligand in Mn(CO) 3(salesh).

AB - The new complexes, M(CO)5(Hsalesh) (M∈=∈Cr (1), Mo (2), W (3)), Re(CO)4Br(Hsalesh) (4) and Mn(CO)3(Hsalesh) (5) have been synthesized by the photochemical reaction of metal carbonyls M(CO)6 (M∈=∈Cr, Mo, W), Re(CO)5Br, and Mn(CO)3Cp with salicylaldehyde ethanesulfonyl hydrazone (Hsalesh). The complexes have been characterized by elemental analysis, EI mass spectrometry, FT-IR and 1H NMR spectroscopy. The spectroscopic studies show that Hsalesh behaves as a monodentate ligand coordinating via imine N donor atom in M(CO)5(Hsalesh) (M∈=∈Cr, Mo, W) and Re(CO)4Br(Hsalesh) and as a tridentate ligand in Mn(CO) 3(salesh).

KW - Hydrazone

KW - Metal carbonyls

KW - Salicylaldehyde ethanesulfonylhydrazone

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DO - 10.1080/00958970600857029

M3 - Article

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