Photochemical reactions of metal carbonyls [M(CO)6 (M = Cr, Mo, W)] with N,N′-bis(salicylidene)-1,2-bis-(o-aminophenoxy)ethane

Elif Subasi; Hamdi Temel; Ozan S. Senturk; Fadime Ugur

doi:10.1080/00958970600571703

Photochemical reactions of metal carbonyls [M(CO)₆ (M = Cr, Mo, W)] with N,N′-bis(salicylidene)-1,2-bis-(o-aminophenoxy)ethane

Elif Subasi^*, Hamdi Temel, Ozan S. Senturk, Fadime Ugur

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

The complexes [M(CO)₄(η²-H₂L)] [M = Cr; 1, Mo; 2, W; 3] have been synthesized by photochemical reactions of VIB metal carbonyls [M(CO)₆] [M = Cr, Mo, W] with N,N′- bis(salicylidene)-1,2-bis-(o-aminophenoxy)ethane (H₂L) in THF and characterized by elemental analyses, FTIR, ¹H NMR and mass spectra. The H₂L ligand is coordinated to the central metal as a bidentate ligand via the central azomethine nitrogen atoms in 1-3.

Original language	English
Pages (from-to)	1807-1811
Number of pages	5
Journal	Journal of Coordination Chemistry
Volume	59
Issue number	16
DOIs	https://doi.org/10.1080/00958970600571703
Publication status	Published - 10 Nov 2006
Externally published	Yes

Funding

We thank BP (Turkey) for the provision of photochemical apparatus and the Research Foundation of Dokuz Eylul, Ege and Dicle Universities for funding. We thank EBILTEM_ and TUBITAK_ for allocation of time for recording NMR and mass spectra, and elemental analyses.

Funders	Funder number
BP

Keywords

Metal carbonyls
N,N′-bis(salicylidene)-1,2-bis-(o-aminophenoxy)ethane
Schiff base

Access to Document

10.1080/00958970600571703

Cite this

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title = "Photochemical reactions of metal carbonyls [M(CO)6 (M = Cr, Mo, W)] with N,N′-bis(salicylidene)-1,2-bis-(o-aminophenoxy)ethane",

abstract = "The complexes [M(CO)4(η2-H2L)] [M = Cr; 1, Mo; 2, W; 3] have been synthesized by photochemical reactions of VIB metal carbonyls [M(CO)6] [M = Cr, Mo, W] with N,N′- bis(salicylidene)-1,2-bis-(o-aminophenoxy)ethane (H2L) in THF and characterized by elemental analyses, FTIR, 1H NMR and mass spectra. The H2L ligand is coordinated to the central metal as a bidentate ligand via the central azomethine nitrogen atoms in 1-3.",

keywords = "Metal carbonyls, N,N′-bis(salicylidene)-1,2-bis-(o-aminophenoxy)ethane, Schiff base",

author = "Elif Subasi and Hamdi Temel and Senturk, \{Ozan S.\} and Fadime Ugur",

year = "2006",

month = nov,

day = "10",

doi = "10.1080/00958970600571703",

language = "English",

volume = "59",

pages = "1807--1811",

journal = "Journal of Coordination Chemistry",

issn = "0095-8972",

publisher = "Taylor and Francis Ltd.",

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TY - JOUR

T1 - Photochemical reactions of metal carbonyls [M(CO)6 (M = Cr, Mo, W)] with N,N′-bis(salicylidene)-1,2-bis-(o-aminophenoxy)ethane

AU - Subasi, Elif

AU - Temel, Hamdi

AU - Senturk, Ozan S.

AU - Ugur, Fadime

PY - 2006/11/10

Y1 - 2006/11/10

N2 - The complexes [M(CO)4(η2-H2L)] [M = Cr; 1, Mo; 2, W; 3] have been synthesized by photochemical reactions of VIB metal carbonyls [M(CO)6] [M = Cr, Mo, W] with N,N′- bis(salicylidene)-1,2-bis-(o-aminophenoxy)ethane (H2L) in THF and characterized by elemental analyses, FTIR, 1H NMR and mass spectra. The H2L ligand is coordinated to the central metal as a bidentate ligand via the central azomethine nitrogen atoms in 1-3.

AB - The complexes [M(CO)4(η2-H2L)] [M = Cr; 1, Mo; 2, W; 3] have been synthesized by photochemical reactions of VIB metal carbonyls [M(CO)6] [M = Cr, Mo, W] with N,N′- bis(salicylidene)-1,2-bis-(o-aminophenoxy)ethane (H2L) in THF and characterized by elemental analyses, FTIR, 1H NMR and mass spectra. The H2L ligand is coordinated to the central metal as a bidentate ligand via the central azomethine nitrogen atoms in 1-3.

KW - Metal carbonyls

KW - N,N′-bis(salicylidene)-1,2-bis-(o-aminophenoxy)ethane

KW - Schiff base

UR - https://www.scopus.com/pages/publications/33750318311

U2 - 10.1080/00958970600571703

DO - 10.1080/00958970600571703

M3 - Article

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SN - 0095-8972

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