Photochemical reactions of metal carbonyls [M(CO)6 (M = Cr, Mo, W)] with N,N′-bis(salicylidene)-1,2-bis-(o-aminophenoxy)ethane

Elif Subasi*, Hamdi Temel, Ozan S. Senturk, Fadime Ugur

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

11 Citations (Scopus)

Abstract

The complexes [M(CO)42-H2L)] [M = Cr; 1, Mo; 2, W; 3] have been synthesized by photochemical reactions of VIB metal carbonyls [M(CO)6] [M = Cr, Mo, W] with N,N′- bis(salicylidene)-1,2-bis-(o-aminophenoxy)ethane (H2L) in THF and characterized by elemental analyses, FTIR, 1H NMR and mass spectra. The H2L ligand is coordinated to the central metal as a bidentate ligand via the central azomethine nitrogen atoms in 1-3.

Original languageEnglish
Pages (from-to)1807-1811
Number of pages5
JournalJournal of Coordination Chemistry
Volume59
Issue number16
DOIs
Publication statusPublished - 10 Nov 2006
Externally publishedYes

Funding

We thank BP (Turkey) for the provision of photochemical apparatus and the Research Foundation of Dokuz Eylul, Ege and Dicle Universities for funding. We thank EBILTEM_ and TUBITAK_ for allocation of time for recording NMR and mass spectra, and elemental analyses.

FundersFunder number
BP

    Keywords

    • Metal carbonyls
    • N,N′-bis(salicylidene)-1,2-bis-(o-aminophenoxy)ethane
    • Schiff base

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