TY - JOUR
T1 - Photochemical reactions of metal carbonyls [M(CO)6 (M = Cr, Mo, W)] with N,N′-bis(salicylidene)-1,2-bis-(o-aminophenoxy)ethane
AU - Subasi, Elif
AU - Temel, Hamdi
AU - Senturk, Ozan S.
AU - Ugur, Fadime
PY - 2006/11/10
Y1 - 2006/11/10
N2 - The complexes [M(CO)4(η2-H2L)] [M = Cr; 1, Mo; 2, W; 3] have been synthesized by photochemical reactions of VIB metal carbonyls [M(CO)6] [M = Cr, Mo, W] with N,N′- bis(salicylidene)-1,2-bis-(o-aminophenoxy)ethane (H2L) in THF and characterized by elemental analyses, FTIR, 1H NMR and mass spectra. The H2L ligand is coordinated to the central metal as a bidentate ligand via the central azomethine nitrogen atoms in 1-3.
AB - The complexes [M(CO)4(η2-H2L)] [M = Cr; 1, Mo; 2, W; 3] have been synthesized by photochemical reactions of VIB metal carbonyls [M(CO)6] [M = Cr, Mo, W] with N,N′- bis(salicylidene)-1,2-bis-(o-aminophenoxy)ethane (H2L) in THF and characterized by elemental analyses, FTIR, 1H NMR and mass spectra. The H2L ligand is coordinated to the central metal as a bidentate ligand via the central azomethine nitrogen atoms in 1-3.
KW - Metal carbonyls
KW - N,N′-bis(salicylidene)-1,2-bis-(o-aminophenoxy)ethane
KW - Schiff base
UR - http://www.scopus.com/inward/record.url?scp=33750318311&partnerID=8YFLogxK
U2 - 10.1080/00958970600571703
DO - 10.1080/00958970600571703
M3 - Article
AN - SCOPUS:33750318311
SN - 0095-8972
VL - 59
SP - 1807
EP - 1811
JO - Journal of Coordination Chemistry
JF - Journal of Coordination Chemistry
IS - 16
ER -