Photochemical reactions of metal carbonyls [M(CO)6 (M = Cr, Mo and W), Re(CO)5Br, Mn(CO)3Cp] with 2-hydroxyacetophenone methanesulfonylhydrazone (apmsh)

Ummuhan Ozdemir; Nurcan Karacan; Ozan Sanlt Şentürk; Sema Sert; Fadime Uǧur (Sarikahya)

doi:10.1023/A:1023655804019

Photochemical reactions of metal carbonyls [M(CO)₆ (M = Cr, Mo and W), Re(CO)₅Br, Mn(CO)₃Cp] with 2-hydroxyacetophenone methanesulfonylhydrazone (apmsh)

Ummuhan Ozdemir
, Nurcan Karacan
, Ozan Sanlt Şentürk^*
, Sema Sert
, Fadime Uǧur (Sarikahya)

^*Corresponding author for this work

Gazi University
Ege University

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

Five new complexes, [M(CO)₅(apmsh)] [M = Cr; (1), Mo; (2), W; (3)], [Re(CO)₄Br(apmsh)] (4) and [Mn(CO)₃(apmsh)] (5) have been synthesized by the photochemical reaction of metal carbonyls [M(CO)₆] (M = Cr, Mo and W), [Re(CO)₅Br], and [Mn(CO)₃Cp] with 2-hydroxyacetophenone methanesulfonylhydrazone (apmsh). The complexes have been characterized by elemental analysis, mass spectrometry, f.t.-i.r. and ¹H spectroscopy. Spectroscopic studies show that apmsh behaves as a monodentate ligand coordinating via the imine N donor atom in [M(CO)₅(apmsh)] (1-4) and as a tridentate ligand in (5).

Original language	English
Pages (from-to)	443-446
Number of pages	4
Journal	Transition Metal Chemistry
Volume	28
Issue number	4
DOIs	https://doi.org/10.1023/A:1023655804019
Publication status	Published - May 2003
Externally published	Yes

Funding

We thank BP (Turkey) for the provision of photochemical apparatus and the Research Foundation of Ege and Gazi Universities for funds. We thank TUBİTAK for allocation of time for n.m.r., mass spectra and elemental analyses.

Funders
Research Foundation of Ege and Gazi Universities for funds

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@article{465ffbfa9b3d4ef3ba871c2566429aba,

title = "Photochemical reactions of metal carbonyls [M(CO)6 (M = Cr, Mo and W), Re(CO)5Br, Mn(CO)3Cp] with 2-hydroxyacetophenone methanesulfonylhydrazone (apmsh)",

abstract = "Five new complexes, [M(CO)5(apmsh)] [M = Cr; (1), Mo; (2), W; (3)], [Re(CO)4Br(apmsh)] (4) and [Mn(CO)3(apmsh)] (5) have been synthesized by the photochemical reaction of metal carbonyls [M(CO)6] (M = Cr, Mo and W), [Re(CO)5Br], and [Mn(CO)3Cp] with 2-hydroxyacetophenone methanesulfonylhydrazone (apmsh). The complexes have been characterized by elemental analysis, mass spectrometry, f.t.-i.r. and 1H spectroscopy. Spectroscopic studies show that apmsh behaves as a monodentate ligand coordinating via the imine N donor atom in [M(CO)5(apmsh)] (1-4) and as a tridentate ligand in (5).",

author = "Ummuhan Ozdemir and Nurcan Karacan and {\c S}ent{\"u}rk, \{Ozan Sanlt\} and Sema Sert and \{Uǧur (Sarikahya)\}, Fadime",

year = "2003",

month = may,

doi = "10.1023/A:1023655804019",

language = "English",

volume = "28",

pages = "443--446",

journal = "Transition Metal Chemistry",

issn = "0340-4285",

publisher = "Springer Netherlands",

number = "4",

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TY - JOUR

T1 - Photochemical reactions of metal carbonyls [M(CO)6 (M = Cr, Mo and W), Re(CO)5Br, Mn(CO)3Cp] with 2-hydroxyacetophenone methanesulfonylhydrazone (apmsh)

AU - Ozdemir, Ummuhan

AU - Karacan, Nurcan

AU - Şentürk, Ozan Sanlt

AU - Sert, Sema

AU - Uǧur (Sarikahya), Fadime

PY - 2003/5

Y1 - 2003/5

N2 - Five new complexes, [M(CO)5(apmsh)] [M = Cr; (1), Mo; (2), W; (3)], [Re(CO)4Br(apmsh)] (4) and [Mn(CO)3(apmsh)] (5) have been synthesized by the photochemical reaction of metal carbonyls [M(CO)6] (M = Cr, Mo and W), [Re(CO)5Br], and [Mn(CO)3Cp] with 2-hydroxyacetophenone methanesulfonylhydrazone (apmsh). The complexes have been characterized by elemental analysis, mass spectrometry, f.t.-i.r. and 1H spectroscopy. Spectroscopic studies show that apmsh behaves as a monodentate ligand coordinating via the imine N donor atom in [M(CO)5(apmsh)] (1-4) and as a tridentate ligand in (5).

AB - Five new complexes, [M(CO)5(apmsh)] [M = Cr; (1), Mo; (2), W; (3)], [Re(CO)4Br(apmsh)] (4) and [Mn(CO)3(apmsh)] (5) have been synthesized by the photochemical reaction of metal carbonyls [M(CO)6] (M = Cr, Mo and W), [Re(CO)5Br], and [Mn(CO)3Cp] with 2-hydroxyacetophenone methanesulfonylhydrazone (apmsh). The complexes have been characterized by elemental analysis, mass spectrometry, f.t.-i.r. and 1H spectroscopy. Spectroscopic studies show that apmsh behaves as a monodentate ligand coordinating via the imine N donor atom in [M(CO)5(apmsh)] (1-4) and as a tridentate ligand in (5).

UR - https://www.scopus.com/pages/publications/0038540322

U2 - 10.1023/A:1023655804019

DO - 10.1023/A:1023655804019

M3 - Article

AN - SCOPUS:0038540322

SN - 0340-4285

VL - 28

SP - 443

EP - 446

JO - Transition Metal Chemistry

JF - Transition Metal Chemistry

IS - 4

ER -

Photochemical reactions of metal carbonyls [M(CO)₆ (M = Cr, Mo and W), Re(CO)₅Br, Mn(CO)₃Cp] with 2-hydroxyacetophenone methanesulfonylhydrazone (apmsh)

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