Photochemical reactions of [η5-C5H 5Mn(CO)3] with Ph2P(S)(CH2) nP(S)Ph2 [n=1, dppm(S)2; 2, dppe(S) 2; 3, dppp(S)2]

Elif Subasi; Ozan S. Senturk; Fadime Ugur

doi:10.1007/s11243-004-4994-7

Photochemical reactions of [η⁵-C₅H ₅Mn(CO)₃] with Ph₂P(S)(CH₂) _nP(S)Ph₂ [n=1, dppm(S)₂; 2, dppe(S) ₂; 3, dppp(S)₂]

Elif Subasi^*, Ozan S. Senturk, Fadime Ugur

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

Six new complexes, Mn(CO)(η⁵-C₅H ₅){Ph₂P(S)(CH₂)_nP(S)Ph₂}] (1a-3a) [(1a), n = 1; (2a), n = 2; (3a), n = 3] and [Mn₂(CO) ₄(η⁵-C₅H₅)₂(cis-μ- Ph₂P(S)(CH₂)_nP(S)Ph₂)] (1b-3b) [(1b), n = 1; (2b), n = 2; (3b), n = 3] have been synthesized by the photochemical reaction of [(ηn⁵-C₅H ₅)Mn(CO)₃] with Ph₂P(S)(CH₂) _nP(S)Ph₂ [n = 1, dppm(S)₂; 2, dppe(S) ₂; 3, dppp(S)₂]. The complexes have been characterized by elemental analysis, mass spectroscopy, f.t.-i.r. and ³¹P-( ¹H]-n.m.r. spectroscopy. The spectroscopic studies reveal that coordination of the ligand is cis-chelate bidentate in [Mn(CO) (η⁵-C₅H₅){Ph₂P(S)(CH ₂)_nP(S)Ph2}] (1a-3a) and cis-bridging bidentate between two metals in [Mn₂(CO)₄(η⁵-C ₅H₅)₂(Cis-μ-Ph₂P(S)(CH ₂)_nP(S)Ph₂)] (1b-3b).

Original language	English
Pages (from-to)	649-652
Number of pages	4
Journal	Transition Metal Chemistry
Volume	29
Issue number	6
DOIs	https://doi.org/10.1007/s11243-004-4994-7
Publication status	Published - Sept 2004
Externally published	Yes

Funding

We thank BP (Turkey) for the provision of photochemical apparatus and TUBITAK-BAYG (Nato A-2) and the Research Foundation of Ege University for funds. We are grateful to Dr. Graeme Hogarth and technical staff for obtaining the elementel analyses and mass spectra in the Christopher Ingold Laboratories, University College, London.

Funders	Funder number
TUBITAK-BAYG	A-2
BP
Ege University Research Foundation

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10.1007/s11243-004-4994-7

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@article{f08fb1798e834863a3ebecce97dbfe27,

title = "Photochemical reactions of [η5-C5H 5Mn(CO)3] with Ph2P(S)(CH2) nP(S)Ph2 [n=1, dppm(S)2; 2, dppe(S) 2; 3, dppp(S)2]",

abstract = "Six new complexes, Mn(CO)(η5-C5H 5){Ph2P(S)(CH2)nP(S)Ph2}] (1a-3a) [(1a), n = 1; (2a), n = 2; (3a), n = 3] and [Mn2(CO) 4(η5-C5H5)2(cis-μ- Ph2P(S)(CH2)nP(S)Ph2)] (1b-3b) [(1b), n = 1; (2b), n = 2; (3b), n = 3] have been synthesized by the photochemical reaction of [(ηn5-C5H 5)Mn(CO)3] with Ph2P(S)(CH2) nP(S)Ph2 [n = 1, dppm(S)2; 2, dppe(S) 2; 3, dppp(S)2]. The complexes have been characterized by elemental analysis, mass spectroscopy, f.t.-i.r. and 31P-( 1H]-n.m.r. spectroscopy. The spectroscopic studies reveal that coordination of the ligand is cis-chelate bidentate in [Mn(CO) (η5-C5H5){Ph2P(S)(CH 2)nP(S)Ph2}] (1a-3a) and cis-bridging bidentate between two metals in [Mn2(CO)4(η5-C 5H5)2(Cis-μ-Ph2P(S)(CH 2)nP(S)Ph2)] (1b-3b).",

author = "Elif Subasi and Senturk, {Ozan S.} and Fadime Ugur",

year = "2004",

month = sep,

doi = "10.1007/s11243-004-4994-7",

language = "English",

volume = "29",

pages = "649--652",

journal = "Transition Metal Chemistry",

issn = "0340-4285",

publisher = "Springer Netherlands",

number = "6",

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T1 - Photochemical reactions of [η5-C5H 5Mn(CO)3] with Ph2P(S)(CH2) nP(S)Ph2 [n=1, dppm(S)2; 2, dppe(S) 2; 3, dppp(S)2]

AU - Subasi, Elif

AU - Senturk, Ozan S.

AU - Ugur, Fadime

PY - 2004/9

Y1 - 2004/9

N2 - Six new complexes, Mn(CO)(η5-C5H 5){Ph2P(S)(CH2)nP(S)Ph2}] (1a-3a) [(1a), n = 1; (2a), n = 2; (3a), n = 3] and [Mn2(CO) 4(η5-C5H5)2(cis-μ- Ph2P(S)(CH2)nP(S)Ph2)] (1b-3b) [(1b), n = 1; (2b), n = 2; (3b), n = 3] have been synthesized by the photochemical reaction of [(ηn5-C5H 5)Mn(CO)3] with Ph2P(S)(CH2) nP(S)Ph2 [n = 1, dppm(S)2; 2, dppe(S) 2; 3, dppp(S)2]. The complexes have been characterized by elemental analysis, mass spectroscopy, f.t.-i.r. and 31P-( 1H]-n.m.r. spectroscopy. The spectroscopic studies reveal that coordination of the ligand is cis-chelate bidentate in [Mn(CO) (η5-C5H5){Ph2P(S)(CH 2)nP(S)Ph2}] (1a-3a) and cis-bridging bidentate between two metals in [Mn2(CO)4(η5-C 5H5)2(Cis-μ-Ph2P(S)(CH 2)nP(S)Ph2)] (1b-3b).

AB - Six new complexes, Mn(CO)(η5-C5H 5){Ph2P(S)(CH2)nP(S)Ph2}] (1a-3a) [(1a), n = 1; (2a), n = 2; (3a), n = 3] and [Mn2(CO) 4(η5-C5H5)2(cis-μ- Ph2P(S)(CH2)nP(S)Ph2)] (1b-3b) [(1b), n = 1; (2b), n = 2; (3b), n = 3] have been synthesized by the photochemical reaction of [(ηn5-C5H 5)Mn(CO)3] with Ph2P(S)(CH2) nP(S)Ph2 [n = 1, dppm(S)2; 2, dppe(S) 2; 3, dppp(S)2]. The complexes have been characterized by elemental analysis, mass spectroscopy, f.t.-i.r. and 31P-( 1H]-n.m.r. spectroscopy. The spectroscopic studies reveal that coordination of the ligand is cis-chelate bidentate in [Mn(CO) (η5-C5H5){Ph2P(S)(CH 2)nP(S)Ph2}] (1a-3a) and cis-bridging bidentate between two metals in [Mn2(CO)4(η5-C 5H5)2(Cis-μ-Ph2P(S)(CH 2)nP(S)Ph2)] (1b-3b).

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U2 - 10.1007/s11243-004-4994-7

DO - 10.1007/s11243-004-4994-7

M3 - Article

AN - SCOPUS:10844289522

SN - 0340-4285

VL - 29

SP - 649

EP - 652

JO - Transition Metal Chemistry

JF - Transition Metal Chemistry

IS - 6

ER -

Photochemical reactions of [η⁵-C₅H ₅Mn(CO)₃] with Ph₂P(S)(CH₂) _nP(S)Ph₂ [n=1, dppm(S)₂; 2, dppe(S) ₂; 3, dppp(S)₂]

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